简介:Theoneplusone(1+1)modeofhydrosilationreactionofladderlikecis-isotaticpolyallylsilsesquioxane(AllyI-T)andpolyhydrosilsesquioxane(H-T)usingdicyclopentadienylplatinumdichloride(Cp2PtCl2)asthecatalystleadstotheformationofanewpolyorganosiloxane(POS).ThepresenceofnanoscaletubularstructureintheproductPOSwaspreliminarilyprovedbyIR,1H-NMR,differentialscanningcalorimetry(DSC),X-raydiffraction(XRD),gelpermeationchromatography(GPC),atomicforcemicroscopy(AFM)andmolecularsimulation.
简介:Theglassytransitionofthepolyethyleneterephthalate(PET)sampleswhichhavebeensubjectedtosolventinducedcrystallization(SINC)wasinvestigatedbymodulateddifferentialscanningcalorimetry(MDSC)anddensitymeasurement.Thedif-ferentialofheatcapacitysignal,dC_p/dTfromMDSC,wasusedtomonitortheSINCprocess.ItrevealsthattheT_gtemperatureshiftstohighervaluewiththeadvancementofSINC.Whenthetoluene-immersingtimewaslonger(168h),thedetectionofT_gbecomemoredifficult,becausesomesmallerpeaksemergedatthelowertemperaturesandtheseareexplainedasthemovementofsmallsegmentsintheamorphousregion.TheseobservedresultsareduetothemorphologyandstructureintroducedbytheSINCprocess.
简介:TheimmunomodulatingeffectsofF12onmouseperitonealmacroplhageswasintendedtobestudiedwithdifferentdosesof20,40,80,and120mg/Kg.F12increasedperoxidaseactivityindexcdependentmammerfrom0.02±0.001,to0.175±0.038,0.211±0.041,0.137±0.045and0.078±0.036,respectively,increasedcytotoxicityfrom127.33±22.96to162.74±19.53,237.30±25.15,178.62±36.22and158.66±42.75dpm,respectively,promotedphagocyticactivityfrom0.03±0.01to0.21±0.016,0.43±0.041,0.40±0.032and0.30±0.160^b,Furthermore,F12inaconcentrationof15,30,60,120ug/mlenhancedIL-1productionfrom0.15±0.02to0.20±0.005^b0.21±0.02,0.22±0.005,0.24±0.002and0.22±0.02,respectively,ThusF12canbeconsideredasaneffectivestimulatorofmacrophages.