简介:Themajoraimscombustionengineersallovertheworldarestrivingatareconservationofenergyandallevia-tionofenvironmentalpollution,forwhichthemonitoringandcontrolofthefurnaceprocessareofprimeimportancetoattainanoptimizedconditionofcombustion.Oxygencontentinfluegasisgenerallyusedasanindicatorofwhethertherightamountofcombustionairissupplied.However,itcannotdirectlyreflectthedegreeofperfectionofthecombustionprocesstakingplaceinthefurnace.OntheotherhandCOisaproductofchemicalreactionwhichdirectlyreflectsthe
简介:尖晶石LiMn2O4是很有发展前途的锂离子电池正极材料,但它在循环过程中存在着容量衰减的问题,其中Jahn-Teller效应是锂离子电池正极材料尖晶石LiMn2O4在应用中容量衰减的难点。对溶胶凝胶法制备的尖晶石LiMn2O4,及其阳离子掺杂LiMxMn2-xO4(M=Li,Ni—Co)正极材料进行了表面改性(包覆MgO),利用x射线衍射、晶格参数和|Mn^4+|/|Mn^3+|比值等参数研究了尖晶石LiMn2O4的Jahn-Teller效应。结果表明:表面改性后的正极材料Li1.05Mn1.9Co0.05Ni0.05O4循环性能明显增强,Jahn-Teller效应得到了有效抑制。