简介:AnewlayeredCu-basedoxychalcogenideBa3Fe2O5Cu2S2hasbeensynthesizedanditsmagneticandelectronicpropertieswererevealed.Ba3Fe2O5Cu2S2isbuiltupbyalternativelystacking[Cu2S2]2-layersandironperovskiteoxide[(FeO2)(BaO)(FeO2)]2-layersalongthecaxisthatareseparatedbybariumionswithFe3+fivefoldcoordinatedbyasquare-pyramidalarrangementofoxygen.Fromthebondvalencearguments,weinferredthatinlayeredCuCh-based(Ch=S,Se,Te)compoundsthe+3cationinperovskiteoxidesheetprefersasquarepyramidalsite,whilethelowervalencecationprefersthesquareplanarsites.Thestudiesonsusceptibility,transport,andopticalreflectivityindicatethatBa3Fe2O5Cu2S2isanantiferromagneticsemiconductorwithaNe′eltemperatureof121Kandanopticalbandgapof1.03eV.Themeasurementofheatcapacityfrom10Ktoroomtemperatureshowsnoanomalyat121K.TheDebyetemperatureisdeterminedtobe113K.TheoreticalcalculationsindicatethattheconductionbandminimumispredominantlycontributedbyO2pand3dstatesofFeionsthatantiferromagneticallyarrangedinFeO2layers.TheFe3dstatesarelocatedatlowerenergyandresultinanarrowbandgapincomparisonwiththatoftheisostructuralSr3Sc2O5Cu2S2.
简介:摘要目的分析皮肤激光美容治疗的综合护理价值。方法将2015年1月到2015年12月期间在本院接受皮肤激光美容治疗的58例患者作为研究对象,将患者按照个人意愿划分为观察组和对照组各29例。对照组采用常规护理干预模式,观察组采用综合护理干预模式,对比两组患者的临床护理满意度及不良反应发生情况。结果观察组患者的临床护理满意度为96.55%(28/29),对照组患者满意度为82.76%(24/29);观察组患者不良反应发生率为3.45%(1/29),对照组患者不良反应发生率为13.79%(4/29),两组之间差异对比具有统计学意义(p<0.05)。结论综合护理模式在皮肤激光美容治疗中的应用,有助于提升临床护理的总体质量,降低患者不良反应发生率,增强患者的护理综合满意度。
简介:研究了自锁阀激光焊接焦点位置与焊缝熔深之间的关系、焊接速度和激光功率与焊缝熔深之间的关系,分析了随着激光功率增加,不同焦点位置的焊接过程依次经历稳定热导焊,热导焊、深熔焊交替进行的不稳定焊接和稳定深熔焊接三种模式,进而研究了稳定焊接模式下工艺参数与焊缝熔深之间的关系,得出了自锁阀在稳定焊接模式下的最佳焊接工艺规范参数。采用该激光焊接工艺规范焊接的常压和高压自锁阀焊缝外观质量、气密、液压以及焊缝氦质谱检漏试验结果全部满足设计要求。常压和高压自锁阀已经应用于嫦娥五号、探月工程、东风导弹武器系统、货运飞船、921-3推进分系统、东方红三号等推进系统的液体火箭发动机之中。
简介:摘要目的本文就NdYAG激光联合532激光治疗原发性闭角型青光眼的临床前期疗效进行观察与探究。方法选自我院眼科从2014年11月至2015年12月期间收治的原发性闭角型青光眼患者60例,依据随机数字表法将其平均分为参照组(n=30)和实验组(n=30)。实验组患者予以NdYAG激光联合532激光治疗,参照组患者予以NdYAG激光治疗,最后比对临床治疗效果。结果两组患者通过不同治疗方法得出结果,实验组患者的一次激光穿孔成功率高于参照组,并发症发生率同参照组进行对比,前者明显较低,且组间比较后差异呈正相关。结论在原发性闭角型青光眼治疗中应用NdYAG激光联合532激光,疗效确切,同时降低并发症发生率,具有临床应用价值。
简介:Inordertodeepentheunderstandingoftherelationshipbetweenfundamentalproperties(including:microstructureandcomposition)andphotocatalyticperformance,fourbismuthatecompounds,including:LiBiO3,NaBiO3,KBiO3,andAgBiO3,areregardedasresearchexamplesinthepresentwork,becausetheyhaveparticularcrystalstructuresandsimilarcompositions.Usingdensityfunctionaltheorycalculations,theirstructural,electronic,andopticalpropertiesareinvestigatedandcomparedsystematically.Firstofall,thecalculatedresultsofcrystalstructuresandopticalpropertiesareinagreementwithavailablepublishedexperimentaldata.Basedonthecalculatedresults,itisfoundthatthetunneledorlayeredmicro-structuralpropertiesleadtothestrongerinteractionbetweenbismuthandoxygen,andtheweakerinteractionbetweenalkaline-earthmetaland[BiO6]octahedron,resultinginthefeatureofmulti-bandgapsinthecasesofLiBiO3,NaBiO3,andKBiO3.ThisconclusionissupportedbythecaseofAgBiO3,inwhichthefeatureofmulti-bandgapsdisappears,duetothestrongerinteractionbetweenthenoblemetaland[BiO6]octahedron.Thesepropertieshavesignificantadvantagesinthephotocatalyticperformance:absorbinglowenergyphotons,rapidlytransferringenergycarriers.Furthermore,thefeaturesofelectronicstructuresofbismuthatecompoundsarewellreflectedbytheabsorptionspectra,whichcouldbeconfirmedbyexperimentalmeasurementsinpractice.Combinedwiththecalculatedresults,itcouldbeconsideredthatthecrystalstructuresandcompositionsofthephotocatalystdeterminetheelectronicstructuresandopticalproperties,andsubsequentlydeterminethecorrespondingphotocatalyticperformance.Thus,anovelBi-basedphotocatalystdrivenbyvisible-lightcouldbedesignedbyutilizingspecificcompositionstoformfavorableelectronicstructuresorspecificmicro-structurestoformabeneficialchannelforenergycarriers.
简介:本文介绍了低温(-50℃)乙烯球罐制造和焊接技术,制定了球罐制造工艺流程和球壳板成形工艺,通过试验确定了焊接预热温度、层间温度和后热温度,并正确选择了焊接材料。制定了乙烯球罐的焊接工艺规范,并成功地完成了低温(-50℃)乙烯球罐的制造和焊接。
简介:Aterahertzexcitationsourcebasedonadual-lateral-modedistributedBraggreflector(DBR)laserworkinginthe1.5μmrangeisexperimentallydemonstrated.Byoptimizingthewidthoftheridgewaveguide,thefundamentalandthefirst-orderlateralmodesareobtainedfromthelaser.Themodespacingbetweenthetwomodesis9.68nm,correspondingtoabeatsignalof1.21THz.BytuningthebiascurrentsofthephaseandDBRsections,thewavelengthsofthetwomodescanbetunedby2nm,withasmallstrengthdifference(<5dB)andalargeside-modesuppressionratio(SMSR>45dB).
简介:证券综合指数的对数收益率的折线图反映收益率的波动呈现出在一段时间内波动比较大,一段时间波动比较小,方差随着时间的变化而变化。在对时间序列数据进行研究的时候,通常假设随着时间的变化方差不会发生变化。但是在关注预测的精确程度时,需要了解方差的大小。文章用Eviews软件对上证综指日收盘价的对数收益率建立EGARCH-M模型,对收益率序列呈现出的波动聚集性,杠杆效应、风险与收益的关系等特征进行了分析,最终对波动率进行预测,结果表明EGARCH-M模型充分描述了波动性聚类的特点,只用很少的参数就可以把实际数据拟合得很好。该模型形式简单,容易估计,提高了对方差的预测精度,对收益率波动率建立模型对于宏观经济理论和金融理论有重要的意义。