简介:Loadedonthecordierite,therareearthdopedcompositecatalystwaspreparedbysol-gelmethodcombinedwithdippingtechnique.TakingOrthodichlorobenzeneasmodel,thecatalystwasusedtoremovethedioxinsofthewastegas.Theresultsshowedthatat280℃andgasspacevelocitybeing8000h-1,theorthodichlorobenzenecouldberemovedeffectivilybythepreparedCeO2-TiO2-V2O5compositecatalystwhoseactivitywasremarkablyenhancedbythedopingofCe,whiletheindustrialside-streamtestofdioxinsfromrefuseincinerationsmokeindicatedthatthedecompositionratecouldreachabove93%underthesameconditions.
简介:采用Al-5Ti-B变质剂对过共晶Al-18Si合金进行反向变质处理,用光学显微镜观察合金的组织与形貌,研究变质剂加入量、变质温度和冷却速度对初晶硅的尺寸、形态和面积分数以及共晶组织的影响。研究表明:当Al-5Ti-B加入量(质量分数)为0.3%时,变质处理后Al-18Si合金中的初晶硅和共晶硅尺寸明显减小,初晶硅的面积分数减小;与其相比,变质剂加入量增加到0.6%时,初晶硅尺寸变化不明显,但共晶硅进一步细化;随冷却速率降低,变质处理后Al-18Si合金中初晶硅相的数量减少,但Si颗粒尺寸明显增大,并且共晶硅细化;与Al-18Si合金在720℃变质相比,该合金在780℃变质处理时,初晶硅的尺寸增大,但初晶硅的面积分数显著减小;合金在850℃变质处理后初晶硅的尺寸、面积分数都比720℃变质处理后明显减小;随变质温度升高,Al-Si合金中的共晶硅明显细化。
简介:Baosteel's5mheavyplateplantwassuccessfullytestedonMarch1,2005.Sincethen,theHeavyPlatePlantofBaosteel(hereinafterreferredtoas'theplant')hasbeenencouragingitsemployeestostudyandtracetheadvancedheavyplatetechnologies,tryingtofindouttherulesofheavyplateproductionanditsqualitycontrol.TheplanthasgraduallymasteredthismodernheavyplateplantandensuredthatBaosteel'sproductionofheavyplatesgrewyearbyyear,with1.41Mtproductputinstoragein2007.Theplanthasfocusedondevelopingnewtechnologiesandproducts,meanwhileenhancingitscapacity.Ithasproducedaseriesofplateproducts,whichcanbeusedinmanufacturingshiphulls,pipelines,bridges,buildings,boilersandpressurevessels.
简介:采用简单水热法和后续高温煅烧制备多孔结构V2O5微球,用X射线衍射仪分析V2O5微球的晶体结构,通过扫描电镜和透射电镜观察和分析微球表面形貌与微观结构。结果表明,微球为单相V2O5,呈形貌均一的多孔结构。作为锂离子电池正极材料,V2O5多孔微球电极在不同电压区间均显示出优异的电化学性能,在2.5~4.0V电压范围内,100mA/g的电流密度下,初始放电比容量达到145(mA·h)/g,接近理论值147(mA·h)/g,循环50圈后仍保持在138(mA·h)/g,容量保持率高达95.2%。此外,该电极还表现出优异的长循环稳定性,在2A/g的电流密度下循环1000圈后放电比容量保持在82.8(mA·h)/g,平均单圈比容量衰减率仅为0.022%。该材料优良的电化学性能得益于三维多孔微球结构。
简介:TheeffectofrapidsolidificationonstructureandelectrochemicalperformanceoftheLaNi4.5Co0.25Al0.25hydrogenstoragealloywasinvestigatedbyX-raypowderdiffractionandasimulatedbatterytest,includingmaximumcapacity,cyclingstability,self-discharge,andhigh-ratedischargeability(HRD).Allthemelt-spunalloysweresingle-phasewiththeCaCu5-typestructure(spacegroupP6/mmm).Incomparisontotheas-castalloy,therapidlyquenchedalloysmanifestedanimprovedhomogeneityofcompositionandexpandedlatticeparameters.Theelectrochemicalmeasurementsshowedthattheactivationproperty,cyclingstabilityandself-dischargeofthealloyelectrodeswerealsoimprovedfortherapidsolidifiedalloys.TheHRDoftheas-castalloywasbetterthanthoseofalltherapidlysolidifiedalloys.Asthequenchingrateincreased,theHRDandexchangecurrentdensityfirstdecreasedandthenincreased.
简介:采用粉末冶金法制备95W-5(Ni/Fe)合金,研究合金的力学性能,并通过扫描电镜(SEM)观察其延性断裂和脆性断裂的断口形貌。结果表明,合金有2种断裂形式,当粘结相与W颗粒界面结合良好时,发生粘结相的延性断裂和W颗粒的穿晶解理断裂,合金的强度和韧性都很高,冲击韧性、抗拉强度和伸长率分别达到29J/cm2、883MPa和10%;而粘结相与W颗粒界面结合较差,粘结相不能完全填充于W颗粒之间时,合金表现为脆性,其冲击韧性和抗拉强度分别为4.69J/cm2和596MPa,断裂前不出现塑性变形。对烧结后的95W-5(Ni/Fe)脆性合金在马弗炉内进行热处理(热处理温度为1150~1280℃,用氩气作保护气氛,保温时间0.5~2h)后,由于改变了W颗粒与粘结相之间的界面结合状态,合金断裂行为转变为延性断裂,力学性能大幅度提高。
简介:Thephasesandmagnetocaloriceffectinthealloys(Gd1-xErx)5Si1.8Ge2.2withx=0,0.1,0.2and0.3wereinvestigatedbyX-raydiffractionanalysisandmagnetizationmeasurement.ThesamplesweresinglephasewiththemonoclinicGd5Si2Ge2-typestructure.WiththeincreaseofErcontent,theCurietemperature(Tc)decreasedobviouslyfrom253Kofthealloywithx=0to114Kwithx=0.3.Themaximummagneticentropychangedinthesamplesof(Gd1-xErx)5Si1.8Ge2.2withx=0.0,0.1,0.2and0.3were6.88,8.32,9.59and10.24J·kg-1·K-1respectivelyintheappliedfieldchangeof0~2.0T.
简介:Er3+/Yb3+codopedzincateBaGd2ZnO5phosphorsweresynthesizedviaatraditionalsolidstatereaction.ThecrystalstructureandphasepuritywerecheckedbymeansofX-raydiffraction(XRD),andtheresultsshowedthatpurephaseBaGd2ZnO5phosphorswithvariousEr3+,Yb3+concentrationswereobtained.TheinfluenceofEr3+andYb3+dopingconcentrationsonthegreenandredupconversionemissionswasstudied.Itwasfoundthatbothgreenandredupconversionemissionsunder980nmexcitationweretwo-photonprocessesindependentfromtherareearthdopingconcentrations.However,theupconversionluminescenceintensitiesgreatlydependedontherareearthdopingconcentration.Furthermore,thepopulationprocessesofupconversionluminescenceandthequenchingmechanismswereanalyzed.Thetemperature-dependentgreenupconversionluminescencewasstudied,andthetemperaturequenchingprocessoftwogreenupconversionemissionswasmodeled.Thethermalquenchingprocessesofthegreenupconversionemissionscouldbewellexplainedbythemodelweproposed.