简介:以4-氨基-3-(4-甲基-1,2,3-噻二唑)-1,2,4-三唑-5-硫酮为原料,与醛在冰乙酸中回流制得15个新型4-取代亚氨基-3-(4-甲基-1,2,3-噻二唑)-1,2,4-三唑-5-硫酮化合物,其结构经IR、1HNMR及元素分析表征,其中,化合物5c的结构经单晶测试确证,该晶体属单斜晶系,P2(1)/c空间群,晶胞参数a=1.4037(3)nm,b=1.5705(3)nm,c=0.6864(14)nm,β=102.06(3)°,V=1.4798(5)nm^3,Z=4,F(000)=656。初步的抑菌活性测试结果表明;所有化合物对黄瓜灰霉病菌Botrytiscinerea都有较好的抑制作用,化合物5l的抑制率达87%,5c、5d和5f的抑制率在78%左右;5a对小麦赤霉病菌Gibberellazeae的抑制率为78.7%;5m对西瓜炭疽病菌Colletotrichumlagenarium的抑制率为65.6%。
简介:将啤酒废酵母制成一种新型的生物吸附剂,用于吸附重金属离子铜。研究了不同温度、时间、pH值,以及铜离子浓度和酵母浓度条件下,啤酒废酵母对Cu^2+的吸附能力。初步确定了啤酒废酵母对Cu^2+吸附的最佳组合,即吸附温度为35℃,吸附时间为55min,起始pH值为5,酵母的质量浓度为1g/L,Cu^2+质量浓度为22mg/L,在此条件下啤酒废酵母对Cu^2+吸附率可达到90.00%左右。通过L16(4^5)正交实验表明,Cu^2+质量浓度和pH值是影响啤酒废酵母吸附铜离子能力的显著因素。对吸附了铜离子的啤酒酵母进行解吸实验,表明在浓度为1mol/L的HCl中,其解吸率为55.00%,与1mol/L的NaOH和去离子水相比,有较高的解吸率。
简介:ForestmanagementisexpectedtoinfluencesoilCO2efflux(FCO2)asaresultofchangesinmicroenvironmentalconditions,soilmicroclimate,androotdynamics.SoilFCO2ratewasmeasuredduringthegrowingseasonof2006inboththinningandnon-thinninglocationswithinstandsrangingfrom0to8yearsafterthemostrecentthinninginChinesefir(Cunninghamialanceolata(Lamb.)Hook)plantationsinHuitongEcosystemResearchStation,Hunan,China.SoiltemperatureandmoisturewerealsomeasuredtoexaminerelationshipsbetweenFCO2andsoilproperties.ForestthinningresultedinhugechangesinFCO2thatvariedwithtimesincecutting.Immediatelyfollowingharvest(year0)FCO2inthinningareaincreasedbyabout30%,declinedto20%–27%belowpre-cuttinglevelsduringyears4–6,andrecoveredtopre-cuttinglevelsat8yearspost-cutting.Asimilartemporalpattern,butwithsmallerchanges,wasfoundinnon-thinninglocations.TheinitialincreaseinFCO2couldbeattributedtoacombinationofrootdecay,soildisturbance,andincreasedsoiltemperatureingaps,whilethesubsequentdecreaseandrecoverytothedeathandgradualregrowthofactiveroots.StrongeffectsofsoiltemperatureandsoilwatercontentonFCO2werefound.ForestthinningmainlyinfluencedFCO2throughchangesintreerootrespiration,andthenetresultwasadecreaseinintegratedFCO2fluxthroughtheentirefellingcycle.