简介:Hierarchicalsea-urchin-shapedmanganeseoxidemicrospheresweresynthesizedviaatacilemetnoabasedonthereactionbetweenKMnO4andMnSO4inHNO3solutionat50C.Theaveragediameterofthemicrospheresis850nm.Themicrospheresconsistofacoreofdiameterof800nmandnanorodsofwidth50nm.Thenanorodsexistattheedgeofthecore.TheBrunauer-Emmett-Tellersurfaceareaofthesea-urchin-shapedmicrospheresis259.4m2/g.Apossibleformationmechanismofthehierarchicalsea-urchin-shapedmicrospheresisproposed.Thetemperaturefor90%conversionofbenzene(T90%)onthehierarchicalurchin-shapedMnO2microspheresisabout218℃.
简介:Inthisstudy,apoly(etherblockamide)(Pebax1657)compositemembraneappliedforCO2capturewaspreparedbycoatingPebax1657solutiononpolyacrylonitrile(PAN)ultrafiltrationmembrane.Ethanol/watermixturewasusedasthesolventofPebaxandtheeffectsofethanol/watermassratiosandPebaxconcentrationonthepermeationpropertiesofcompositemembranewerestudied.Toenhancethecompositemembranepermeance,thegutterlayer,madefromreactiveaminosiliconecrosslinkingwithpolydimethylsiloxane(PDMS),wasdesigned.Theinfluenceofcrosslinkingdegreeofthegutterlayeronmembraneperformancewasinvestigated.Asaresult,aPebax/aminoPDMS/PANmultilayermembranewithhexaneresistancewasdeveloped,showingCO2permeanceof350GPUandCO2/N2selectivityover50.Theblendofpolyethyleneglycoldimethylether(PEG-DME)withPebaxascoatingmaterialwasstudiedtofurtherimprovethemembraneperformance.AfterbeingcombinedwithPEG-DMEadditive,CO2permeanceofthefinalPebax-PEG-DME/amino-PDMS/PANcompositemembranereached400GPUabovewithCO2/N2selectivityover65.
简介:Weprovideanewclassofinteriorsolutionofa(2+1)-dimensionalanisotropicstarinFinchandSkeaspacetimecorrespondingtotheBTZblackhole.WedevelopthemodelbyconsideringtheMITbagmodelEOSandaparticularansatzforthemetricfunctiongrrproposedbyFinchandSkea[M.R.FinchandJ.E.F.Skea,Class.Quantum.Grav.6(1989)467].Ourmodelisfreefromcentralsingularityandsatisfiesallthephysicalrequirementsfortheacceptabilityofthemodel.
简介:MoleculardynamicssimulationsareperformedtostudythegrowthmechanismofCH4-CO2mixedhydrateinxCO2=75%,xCO2=50%,andxCO2=25%systemsatT=250K,255Kand260K,respectively.OursimulationresultsshowthatthegrowthrateofCH4-CO2mixedhydrateincreasesastheCO2concentrationintheinitialsolutionphaseincreasesandthetemperaturedecreases.Viahydrateformation,thecompositionofCO2inhydratephaseishigherthanthatininitialsolutionphaseandtheencagingcapacityofCO2inhydratesincreaseswiththedecreaseintemperature.ByanalysisofthecageoccupancyratioofCH4moleculesandCO2moleculesinlargecagestosmallcages,wefindthatCO2moleculesarepreferablyencagedintothelargecagesofthehydratecrystalascomparedwithCH4molecules.Interestingly,CH4moleculesandCO2moleculesfrequentlyreplacewitheachotherinsomeparticularcagesitesadjacenttohydrate/solutioninterfaceduringthecrystalgrowthprocess.Thesetwospeciesofguestmoleculeseventuallyacttostabilizethenewlyformedhydrates,withCO2moleculesoccupyinglargecagesandCH4moleculesoccupyingsmallcagesinhydrate.
简介:Inthispaper,weareconcernedwiththeglobalexistenceandconvergenceratesofthesmoothsolutionsforthecompressiblemagnetohydrodynamicequationswithoutheatconductivity,whichisahyperbolic-parabolicsystem.TheglobalsolutionsareobtainedbycombiningthelocalexistenceandaprioriestimatesifH3-normoftheinitialperturbationaroundaconstantstatesissmallenoughanditsL1-normisbounded.Aprioridecay-intimeestimatesonthepressure,velocityandmagneticfieldareusedtogettheuniformboundofentropy.Moreover,theoptimalconvergenceratesarealsoobtained.
简介:Wereportedabifunctionalmaterial,Cr-salenimplantedconjugatedmicroporouspolymer(Cr-CMP),whichisabletocaptureexcellentCO2amountsandhasaremarkablecatalyticactivitytowardsthecycloadditionreactionofCO2toepoxidesformingcycliccarbonatesatmildconditionswithoutadditionalsolvents.ThisheterogeneousCr-CMPcatalysthasasuperiorcatalyticactivitytoitsrelatedhomogeneouscatalystandcanbereusedmorethantentimeswithoutasignificantdecreaseincatalyticactivity.
简介:Nano-sizedhexagonalmagnesiumhydroxide(Mg(OH)2)withgooddispersibilitywassynthesizedbyadoubleinjection-hydrothermalmethod,utilizingpolyvinylpyrrolidone(PVP)asanadditiveandwithoptimizedprocessingparameters.SEMandBETanalysisshowedthatthemeanparticlesizeandspecificsurfaceareaoftheMg(OH)2particleswere174nmand50.77m2/g,respectively.TheFT-IRspectraandtheXRDpatternsshowedthatPVPwasadsorbedonthesurfaceoftheMg(OH)2crystal,thuseffectivelylimitingparticleagglomerationandhinderingcrystalgrowthalongthe(101)plane.TGAshowedadecreaseinthedecompositiontemperatureandanincreaseintheweightlossoftheMg(OH)2particlesduetoadditionofPVP.
简介:研究目的:研究新型磁性回热填料Gd2O2S对液氦温区高频脉管制冷机多级回热器损失特性的影响。创新要点:确定了不同回热填料以及运行参数(频率、平均压力)下液氦温区多级脉管制冷机的制冷温度和各级预冷量,进一步明确了4K高频回热损失机理。研究方法:采用理论研究与实验验证相结合的方法,基于一台两级G-M型低频脉管制冷机预冷的单极斯特林型高频脉管制冷机,研究多级回热器在高频以及4K温区下的损失特性。选取新型回热填料Gd2O2S替代部分回热填料HoCu2,比较回热器采用两种填料时在不吲运行频率及平均压力下的冷端制冷温度(图10)、各级预冷量和预冷温度(图1112)。重要结论:采用孔隙率较小的新型磁性回热填料Gd2O2S可显著改善第一级回热器内压力波与质量流的相位关系,从而减小该级回热损失。减小平均压力可以降低制冷机无负荷制冷温度并减小第二级预冷量,但制冷工质氦的体积比热容会急剧增大,从而使低温级回热器的换热对频率非常敏感。此外,频率对高温级回热器的回热特性影响不明显。该方法可以为三级斯特林型4K多级脉管制冷机提供设计依据。
简介:Westudytheoreticallyhowtoproduceanddetecttheultracoldground-stateCs2moleculefromFeshbachstate.Nu-mericalcalculationsareperformedbysolvingthequantumLiouvilleequationbasedonmultilevelBlochmodel.Theproducingefficiencyreaches55%andthedetectingefficiencyis31%.TheproducinganddetectingefficienciesarecloselyrelatedtotheRabifrequenciesoflaserpulses.Thedecayofrelevantelectronicandvibrationalstatesobviouslyreducestheproducinganddetectingefficiencies.
简介:WediscussthenonlinearSchrdingerequationwithvariablecoefficientsin2Dgraded-indexwaveguideswithdifferentdistributedtransversediffractionsandobtainexactbrightanddarksolitonsolutions.Basedonthesesolutions,wemainlyinvestigatethedynamicalbehaviorsofsolitonsinthreedifferentdiffractiondecreasingwaveguideswiththehyperbolic,GaussianandLogarithmicprofiles.Resultsindicatethatforthesameparameters,theamplitudeofbrightsolitonsintheLogarithmicprofileandtheamplitudeofdarksolitonsintheGaussianprofilearebiggestrespectively,andtheamplitudeinthehyperbolicprofileissmallest,whilethewidthofsolitonshastheoppositecase.
简介:Underinvestigationinthispaperisa(3+1)-dimensionalvariable-coefficientKadomtsev–Petviashviliequation,whichdescribesthepropagationofsurfaceandinternalwaterwaves.ByvirtueofthebinaryBellpolynomials,symboliccomputationandauxiliaryindependentvariable,thebilinearforms,solitonsolutions,B¨acklundtransformationsandLaxpairareobtained.Variablecoefficientsoftheequationcanaffectthesolitonicstructure,whentheyarespeciallychosen,whilecurvedandlinearsolitonsareillustrated.Elasticcollisionsbetween/amongtwoandthreesolitonsarediscussed,throughwhichthesolitonskeeptheiroriginalshapesinvariantexceptforsomephaseshifts.
简介:Siliconcarbidefiber/siliconcarbidematrix(SiCf/SiC)compositesareofinterestasafuelcladdingandstructuralmaterialindesignsofadvancednuclearreactorduetotheirsuperiorthermo-mechanicalpropertiesandstabilitiesandlowcross-sectionforneutroncaptureunderthesevereserviceenvironmentincludinghightemperatureandhighenergyneutronbombardment.SiCf/SiCcompositionsconsistsofSiCfiberandSiCmatrixwhichexistinwellover100polymorphsdependentonthevariedstackingofSi-Cclose-packedatomicplanes,2H-SiC,4H-SiC,6H-SiC,3C-SiC,15R-SiC,etc.EnergeticHeatomscanbecreatedandaccumulatedvianuclearreactions.HeatomsagglomerateandcoarsenintoHebubblesandcandeterioratestructuralpropertiesbyinducingcrackandcreep.Inthisexperiment,thedamageofn-type4H-SiCwafers(researchstandard,suppliedbytheCreeResearchInc.)withathicknessof0.38mmimplantedwith100keVHe+toafluenceof31016He+/cm2andpost-implantation-annealedbehavioratdifferenttemperaturewerestudiedusingRamanscatteringspectroscopy.