简介:Organicmultiplequantumwells(OMQWs)consistingofalternatinglayersoforganicmaterialshavebeenfabricatedfromtris(8-hdroxyquinoline)aluminum(Alq)and2-(4-biphenylyl)-5-(4-tertbutylphenyl)-1,3,3-oxadiazole(PBD)byamultisource-typehigh-vacuumorganicmoleculardeposition.Fromthesmall-angleX-raydiffractionpatternsofAlq/PBDOMQWs,aperiodicallylayeredstructureisconfirmedthroughtheentirestack.TheAlqlayerthicknessintheOMQWswasvariedfrom1nmto4nm.Fromtheopticalaborption,photoluminescenceandelectroluminescencemeasurements,itisfoundthattheexcitonenergyshiftstohigherenergywithdecreasingAlqlayerthickness,ThechangesoftheexcitonenergycouldbeinterpretedastheconfinementeffectsofexcitonintheAlqthinlayers.Narrowingoftheemissionspectrumhasalsobeenobservedfortheelectroluminescentdevices(ELDs)withtheOMQWsstructureatroomtemperature.
简介:Thenear-ultraviolet(n-UV)excitedblue-emittingSr2MgSi2O7:Eu2+phosphorsareusedforfluorescencelampandtricolorwhiteLEDs.Theeffectofnitrogen-dopedonthestructureofthehostandtheenhancementofphotoluminescenceisexperimentallyinvestigated.Theresultsshowthatastheamountofnitrogen-dopedvariesfrom0to0.6(at.),theluminousintensityisfoundtobeincreasedto169%,andthepartialreplacementofObyNresultsinachangeofthecrystalfieldbymodifyingthesymmetryofthecrystalstructure.Asaresult,withthenitrogen-dopedinsmallamount,theluminousintensity,chromaticitycoordinatesandthecolorpuritycanbeadjustedtoadesiredvalueintheapplications.