简介:Intensevisibleemissionsfromdysprosium(Dy3+)ionsdopedglassesbecameprospectivefordiversetechnologicalapplications.Inthispaper,physical,opticalandstructuralpropertiesofmagnesiumborateglassesdopedwithvariedconcentrationsofDy2O3wereexamined.Suchglassesweresynthesisedbymeltquenchingmethodandcharacterizedatroomtemperatureusingseveralanalyticaltechniques.Luminescenceandabsorptionspectra(inthevisibleregion)ofas-quenchedsampleswereusedtoevaluatethephysicalandopticalproperties.XRDpatternconfimstheamorphousstateofas-quenchedsamples.TheFouriertransforminfrared(FTIR)spectraofglassesrevealvariousbondingvibrationsassignedtodifferentfunctionalgroups.UV-vis-NIRspectradiscloseeightabsorptionbandsaccompaniedbyabandforhypersensitivetransitionpositionedat1260nm(6H15/2→6F11/2).ThevaluesofdirectandindirectopticalenergybandgapofthestudiedglassesaredecreasedwiththeincreaseofDy3+ioncontents.Thephotoluminescencespectraofallglassesundertheexcitationof380nmdisplaytwoprominentemissionbandscentredat497nm(4F9/2→6H15/2,blue)and587nm(4F9/2→6H13/2,green).Theachievedintenseluminescencefromtheproposedglasscompositionmaybebeneficialforsolidstatelaserapplications.
简介:在硅酸盐体系(Na2SiO3+KOH)电解液中,采用微弧氧化技术在5052铝合金表面原位生成微弧氧化膜层。并利用SEM、EDS和XRD等仪器设备,分析微弧氧化膜层形貌、元素分布和相组成,着重分析氧化时间对膜层厚度、表面孔隙率和最大孔洞直径及膜层耐腐蚀性的影响。结果表明:微弧氧化膜层表面有典型的“火山堆积”形貌生成,且膜层厚度、表面孔隙率和最大孔洞直径随氧化时间的增加而增大;膜层主要元素为O和Al,相组成为γ-Al2O3和α-Al2O3,且主要为γ-Al2O3;微弧氧化处理可显著提高试样的耐腐蚀性能,腐蚀电流密度至少下降2个数量级,电化学阻抗模值|Z|至少增加2个数量级,随氧化时间从10min延长到50min试样的耐腐蚀性能先提升后降低,氧化时间为20min的试样耐腐蚀性能最好。