简介:TheeffectofMnsubstitutionforpartialFeinRFe11Tionstructureandmagneticpropertiesofcompoundswasresearched.RFe7Mn4Tisamples(R=Y,Tb,Dy,Ho,Er)werepreparedbymeansofvacuumarc-meltingandsubsequentvacuumannealing.ThestructureandmagneticpropertiesofRFe7Mn4TicompoundswereinvestigatedbyX-raypowderdiffractionandmagneticmeasurements.Thefollowingconclusionswereobtained:alltheRFe7Mn4TicompoundscrystallizeintheThMn12-typestructure.Thelatticeconstantsandtheunit-cellvolumechangedwiththeincreaseofatomicnumberforR=Y,Th,Dy,Ho,andEr.ThecompensationcharactersappearfortheDyFe7Mn4TiandHoFe7Mn4Ticompounds,andthecompensationtemperatureswereabout123Kand90K,respectively.TheCurietemperature,thesaturationmagnetization,andsaturationmomentofRFe7Mn4Ticompoundsweregiven.
简介:以某热力管网首站的换热器为研究对象,采用西门子两个S7-200PLC的主从结构的方式来解决PLC外部I/O端子较多的问题,并采用Eview5000触摸屏作为系统上位机,利用PIDTuneControlPanel实现了对四个换热器的温度控制,具有手动/自动两种控制方式,其控制精度达到了预定的要求,且系统成本低廉、界面友好、控制灵活。
简介:合成了一种未见报道的标题化合物((C5N2H6)3(C5N2H7)3[(PO4)Mo12O36]·2H2O,Mr=2403.00)并得到单晶,晶体衍射实验发现其属于单斜晶系,P2(1)/n空间群,晶体学参数:a=13.316(3),b=22.414(5),c=20.063(4),α=90.00(4)°,β=100.743(3)°,γ=90.00°,V=5883(2)3,Z=4,Dc=2.713Mg/m3,μ(MoKα)=2.608mm-1,F000=4604,最终R=0.0596,wR=0.1345,GoF=1.042.配体由由簇阴离子[(PO4)Mo12O36]3-之间通过端基氧与2-氨基吡啶形成氢键而相互连接,中间填充了一些水分子及2-氨基吡啶.