简介:ThesplittingofpotentialenergylevelsforgroundstateX2ΠgofOx2(x=+1,1)underspin–orbitcoupling(SOC)hasbeencalculatedbyusingthespin–orbit(SO)multi-configurationquasi-degenerateperturbationtheory(SO-MCQDPT).TheirMurrell–Sorbie(M–S)potentialfunctionsaregained,andthenthespectroscopicconstantsforelectronicstates2Π1/2and2Π3/2arederivedfromtheM–Sfunction.TheverticalexcitationenergiesforOx2(x=+1,1)areν[O+12(2Π3/2→X2Π1/2)]=195.652cm1,andν[O12(2Π1/2→X2Π3/2)]=182.568cm1,respectively.Allthespectroscopicdataforelectronicstates2Π1/2and2Π3/2aregivenforthefirsttime.
简介:YBa2Cu3Ox(YBCO)thinfilmsgrownondifferentsubstrateswithand/orwithoutEu2CuO4(ECO)bufferlayerwereinvestigatedbyX-raywideanglediffraction,reflection,diffusescatteringandtopography.TheresultsshowthatfortheyttriastabilizedZrO2(YSZ)substrate,thepresenceofanECObufferlayerimprovesthecrystallinequalityoftheYBCOfilm,whileanegativeeffectisobservedfortheSrTiO3(STO)substrate.ThelateralcorrelationlengthforasamplegrownonaYSZsubstratewithECObufferLayerismuchgreaterthangrownonanSTOsubetrate.TheSTOsubstrateusedhasmosaicstructure.2001ElsevierScienceB.V.Allrightsreserved.
简介:Inthefarfieldoftheintensitydistributionofthebeamdeliveredbyatwo-stagetransient–collisionalexcitationX-raylaser(XRL),anon-expectedinterferencepatternthatisstablefromshottoshothasbeendiscovered.Itisdemonstratedthattheinterferenceiscausedbytheemergenceofanimaginarysourceintheamplifyingplasma,whichisphasematchedtotheradiationofthegenerator.TheobservedphenomenoniscalledanX-raycoherentmirage.Toexplaintheobtainedresults,anewtheoreticalapproachisdeveloped.ThebasicessentialconditionsforformationoftheX-raymirageareformulated,andpossibleapplicationsarediscussed.Thispaperdetailstheexperiments,includingtheformulationofthenecessaryandsufficientconditionsforformationoftheX-raymirage,andpossibleapplicationsarediscussed.
简介:ThestatusoftheEuropeanX-rayFree-ElectronLaser(EuropeanXFEL),underconstructionnearHamburg,Germany,isdescribed.ThestartofoperationsoftheLCLSatSLACandofSACLAinJapanhasalreadyproducedimpressivescientificresults.TheEuropeanXFELfacilityispoweredbya17.5GeVsuperconductinglinearacceleratorthat,comparedtothesetwooperatingfacilities,willgeneratetwoordersofmagnitudemorepulsespersecond,upto27000.Itcanthereforesupportmodesofoperationswitchingthebeamupto30timespersecondamongthreedifferentexperiments,providingeachofthemwiththousandsofpulsespersecond.Thescientificpossibilitiesopenedupbythesecapabilitiesarebrieflydescribed,togetherwiththecurrentinstrumentaldevelopments(inoptics,detectors,lasers,etc.)thatarenecessarytoimplementthisprogram.
简介:Co(II)-salenwasencapsulatedinMIL-100(Cr)metalorganicframeworkby"shipinabottle"tosynthesizeanewelectrocatalyst,Cosalen@MIL-100(Cr).ThematerialwascharacterizedbyXRD,FT-IR,UV-VisandN2-adsorption.TheCosalen@MIL-100(Cr)modifiedglassycarbonelectrodeexhibitsawell-definedreductionpeakatthepotentialof–0.21Vtowardtheoxygenreductionreaction(ORR)bycyclicvoltammetry(CV)inpH=6.84phosphatebuffer.Almost400mVpositiveshiftofpotentialatCosalen@MIL-100(Cr)modifiedelectrodeforORRcomparedwiththatatbareglassycarbon,indicatesthatCosalen@MIL-100(Cr)possessesexcellentelectrocatalyticactivity.ThetransferrednumberofelectronsforORRwasdeterminedbychronocoulometry.TheresultsuggeststhattheintroductionofCo(II)-salencomplexintoMOFincreasestheelectrocatalyticactivityviaafour-electronreductionpathway.Furthermore,thiselectrocatalystexhibitsgoodstabilityandreproducibility.
简介:Theadsorptionandelectronicpropertiesofisolatedcobaltphthalocyanine(CoPc)moleculeonanultrathinlayerofNaClhavebeeninvestigated.High-resolutionSTMimagesgiveadetailedpictureofthelowestunoccupiedmolecularorbital(LUMO)ofanisolatedCoPc.ItisshownthattheNaClultrathinlayerefficientlydecouplestheinteractionofthemoleculesfromtheunderneathmetalsubstrate,whichmakesitanidealsubstrateforstudyingthepropertiesofsinglemolecules.Moreover,strongdependenceoftheappearanceofthemoleculesonthesamplebiasintheregionofrelativelyhighbias(>3.1V)isascribedtotheimagepotentialstates(IPSs)ofNaCl/Cu(100),whichmayprovideuswithapossiblemethodtofabricatequantumstoragedevices.
简介:X-γradiationbelongtotheionizingradiation.Ionizingradiationsinkstoenergyinorganismbutproduceadisservicetotheorganism.Justasmedicine,thedisserviceoftheradiationtowardsOrganismisdecidedbytoacceptradiationquantify,theradiationquantifywasnameddose.Radiationprotection'sbasicmissionsistowanttoresultthedosetofixquantify.InthissurveythedoseatworkplaceanditssurroundingsenvironmentsofHL-2Adevicewasmeasuredandtheassessmentwasgivenout.