简介::Twonovelpoly[(3-alkyhhiophene-2,5-diyl)-(benzylidenequinomethane-2,5-diyl)s]derivatives,poly[(3-butylthiophene-2,5-diyl)-(p-N,N-dimethylamino)benzylidenequinomethane-2,5-diyl)](PBTDMABQ)andpoly[-(3-octylthiophene2,5-diyl)-(p-N,N-dimethylamino)benzylidenequinomethane-2,5-diyl)](POTDMABQ),weresynthesized.Thebandgapsofthetwopolymersarecalculatedas1.75eVforPBTDMABQand1.69eVforPOTDMABQ,respectively.Thehomogenousfilmsofthetwopolymerswerepreparedandtheirthird-ordernonlinearopticalpropertieswerestudiedbythebackwarddegeneratefour-wavemixingat532nm.Byusingtherelativemeasurementtechnique,thethird-ordernonlinearopticalsusceptibilitiesofPBTDMABQandPOTDMABQarecalculatedas5.62×10^-9and1.22×10^-8ESU,respectively.Itisfoundthatsubstitutedalkygroupshavestrongeffectsonthebandgapandnonlinearopticalpropertiesofthetwopolymers.Therelativelybigthird-ordernonlinearopticalsusceptibilitiesandsmallbandgapofPOTDMABQresultedmainlyfromthelongeralkylwithstrongelectron-donatingabilitycanenhancethedelocationdegreeofconjugatedπelectronics.
简介:TheopticalabsorbanceinnearUVwavelengthregioninSnO2nanoclustersinanexternalelectricfieldisdeterminedatroomtemperature.Theabsorbancespectraasapplicedfieldandtheabsorbancevariationswiththeappliedfieldareobtained.Therelationbetweenabsorbancechangeandappliedfieldisnon-linear.andissaturatedathighfieldregion.
简介:中华电信公司全民释股计划将卖出近50亿股,吸收逾2.400亿新台币资金,由于金额庞大,将规划分次释出.以不超过三次为宜,同时采先多后少的释股方式,并设法提高市场购买意愿。中华电信全民释股案将自99年7月开始,至2001年公股降至50%以下,完成民营化目标。根据中华电信财务顾问中华开发规划的释股方案,中华电信现有资本额964亿元台币,释出股数须超过48.2亿股,才能达到民营化目标。中华开发以理有中华电信的资产与负债初估,释股股价应为50元新台币,即释股金额超过2.400亿元新台币。中华开发并预估,中华电信的股价可能须打折扣,释股股价能介于35元新台币至50元新台币之间。
简介:VO2thinfilmswithgoodswitchingpropertieswerepreparedbycontrollingtheannealingtimeandtheannealingtemperatureinavacuumsystem.Thestructural,opticalandelectricalpropertiesofthesampleswerecharacterizedbyusingXRD、XPS、UV-VISandelectricalmeasurements.TheswitchingparametersofVO2thinfilmwereinvestigatedtoo.TheresultsindicatethatbeforeandafterphasetransitiontheresistanceofVO2thinfilmschangesaboutthreeordersofmagnitude,thevariationoffilmtransmittanceof40%hasbeencarriedoutwiththeabsorptivityswitchingvelocityofabout0.2607/minat900nm.Thestructuralpropertyofsampleshasbeenimprovedbutthephase-transitionpropertieshavebeendecreasedbyincreasingtheannealingtimeandannealingtemperature.ThevalenceofVionsandthestructureofsampleshavegreateffectonphasetransitionpropertiesofVO2thinfilms.Discussionontheeffectsofannealingtimeandannealingtemperatureonthephase-transitiontemperatureandhysteresiswidthshowsthatthebestreasonableannealingtimeandannealingtemperaturecanbeachieved.
简介:MaximIntegratedProducts(MXIM)推出MAX1577Z/MAXl577Y型高效1x/2x电荷泵,可为自光LED提供高达1.1A的调节电流(可保证800mA)。采用独有的自适应模式开关技术,可为摄像模式或背光提供极高的效率(高达92%)。即使是在低电池电压情况下,其极小的开环输出阻抗仍可实现最大的自光LED闪光灯亮度。这两款器件仅需三个微型陶瓷电容,省去了升压型DC/DC转换器和薄型电感器,确保满足翻盖器式手机对器件高度的要求。MAX1577Z/MAX1577Y的1MHz高速开关频率可使用非常小的外部元件。经过优化的稳压方案确保具有低EMI和低输入纹波。