简介:合成了通式为K10H5[Ln(PMo7W2VO39)2].nH2O(Ln-La^3+,Ce^3+,Pr^3+,Nd^3+,Sm^3+,Eu^3+,Gd^3+,Dy^3+,Yb^3)的9种五元新型杂多配合物,并用元素化学分析,TG,ICP,IR,UV,31^1P,51V-NMR,ESR,XPS,XRD进行了表征,结果表明新配合物仍保持Keggin结构,稀土元素处于配合物的内界。借助TG-DTA,不同温度下的IR,XRD的水溶性实验考察了新配合物的热解性质,得出了热稳定的温度范围为400℃-500℃,为催化研究提供了依据。
简介:ThechoicenumberofagraphG,denotedbyX1(G),istheminimumnumberksuchthatifalistofkcolorsisgiventoeachvertexofG,thereisavertexcoloringofGwhereeachvertexreceivesacolorfromitsownlistnomatterwhatthelistsare.Inthispaper,itisshowedthatX1(G)≤3foreachplanegraphofgirthnotlessthan4whichcontainsno6-,7-and9-cycles.
简介:WithintheframeworkoftheUsdpf(16)interactingbosonmodel(IBM),theeffectsofstrongcorrelationsofthedipole(p--boson)andtheoctupole(f--boson)degreeoffreedomonthepositive-paritystatesofeven-evennucleiinSU(3)limitarediscussed.Itisshownthatconfigurationsofanevennumberofmanyp-andf-bosonscannotonlybeincorporatedintotheusuallow-lyingcollectiverotationalbands,suchasthegroundstateband,β-andγ-vibrationalbands,butalsonaturallyformtheKπ=1+,3+rotationalbands,etc.TheseresultsaresimilartothatofUsdg(15)-IBMandinagreementwellwiththeexperimentaldataofthe17672Hf104nucleus.Besides,severalintrabandE2transitionprobabilitiesaregiven,whichareconsistentwiththatofUsd(6)-IBM.
简介:A New E3 Transition from 9+ Isomer in 144Pm NucleusANewE3Transitionfrom9+Isomerin144PmNucleus¥ZhangYuhu;Y.Gono;ZhaoQinz...
简介:Parametersforthe3W1sourceatBSRFweredeterminedinboththededicatedandparasiticmodeandtheirsuitabilityforproteincrystallographybeamlineatBSRFwererealized.Itisdiscussedthatthephysicsmotivationandthedesignofthe3W1iscomparedwithsimilarexperimentalstationsattheBrazilianLightSourec(1.37Gev)andMax-IIinSweden(1.5GeV).Thephotonfluxfromthe3W1sourcdisabout2×10^11photon/smAinthewavelengthrangeof2.0-0.9Ainparasiticmodeand50-80timeshigherinthededicatedmode.Boththededicatedandparasiticmodesaresuitableformacromolecularstructureexperiments.2001ElsevierScienceB.V.Allrightsreserved.
简介:Comparativemolecularfieldanalysis(CoMFA),athreedimensionalquantitativestructure-activityrelationship(3D-QSAR)methodwasappliedtoaseriesofdiindolylmethane(DIM)analogstostudytherelationshipbetweentheirstructureandtheirinductionofCYP1A1-associatedethoxyresorufin-O-deethylase(EROD)activity.ADISCOmodelofpharmacophorewasdervedtoguidethesuperpositionofthecompounds.Thecoefficientofcross-validation(q^2)andnoncross-validation(r^2)forthemodelestablishedbythestudyare0.827and0.988respectively,thevalueofvarianceratio(F)is103.53andstandarderrorestimate(SEE)is0.044.ThesevaluesindicatethattheCoMFAmodelderivedissignificantandmighthaveagoodpredictionforthecatalyticactivityofDIMcompounds.Asaconsequence,thepredictedactivityvaluesofnewdesignedcompoundswereallhigherthanthatofthereportedvalue.
简介:Thethermalbehavior,mechanismandkineticparametersoftheexothermicdecompositionreactionof3,3-bis(azidomethyl)oxetane/tetrahydrofuran(BAMO/THF)copolymerinamodehavebeeninvestigatedbymeansofDSC,TG-DTG,fastandlowerthermolysis/FrIRandTG-MS.Thereactionmechanismwasproposed.Theapparentactivationenergyandpre-exponentialconstantofexothermicdecompositionreactionofthecompoundat0.1MPaare167.04kJ·mol^-1and10^14.41s^-1,respectively.ThecorrespondingcriticaltemperaturesofthermalexplosionobtainedfromtheonsettemperatureTeandthepeaktemperatureTpare223.20and245.78℃,respectively.ThekineticequationoftheexothermicdecompositionprocessofBAMO/THFat0.1MPacouldbeexpressedas:dα/dT=10^15.19[-ln(1-α)^2/3e^-2.009×10^4/T
简介:Thispaperdescribesanewmethodwhichhasbeendevelopedforthesolutionofdirectandinverseproblemsof3-Dcompressibleflowsinturbomachinery.Twotypesofstreamfunctionsarepropsedinthepaperandtheatreamfunction-coordinatesystemisappliedinnumericalcomputations,Thealgorithmisappliedtostatorbladesandtheresultsarecomparedwithexperimentaldata.Itisthownthatthecomparisonsareverysatisfactory.
简介:Inthispaper,theauthorsobtaintheBaecklundtransformationontime-likesurfaceswithconstantmeancurvatureinR^2,1.Usingthistransformation,familiesofsurfaceswithconstantmeancurvaturefromknownonescanbeconstructed.
简介:让p是一个奇怪的素数。在我们介绍的这份报纸,二次的线性p鈥揳lgebraQ1由合适改变Q的发电机获得了,在H鈭炩€搑ing系列的范畴的cohomology操作的同类的二次的代数学,并且仔细看在情况p=相似的商在cohomology上导致的地图2,结果是injective。因此,它的目标包含古典亚当斯的E2鈥搕erm光谱顺序作为subalgebra。对的明确的描述在Q上在合理假设下面被给是Koszul代数学。关键词Koszul代数学-代数学的Cohomology-亚当斯光谱顺序先生(2000)题目分类55S10-18G15-55T15
简介:PhaseShiftingAndLogicalMoire(PSALM)isakindofcomputerimageprocessingmethodwhichcanbeusedinphasemeasurementandtoobtaintheshape,deformationandstraindistributionofanobject.Thispaperpresentsthestructureandworkingprocedureofa2DphasemeasurementPSALM2Dprogramanditsapplication.Whenanalyzingmoireinterferometricfringes,wecanobtain2Ddistributionofdisplacementandstrain.Whenitisusedinreflectionmoirewecanmeasuretheslopeofaspecimen.SatisfactoryvisualizationandquantitativeresultsaregivenbyPSALM2D.
简介:Fourkindsofpalladiumcatalystsdispersedonpoly-N-vinyl-2-pyrrolidonewerepreparedbyusingCH3OH-NaOH,NaBH4,H2OorCH3OH-H2Oasthereducingagentintheprocessofcatalystpreparation.ThecatalystswerecharacterizedbyXPS,TEM,XRDandusedforthehydrogenationofmethylacrylate.Itwasfoundthatthevalencestateofpalladiumanddistributionofpalladiumparticlesaswellasthehydrogenationrateweregreatlyaffectedbythereducingagent.ThebestevenlydispersedpalladiumcatalystshowinghighhydrogenationactivitywaspreparedusingCH3OH-NaOHasthereducingagent.
简介:忍受2,6二度(imino)的一系列钴建筑群含苯氧基的ligands,LCoCl2[L=2,6-(ArNCH)2CH3C6H2OH]被ligand2,6二度(imino)的反应综合有钴二氯化物的相等的鼹鼠的酚,和这些建筑群被元素的分析描绘,1HNMR,MS和红外系列。一建筑群的结构被单个水晶X光检查衍射分析决定。