简介:ThesusceptibilityofweldedjointfortheX65pipelinesteeltoH2Sstresscorrosioncracking(SCC)isinvestigated.SCCtestsonthesteelarecarriedoutintheenvironmentbasedonNACETM-01-77solutionwithsaturatedgaseousH2S.Thethresholdstressintensityfactorandcrackpropagationvelocityarecalculatedaccordingtowedge-openingloading(WOL)specimens.Thethree-dimensionalelastic-plasticfiniteelementanalysisofWOLspecimensisperformedbyusingtheFEMprogrammingpackageANSYS.Stressfieldandconcentrationofhydrogendistributionpropertyaheadofthecracktipareobtained.ThispapersurveyedthemicrostructureofweldedjointandstudiedonthemechanicalpropertiesofX65pipelinesteel.Itprovidesexperimentalbasisforstudyingstresscorrosion.Theresultsofnumericalanalysisareconsistentwithconclusionsofstresscorrosiontest.
简介:Anewseriesofrareearthcompounds,Y2-xErxMo4O15(x=0.0-2.0),weresynthesizedandtheirstructuresweredeterminedbypowderX-raydiffraction(XRD).RietveldanalysisofXRDpatternsrevealsthatthecompoundsofthisseriescrystallizeinmonoclinicsystemwithspacegroupP21/c.Thelatticeparametersa,b,c,βandtheunitcellvolumeVde-creaselinearlywithincreasingErcontent.Thethermalexpansionpropertiesofthesecompoundswerestudiedunderhigh-temperatureXRD.PositivethermalexpansionsofcompoundsY2-xErxMo4O15arefoundtobeanisotropicalongthethreecrystallographicdirectionswhereaandcaxesexpandwhilebaxiscontractsinthewholetemperaturerange.Byanalysisofdata,theexpansionofweakbandMo2-O14withrisingtemperatureshouldberesponsibleforpositivethermalexpansion.
简介:Mgx(Ti0.9Zr0.2Mn1.5Cr0.3)(x=20%,30%,40%)(集体部分)合成粉末被反应的球milling与氢和他们的氢存储性质准备,微观结构被XRD,SEM和pressure-composition-temperature调查测量。结果证明composites在553K和好加氢动力学有3.83%-5.07%氢能力,甚至在房间温度。在他们之中,milledMg-30%(Ti0.9Zr0.2Mn1.5Cr0.3)合成当它能快速在373K吸收2.1%氢,有最高的加氢动力学,3.5%在在473K的2000s,在3MPa氢压力下面在553K在60s弄平3.26%。改进加氢性质来自粒子在Mg粒子的表面上一致地驱散的Ti0.9Zr0.2Mn1.5Cr0.3的催化效果。
简介:本文采用扫描振动微电极和局部电化学交流阻抗谱测试了近中性pH环境中X70管线钢平滑试样及裂纹尖端发生的局部溶解电化学行为,用来确定并量化应力和氢以及它们对阳极溶解的协同作用在裂纹扩展中的作用。研究结果表明,外加拉伸应力能够提高管线钢的阳极溶解速度,应力较小时,应力加速溶解并不明显;应力提高到80%屈服强度时,管线钢的阳极溶解速度显著提升。裂纹或者裂纹状缺陷的存在会引起应力集中因而会导致加速局部阳极溶解速度。当预制裂纹CT试样受到3000N拉力时,裂尖的应力影响阳极溶解因子高达3.6,而低应力区域只有1.10。近中性pH环境中氢与应力对管线钢在的阳极溶解的联合作用,这对裂纹的扩展起到了决定性的作用。受到525MPa应力的平滑试样在不同电流密度0.1mA/cm^2,1mA/cm^2,5mA/cm^2,10mA/cm^2和20mA/cm^2充氢后,氢与应力对阳极溶解的协同影响因子,分别是1.048,1.668,2.568,3.976和5.437。
简介:PolycrystallinesamplesofLa12x(Sr12yAgy)xMnO3(y=0.0,0.2,0.4,0.6,1.0)werepreparedbythesolid-statereactionmethod.ThetemperaturestabilityofmagnetoresistanceandmagnetoresistanceenhancementinLa1-x(Sr1-yAgy)xMnO3systemwithbothunivalentandbivalentelementsdopedatAsiteandwithunchangedvalueofMn3+/Mn4+ratiowereexploredthroughthemeasurementsofX-raydiffractionpatterns,magnetiza-tion-temperature(M-T)curves,resistivity-temperature(q-T)curvesandmagnetoresistance-temperature(MR-T)curves.Theresultsareasfollows:therearetwopeaksintheq-TcurvesofthesampleswithAgdoping,oneiscausedbyresistancechangeduringtheparamagnetism-ferromagnetismtransition,andtheotherisfromboundary-dependentscatteringofconductionelectronsontheboundariesofgrains.ThepeakvalueofMRincreaseswithincreasingAgdopingcontent,anditincreasesfrom8.2%fory=0.2to29.6%fory=1.0underthemagneticfieldofB=0.8T;MRremainsaconstantof12%inthetemperaturerangeof218-168Kforthesamplewithy=1.0,andthetemperaturestabilityofMRisinfavorofthepracticalapplicationofMR.
简介:TheagingbehaviorofAl-Cu-Mg-AgalloyswithhighCu/Mgwasstudiedbytransmissionelectronmicroscopy(TEM)andsmall-angleX-rayscattering(SAXS)usingsynchrotronradiation.TEMstudyrevealsthatthemajorstrengtheningphasesofthealloyafteragingat160?Cfor10hareΩandlessθ′.SAXSstudyshowsthatthescatteringpatternsarecomposedofseveralconcentriccirclesatthebeginningofagingprocess,whichisreplacedbythebutterfly-wingsscatteringpatternswiththeincreaseofagingtime...
简介:采用SEM、TEM、EDS、DSC、XRD和拉伸实验研究铸态7X50合金及其均匀化处理过程的组织演变。结果表明,铸态7X50合金相组成主要有S(Al2CuMg)、T(Al2Mg3Zn3)、MgZn2和少量的Al7Cu2Fe和Al3Zr相。均匀化处理过程中枝晶网和残留相逐渐减少,经(470°C,24h)+(482°C,12h)均匀化处理时,T相消失,S相有微量残留,Al7Cu2Fe相几乎没有变化。铸态合金的DSC曲线中在477.8°C处有一较强吸热峰,经470°C、1h均匀化后合金的DSC曲线在487.5°C处出现一个新的吸热峰,而经482°C、24h均匀化处理后合金在487.5°C处的吸热峰基本消失。在XRD谱中未出现T(Al2Mg3Zn3)相,这和T相与S(Al2CuMg)及MgZn2相相关的结论相吻合。预均匀化处理制备的板材中再结晶晶粒分数明显降低,抗拉强度和断裂韧性相对常规均匀化处理制备的板材分别提高约15MPa和3.3MPa·m1/2。
简介:ThestructureandelectrochemicalpropertiesofanewlowcobalthydrogenstorageelectrodealloysLa1-xLixNi3.2Co0.3Al0.3(0≤x≤0.2)wereinvestigatedwithadifferentadditionsofLiinreplacementofLa.WiththeincreaseofLicontentsthemaximumdischargecapacityincreasesfrom240mAh·g-1(x=0)to328.4mAh·g-1(x=0.1)andthecyclestabilityisimprovedcorrespondingly.ThecapacitydecaycanremaiN28.6%(x=0.2)after230charge/dischargecycles.Thehighratedischarge(HRD)abilityofthealloys(x≤0.1)isimprovedandthebestHRDis34.1%(x=0.1)underthedischargecurrentdensity1200mA·g-1.ItisfoundthatthepreparedalloysarebasicallycomposedofLaNi5asmatrixphaseandLaNi3assecondphase(x≤0.1).ButtheabundanceofLaNi3phasedramaticallydecreaseswithincreasingx.Whenx=0.2,anewphaseAl(NiCo)3isformed.
简介:基于微观相场模型,通过分析Ni75AlxV25-x合金在沉淀过程中D022(Ni3V)相沿[001]方向形成的有序畴界面的界面结构、界面迁移及界面成分,研究界面结构对界面迁移特征和溶质偏聚的影响。研究表明:D022相沿[100]方向形成4种有序畴界,界面的迁移性与界面结构有关,除具有L12相的局部特征的界面(001)//(002)之外,其余3种界面都可以迁移;在界面的迁移过程中,V原子跃迁至最近邻的Ni位置并置换Ni原子,反之亦然,即处在最近邻的Ni原子和V原子发生位置交换而导致界面迁移;在迁移过程中,原子的跃迁行为具有位置选择性,每种可迁移界面都按照特定的原子跃迁模式进行迁移;原子在跃迁过程中选择最优化的路径使得界面发生迁移,原子跃迁过程中的位置选择性使得界面在迁移前、后的结构保持不变;合金元素在界面处具有不同的贫化和偏聚倾向,在所有的界面处,Ni偏聚而V贫化,Al在界面(001)//(001)·1/2[100]处贫化在其他界面处偏聚;同种合金元素在不同界面处的偏聚和贫化程度不同。