简介:Theabinitiomolecularorbitalmethodisemployedtostudytheenantioselectivereductionofacetophenonewithboranecatalyzedbythiszolidino[3,4-c]oxazaborolidine.Computationresultshowsthatthecontrollingstepforthereductionisthedecompositionofthecatalyst-alkoxyboraneadductandthereductionleadstoS-alcohols.ThetransitionatateofthehydridetransferfromtheboranemoietytothecarbonylcarbonofacetophenoneisatwistedchairstructurewithaB(2)-N(3)-BBH3-HBH3-CCo-OCO6-memberedring.
简介:LetM^nbeaclosedspacelikesubmanifoldisometricallyimmersedindeSitterspaceSp^(n+p)(c),DenotebyR,HandSthenormalizedscalarcurvature,themeancurvatureandthesquareofthelengthofthesecondfundamentalformofM^n,respectively.SupposeRisconstantandR≤c.ThepinchingproblemonSisstudiedandarigiditytheoremforM^nimmersedinSp^(n+p)(c)withparallelnormalizedmeancurvaturevectorfieldisproved.Whenn≥3,thepinchingconstantisthebest.Thus,themistakeofthepaper“Space-likehypersurfacesindeSitterspacewithconstantscalarcurvature”(seeManusMath,1998,95:499-505)iscorrected.Moreover,thereductionofthecodimensionwhenM^nisacompletesubmanifoldinSp^(n+p)(c)withparallelnormalizedmeancurvaturevectorfieldisinvestigated.
简介:IntroductionInthepastseveralyears,muchresearchworkhasbeendoneforthesynthesisofC-fusedbicyclo-β-lactamcompoundsandaconcise“DoubleAnnulation”procedurehasbeendeveloped.Theβ-lactamringisformedbytheclassicalStaudingerreaction[1—3]betweenα-(alkylthio)acylchlorideandanequivalentα,β-unsaturatedimine.Thesulfurringissubsequentlyfusedontotheβ-lactamunitbymeansofahalogen-promotedheterocyclizationprocess[4—6].ThisprocedurewasappliedtothesynthesisofpenemasillustratedinFig.1.TheobtainedX-penemsareakindofimportantintermediatesforsynthesizingaseriesofβ-lactamcompounds,forexample,theyarecarboxylatedbycouplingreactionsontheCatomwhichislinkedtohalagen,formingpenem[7].Animportantpurposeintheresearchfieldistoprobeintonewβ-lactammedicines.
简介:HKq一,p(w1,w2)并且HKq一,p(w1,w2)C-Z类型的固定单个不可分的操作员被证明。
简介:本文利用四元数矩阵的广义Frobenius范数建立一个关于四元数矩阵的实函数,并讨论了它的极值问题.然后在四元数矩阵方程AX-YB=C的解集合中导出了与给定矩阵的最佳逼近解的表达式.
简介:采用光电法研究炸药反应区结构的实验装置如图1所示,炸药装置用平面波透镜起爆。为了屏蔽炸药爆轰发光,在炸药样品和窗口材料氯仿之间用0.01mm厚的铜箔隔开。然后用硅油将铜箔紧紧地贴在被测样品的表面,其目的是避免炸药样品与铜箔之间有空气隙存在,以免其影响测试精度。为了防止氯仿的渗漏,在铝套筒和炸药样品之间用真空油脂密封。光纤一端直接插入装置之中,另一端和高温计的各通道相连。炸药爆轰后,在透明液体氯仿中产生冲击波,在冲击波作用下液体发光,光纤和光电倍增管将光信号转变为电信号,记录在示波器上,计算得到氯仿中的冲击波温度随时间的变化曲线。
简介:Tris)(η5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosylclusterwasobtainedfromthereactionofcyclopentadienyldicarbonylirondimerwithnitrogenmonoxideinxylene.Theclusterwascharacterizedbyelementalanalyses,IR,MSand1HNMR.Thecrystalstructureof[(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8OwasdeterminedbyX-raydiffractionanalysis.ItcrystallizesintheorthorhombicspacegroupPnma,a=9.053(2),6=10.545(2),c=22.525(4)A,V=2150.3(7)A3,Z=4,Dc=1.68g.cm-3;structuresolutionandrefinementbasedon1141reflectionswithI>3.0(I)(MoKa,A=0.71073A)convergedatR=0.0540.Theinfraredabsorptionbandat1325cm-1oftheμ3-NOinthecluster,whichisredshifted,showsthatμ3-NOisactivated.