简介:Amathematicalmodelforthethree-dimensionalsimulationoffreedendriticgrowthandmicrostructureevolutionwasdevelopedbasedonthegrowthmechanismofcrystalgrainsandbasictransferequationssuchasheat,massandmomentumtransferequations.Manyfactorsincludingconstitutionalundercooling,curvatureundercoolingandanisotropy,whichhadvitalinfluencesonthemicrostructureevolution,wereconsideredinthemodel.SimulatedresultsshowedthatfinalmicrostructuralpatternsandfreedendriticgrowthcouldbepredictedreasonablyandcalculatedresultswerecoincidentwithexperimentalThesimulatedresultsoffreedendriticgrowthindicatedthatthestrengthofanisotropyhassignificanteffectsonfreedendriticgrowth,dendriteprofile,microsoluteandtemperaturedistribution.Thedendriticgrainprofileswithfully-grownparallelsecondaryarmtendtobeformedattheintensiveanisotropy,whilenearoctahedralgrainprofileswithsmallprotuberancesofsurfaceatlowstrengthofanisotropy.Thesimulatedresultsoffreedendriticgrowthalsoindicatedthattherearesmallmoltenpoolsleftininterdendriticareas.Thisishelpfultounderstandthefundamentaloftheformationofmicrostructurerelateddefectssuchasmicrosegregationandmicroporosity.
简介:Thevolatilizationkineticsofantimonytrisulfideinsteamatmospherewasstudiedwiththermogravimetryattemperaturesfrom923to1123K.Atheoreticalmodelwasdevelopedtocalculatetheoverallrateconstantandthemasstransfercoefficientingasphases.Theexperimentalresultsshowthatthevolatilizationrateisenhancedwithincreasingtemperatureandsteamflowrate.Thevolatilizationrateismainlycontrolledbythemasstransportingasphases.Theapparentactivationenergyfortheprocessisfoundtobe59.93kJ/mol.ItisdemonstratedthatSb2S3isdominantlyoxidizedintoSb2O3andH2Sbywatervaporinthevolatilizationprocess.Someantimonymetalisformed.Thereactionmechanismisdiscussedinaccordancewithexperimentaldata.
简介:Throughmeasuringthecoefficientoflinearexpansion,thestructureandpropertiesoftheLi2O-Al2O3-SiO2lowexpansionglassceramicscontainingB2O3arestudiedbyJRandXRD.ItisshoutnthattheIRmethodisefficientinthestudyoftheglass-ceramicsstructure.Thereisa"Boronabnormality"inthesystemwhichhasanimportantinfluenceonthepropertiesoftheglass-ceramics.
简介:Eu(TTA)4CsHsNC16H33(TTA:1-(2-Thenoy)-3,3,3-Trifluoracetate)isencapsulatedinSi-MCM41modifiedwithN-(3-Trimethoxysilethyl)ethylenediamine.Theemissionspectrumoftheassemblyshowsonlya5D0→7F2transition.Ascomparedwiththerareearthcomplexitself,thelifetimeoftheassemblybecomeslongeranditsstabilityundertheUVradiationismuchbetter.
简介:结果证明Mg在空间在钢的张力的性质和坚硬上有更少的效果温度,而是Mg的正确数量改进影响和破裂坚韧并且减少破裂转变温度更加由于包括修正,象一样通过加强谷物边界并且修改边界碳化物戏剧性地延长槽口压力破裂生活。有一个最佳Mg内容,它在试验性的35CrNi3MoV钢是大约0.0030%。(编辑作者摘要)8个裁判员。
简介:Howtocontrolmeltcompositionisthekeyforgettinghighqualityalloymelt.Thepapermadethefollowingefforts:(1)TheactivitycoefficientsinTi-15-3melthavebeencalculated.(2)Takingadvantageoftheactivitycoefficients,theevaporationlossesofcomponentsinTi-15-3meltduringISMprocesshavebeenstudied.Thecalculatedresultsshowthatthereisacriticalvacuumdegree(about1.33Pa)duringmeltingprocess.
简介:Si3N4/TiCnanocompositeceramicshavebeenfabricatedbyhotpressingtechniquewithAl2O3andY2O3asadditives.TheresultsshowedthatwelldispersedcompositepowderwascarriedoutbyaddingdispersantandadjustingpHvaluesofsuspensions.RemarkableincreaseinflexuralstrengthatroomtemperatureswasobtainedbyaddingnanoparticlesinSi3N4matrixwith10%(wtpct)ofnano-Si3N4and15%ofnano-TiC.Theflexuralstrength,fracturetoughnessandhardnesswere1025MPa,7.5MPa·1/2and15.6GPa,respectively.Themicrostructuresofmaterialswereanalyzedbyscanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM),whichindicatedthatTiCnanoparticlesdistributeinthematrixandatthegrainboundaries.Accordingtothefractureform,lowcontentsofnanoparticlescouldrefinematrixgrainsandleadtothecrackdeflectionaswellascrackpinning.Themultiplexmicrostructurewasformedbymixingnano-Si3N4particles.Thecracktrajectoriesexhibitedcrackdeflection,rod-likegrainbridgingandpull-out.
简介:以前曾指出由3,3’,4,4’-联苯基四羧酸二酐(BPDA)和1,2-双(4-氨基苯氧基)苯(亦称三苯基醚邻苯二酚二胺(TPEC))衍生的聚酰亚胺具有优异的拉伸性能和良好的热性能。本文对由BPDA、TPEC及其它芳香族二胺制备的共聚酰亚胺的性能做了初步评价。由BPDA和各种芳香族二胺制备的均聚酰亚胺通常具有良好的机械性能和热性能。然而,它们不溶于现有的各种有机溶剂中。在某些条件下,用BPDA与等摩尔TPEC和其它芳香族二胺混合物可以制备可有机溶解的BPDA型共聚酰亚胺。这些共聚酰亚胺可以形成坚韧的薄膜,它们具有较高的模量和强度。多数情况下,也具有较高的断裂伸长率。
简介:Er^3+-dopedSrBi4Ti4O15-Bi4Ti3O12(SBT-BIT-xEr^3+,x=0.00,0.05,0.10,0.15and0.20)inter-growthceramicsweresynthesizedbythesolid-statereactionmethod.Structural,electricalandup-conversionpropertiesofSBT-BIT-xEr^3+wereinvestigated.Allsamplesshowedasinglephaseoftheorthorhombicstructure.RamanspectroscopyindicatedthattheEr^3+substitutionforBi^3+atAsitesofthepseudo-perovskitelayerincreasesthelatticedistortionofSBT-BIT-xEr^3+ceramics.ThesubstitutionofBi^3+byEr^3+leadstoadecreaseofdielectriclosstanδandanincreaseofconductivityactivationenergy.Piezoelectricconstantd33wasslightlyimproved,butdielectricconstantwasdecreasedwiththeEr^3+doping.TheSBT-BIT-xEr^3+ceramicwithx=0.15exhibitstheoptimizedelectricalbehavior(d33~17pC/N,tanδ~0.83%).Moreover,twobrightgreen(532and548nm)andonered(670nm)emissionbandswereobservedunderthe980nmexcitation.Optimizedemissionintensitywasalsoobtainedwhenx=0.15fortheSBT-BIT-xEr^3+ceramic.Therefore,thiskindofceramicsoughttobepromisingcandidatesformultifunctionaloptoelectronicapplications.