简介:Nitrobenzene-containingindustrialwastewaterwasdegradedinthepresenceofozonecoupledwithH2O2byhighgravitytechnology.Theeffectofhighgravityfactor,H2O2concentration,pHvalue,liquidflow-rate,andreactiontimeontheefficiencyforremovalofnitrobenzenewasinvestigated.TheexperimentalresultsshowthatthehighgravitytechnologyenhancestheozoneutilizationefficiencywithO3/H2O2showingsynergisticeffect.ThedegradationefficiencyintermsoftheCODremovalrateandnitrobenzeneremovalratereached45.8%and50.4%,respectively,underthefollowingreactionconditions,viz.:ahighgravityfactorof66.54,apHvalueof9,aH2O2/O3molarratioof1:1,aliquidflowrateof140L/h,anozoneconcentrationof40mg/L,aH2O2multipledosingmodeof6mL/h,andareactiontimeof4h.Comparedwiththeperformanceofconventionalstirredaerationmixers,thehighgravitytechnologycouldincreasetheCODandnitrobenzeneremovalraterelatedwiththenitrobenzene-containingwastewaterby22.9%and23.3%,respectively.
简介:Alkylationoftoluenewith2-chloro-2-methylpropane(t-Bu-Cl)tosynthesizepara-tert-butyltoluene(PTBT)wascarriedoutinthepresenceoftriethylaminehydrochloride-aluminumchlorideionicliquidsusedasthecatalyst.TheionicliquidswerepreparedwithdifferentmolarratiosofEt3NHCltoAlCl3,andtheeffectofthemolarratiobetweenAlCl3andEt3NHCl,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratiooftoluenetochloro-2-methylpropaneonthealkylationreactionoftoluenewithchloro-2-methyl-propanewasinvestigated.ThetestresultsshowedthattheacidicionicliquidspreparedwithEt3NHClandAlCl3hadgoodactivityandselectivityforthealkylationreactionoftoluenewithalkylchloridetoproducePTBT.TheoptimalreactionconditionswerespecifiedatanAlCl3toEt3NHClratioof1.6,areactiontemperatureof20℃,amassfractionoftoluenetoionicliquidof10%,andachloro-2-methylpropanetotoluenemolarratioof0.5.Underthesuitablereactionconditions,a98%conversionofchloro-2-methylpropaneandan82.5%selectivityofPTBTwereobtained.Ionicliquidscouldbereused5timeswithitscatalyticactivityunchanged,andtheregeneratedionicliquidscanberecycled.
简介:TheesterificationoflauricacidwithmethanolcouldbeefficientlycatalyzedbyZrOCl2·8H2O,andthisreactionwasstudiedtodevelopagreenmethodforbiodieselproduction.Theinfluencingfactors,suchasamountofcatalyst,reactiontimeandmolarratioofacidtomethanol,wereinvestigated.TheresultsindicatedthattheZrOCl2·8H2Ocatalystshowedhighcatalyticactivity,andgavea97.0%methyllaurateconversionrateunderthefollowingoptimizedconditions,viz.:alauricacid/methanolmolarratioof1:10,acatalystdosageof4%,andareactiondurationof2hatmethanolrefluxingtemperature.Thecatalystcouldbeeasilyrecoveredwhileitsactivitycouldbewellretainedafterthreecycles.TheZrOCl2·8H2Ocatalystalsoexhibitedexcellentcatalyticactivityfortheesterificationofdifferentfreelong-chainfattyacids(includingnonedibleoilswithhighacidvalue)withdifferentshortcarbonchainalcohols.Therefore,theZrOCl2·8H2Ocatalysthasgoodpotentialforthesynthesisofbiodieselfromlow-costfeedstockssuchaswastevegetableoilsandnon-edibleoils.
简介:Theproject“R&DofFCCtechnologycapableofproducinggasolinecomponentmeetingtheEuroⅢstandardcoupledwithincreasedpropyleneyield”jointlyperformedbyRIPP,JiujiangRefinery,ZhenhaiRefinery,LuoyangRefinery,andQiluCatalystFactoryhadpassedonJuly23,2005thetechni-calappraisalorganizedbySINOPECTechnologyDevelop-mentDivision.
简介:本发明已经发现一种用于双酚A的高生产率催化剂,它包括在引入砜交联的条件下由聚苯乙烯/二乙烯基苯(PS、DVB)共聚物制成的强酸性阳离子交换树脂球。
简介:冷湖3—5号构造带是柴北缘地区重要的含油气构造带,通过对该构造带的研究认为,其油气成藏主要受以下3个因素控制:①冷西次凹巨厚的残余下侏罗统地层为该构造带成藏提供了良好的物质基础;②冷湖地区第三纪以来下侏罗统烃源岩埋藏适中,构造与大规模生排烃期配置关系好;③残余生烃凹陷的构造演化使冷湖构造带成为最有利的构造带;④冷湖构造带北高南低的构造背景,决定了较高部位冷湖3—4号构造成藏优于较低部位冷湖5号构造。冷湖3—5构造带油源充足,生排烃和构造配置关系好,可发育构造、构造一岩性、不整合等类型油气藏,冷湖构造带仍是柴北缘扩展勘探的有利区带。