简介:用同步辐射原位高压能散X射线衍射技术,对碳纳米管进行了结构和物性的研究,压力达50.7GPa。在室温常压下,碳纳米管的结构和石墨的hcp结构相似,其(002)衍射线的面间距为d002=0.3404nm,(100)衍射线的面间距为d100=0.2116nm。从高压X射线衍射实验看到,当压力升到8GPa以上,(002)线变宽变弱,碳纳米管部分非晶化。而当压力从10GPa或20GPa卸压至零,(002)线部分恢复。但当压力升至最高压力50.7GPa时,碳纳米管完全非晶化,而且这个非晶化相变是不可逆的。我们用Birch-Murnaghan方程拟合实验数据,得到体弹模量为K0=54.3±3.2GPa(当K’0=4.0时)。
简介:AnX-rayradiationsourcewithapproximatelyconstantradiationtemperatureisrealizedbyirradiatinggoldenhohlraumwithashapedlaserpulse.Asimpletheoreticalmodelbasedonpowerbalanceisusedtodesigntheshapeofthedrivelaserpulse.ExperimentsarecarriedoutontheShenguangIIIprototypelaserfacility,andtheexperimentalresultsarepresentedforradiationsourceswiththeflat-toplastingabout2.5nsattwodiferentpeaktemperaturesofabout150eVand170eV,respectively,includingthetimehistoriesofthetemperatures,theshapesofthedrivelaserpulsesandthetimeintegratedradiationspectra.Thevalidityofthemodelandpossibleimprovementsarediscussed.
简介:本文利用X射线小角衍射和漫散射技术研究了两组具有不同GMR的NiFe/Cu多层膜样品的界面结构。利用在CuK吸收边附近的能量扫描得出了关于NiFe和Cu层的结晶性情况。结果表明两组样品在界面结构和结构性上有明显的区别。另外,我们还发现NiFe和Cu层的原子密度差别比块材料的差别大27%。
简介:ThemetalbindingsitesinthetwoPtcontainingmetallothioneins(Pt-MTandPt14MT)wereexaminedbymeansofPt(II)L3-edgeextendedX-rayabsorptionrinestructure(EXAFS)spectroscopy.ComparisonsbetweenthephaseandamplitudefunctionsderivedfromtheisolatedshellstothoseofPt…Pt.Pt-SandPt-NmodelcomponentsshowedthateachplatinuminPt7MTwascoordinatedbyfoursulfuratomsatadistanceof2.31±0.01A.AnalysisoftheoutershelldataofplatinumatominPt7MTindicatedbackscatteringplatinumatomatapproximate4.29A.StrkinglydifferentstructuralparametershadbeenobtainedforthePt14MTspecies.fittingofthefirstshellrevealedthateachplatinumwascoordinatedbytwosulfursatthedistanceof2.3-±0.02Aandtwonitrogensat2.02±0.02A.TheresultsoftheworkprovidedthedetailedinformationconcerningthelocalenvironmentsofthecoordinatedPt(II)inthesetwoplatinothioneins.
简介:Synchrontronradiationx-rayreflectivitymeasurementisusedtostudytheconcentrationprofileofaδ-dopedErlayerinSiepitaxialfilmgrownbymolecular-beamepitaxy.Theoscillationofthereflectivityamplitudeasafunctionofreflectionangleisobservedintheexperiment.Bydoingatheoreticalsimulation.theconcentrationprofileofEratomscouldbederied.Itisshownthattheoriginallygrownδ-dopedErlayerchangesintoanexpionentiallydecayedfunctionduetotheErsegregation.Thetemperaturedependenceofthe1/edecaylengthindicatesthatthesegregationisakineticallylimitedprocess.Theactivationenergyisdeterminedtobe0.044±0.005eV.