简介:这个工作的目的是用电气化学的技术,光显微镜学,扫描电子显微镜学(SEM),和精力与氟化物离子在酸的人工的口水为牙齿的应用学习Ti-6Al-4V合金的降级行为散的spectrometry(版本)。试验性的结果证明那个氟化物离子在Ti-6Al-4V合金的降级上有重要影响,并且有氟化物离子(大约0.1wt%)的明显的批评集中。与增加氟化物离子集中,腐蚀潜力(E合金的corr)移动了向否定并且同时,合金的阻抗减少了到严重pitting腐蚀的从最小的腐蚀的显著转变在跟随TiO2的溶解的合金表面上被观察被动电影,导致合金的腐蚀抵抗的减少。TiO2的电气化学的溶解被动电影包含了氟化物原子的亲核的攻击到TiO2的钛原子。另外,在酸的口水的Ca2+和Na+可以包含表面反应并且使反应更复杂。
简介:AdditivelymanufacturedTi-6Al-4Vlatticestructureshavefoundimportantnicheapplications.However,theyoftenshowinsufficientcompressiveductilityorinsufficientstructuralintegrity.Inthisstudy,abatchof45octahedralTi-6Al-4Vlatticestructureswasmanufacturedinthreedifferentstrutdiameters(0.5,1.0,1.5mm)byselectiveelectronbeammelting(SEBM).Theinfluenceofpost-SEBMannealingonthecompressivedeformationcharacteristicsofthelatticestructurewasinvestigated.Theas-builtTi-6AI-4Vlatticesfragmentedwhenthecompressivestrainreached13%-23%dependingonstrutdiameter.Annealingat950℃(Ptransustemperature:995℃)onlyslightlyimprovedthecompressiveductilityofthelatticestructures.However,annealingat1050℃(p-annealing)fundamentallychangedthecompressivedeformationmodeofthelatticestructures.Theresultantcompressivestress-straincurvewasfeaturedbyalongsmoothplateauandnofactureoccurredevenaftersignificantdensificationofthelatticestructurehadtakenplace(>50%ofcompressivestrain).
简介:在一个加速腐蚀的环境系列,在疲劳和7B04-T6铝合金的腐蚀行为上,热吃惊的效果是坚定的。环境光谱也就是由二个模块组成:咸水花的腐蚀和热吃惊。机械性质上的热吃惊的效果经由张力的测试被决定;SEM,DCS,和XRD被用来在腐蚀产品上决定热吃惊的效果。另外,产品的腐蚀抵抗通过电气化学的测试被查明。结果证明铝合金的机械性质和疲劳生活将与延长热吃惊时间衰退。热吃惊过程可以比在一些艾尔的不热的吃惊标本,和转变上形成的那些导致更稠密的表面腐蚀产品(哦)3进AlOOH。AlOOH可能在腐蚀以后在疲劳生活导致了改进腐蚀抵抗和因此更低的减少,与不热的吃惊标本的相比。重复corrosion/thermal吃惊可能在疲劳生活推迟了进一步的死亡。因此,适当相等的热吃惊温度和时间的选择为设计环境光谱是必要的。
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简介:Anovel,Ti-6A1-4V(Ti64)/Hydroxyapatite(HAat5%byweightconcentration)metal/ceramiccompositehasbeenfabricatedusingelectronbeampowderbedfusion(EPBF)additivemanufacturing(AM):specifically,thecommercialelectronbeammelting(EBMR)process.InadditiontosolidTi64andTi64/5%HAsamples,fourdifferentunitcell(model)open-cellularmeshstructuresfortheTi64/5%HAcompositewerefabricatedhavingdensitiesrangingfrom0.68to1.12g/cm^3,andcorrespondingYoung'smodulirangingfrom2.9to8.0GPa,andcompressivestrengthsrangingfrom-3to11MPa.ThesolidTi64/5%HAcompositeexhibitedanoptimaltensilestrengthof123MPa,andelongationof5.5%incontrasttoamaximumcompressivestrengthof875MPa.Boththesolidcompositeandmeshsamplesdeformedprimarilybybrittledeformation,withthemeshsamplesexhibitingerratic,brittlecrushing.Solid,EPBF-fabricatedTi64sampleshadaVickersmicroindentationhardnessof4.1GPawhiletheTi64/5%HAsolidcompositeexhibitedaVickersmicroindentationhardnessof6.8GPa.ThelowestdensityTi64/5%HAcompositemeshstrutsectionshadaVickersmicroindentationhardnessof7.1GPa.Opticalmetallography(OM)andseanningelectronmicroscopy(SEM)analysisshowedtheHAdispersoidstobehighlysegregatedalongdomainorgrainboundaries,buthomogeneouslydistributedalongalpha(hcp)plateletboundarieswithinthesedomainsintheTi64matrixforboththesolidandmeshcomposites.Thealphaplateletwidthvariedfrom-5μmintheEPBF-fabricatedTi64to-1.1μmfortheTi64/5%HAmeshstrut.TheprecursorHApowderdiameteraveraged5μm,incontrasttothedispersedHAparticlediametersintheTi64/5%HAcompositewhichaveraged0.5μm.ThisworkhighlightstheuseofEPBFAMasanovelprocessforfabricationofatruecompositestructure,consistingofaTi64matrixandinterspersedandexposedHAdomains,whichtotheauthorsknowledgehasnotbeenreportedbefore.Theresultsalsoillustratetheprospectsnotonlyforfabrica
简介:用新型固体工业废渣——大洋多金属结核浸出渣作为吸附剂,通过改变废水溶液pH值、吸附时间、溶液体积等条件,研究大洋多金属结核浸出渣对重金属离子Cr^6+吸附率的影响,从而确定了浸出渣作为吸附剂处理Cr^6+重金属废水的最佳吸附条件。
简介:Three-dimensional-printed(3D-P)titaniumimplantsdisplaymanyadvantages,suchasdesignflexibility,higherefficiency,thecapabilitytoeasilyconstructcomplexorcustomizedstructures,etc.,andisbelievedtopotentiallyreplacetraditionalimplants.However,thebiologicalperformanceofthe3D-Ptitaniumsurfacehasnotbeeninvestigatedsystematically.Herein,weanalyzedthesurfacecharacteristicsof3D-PTi6AI4Vimplantsandevaluatedthebiologicalresponsesofbonemarrowderivedmesenchymalstromalcells(BMSCs)tothe3D-Psurfaceinvitro.Moreover,afterimplantationintotheratfemoralcondylefor3and6weeks,theosseointegrationperformaneewasevaluated.Theresultsshowedthe3D-PTi6Al4Vimplantpresenteddistinctfluctuantmacroscaleroughsurfaceandrelativelybetterhydrophilicitywhichenhancedtheadhesion,proliferation,osteogenicdifferentiationandangiogeneticfactorexpressionofBMSCs.Moreover,theinvivoosseointegrationperformancewasalsobetterthanthatofthecontrolgroupattheearlystage.Thepresentstudysuggestedthe3D-Ptitaniumalloyisapromisingcandidatetobeusedasimplantmaterial.
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简介:Sodiumparanitrophenolatedihydrate(NPNa·2H2O)isanexcellentsemiorganicnonlinearoptical(NLO)material,crystallizesbothinwaterandmethanolwithhighdegreeoftransparency.Goodopticalqualitysinglecrystalsofdimensionupto18mmx6mmx3mmareobtainedbyisothermalsolventevaporationtechnique.Thesolubilityofthecrystalindifferentsolventswasmeasuredgravimetrically.ThesinglecrystalsofNPNa·2H2Oshowvariationinphysicalpropertiesandgrowthrateindifferentsolvents.Methanolorethanolsolutionyieldscrystalsofbipyramidalshapewithclearmorphology.However,methanolgrowncrystalisexhibitingimprovedhardnessparametersandpossessesexcellentthermalstabilityascomparedtowatergrowncrystals.TheeffectsofsolventonhardnessparameteralongwiththermalandopticalpropertiesofNPNa·2H2Owasrevealedinthispaper.
简介:来临三维(3-D)打印了技术在设定的多孔的钛(Ti)的制造提供大可能性植入。然而,打印Ti的bioinert性质提出一个突出的问题。混合微弧的氧化并且热水(MAO-HT)多孔的金属上的处理能生产multi-scaled层次矫形植入,为3-D的表面修正的出现大潜力打印了植入。在这研究,有毛孔的圆柱的多孔的Ti6Al4V(Ti64)脚手架640缩放吗??
简介:ZrC涂层被低压力在石墨底层上扔有Br的化学蒸汽免职(LPCVD)2-Zr-C3H6-H2-Ar系统。微观结构和ZrC涂层的生长行为上的免职时间的效果被调查。ZrC涂层在一个岛层模式成长了。涂层的形成被ZrC的成核统治在起始20分钟,和快速的成核产生了ZrC的有细密纹理的结构涂层。免职时间什么时候在30min上,涂层的生长被统治由晶体,给安排列的结构。精力散X光检查光谱学证明到锆的碳的臼齿的比率在在ZrC涂层,和X光检查的1:1附近显示出的光电子光谱学ZrC是在涂层的主要阶段,由大约2.5mol%伴随了ZrO2次要的阶段。