简介:Thecreationandpropagationoflongitudinalacousticphonons(LAPs)inhighqualityhematitethinfilms(α-Fe2O3)epitaxiallygrownondifferentsubstrates(BaTiO3,SrTiO3,andLaAlO3)areinvestigatedusingthefemtosecondpump–probetechnique.Transientreflectionmeasurements(?R/R)indicatethephoto-excitedelectrondynamics,andtheinitialdecaylessthan1psandtheslowdecayof~500psareattributedtotheelectron-LOphononcouplingandelectron–holenonradiativerecombination,respectively.LAPsinα-Fe2O3filmcanbecreatedbyultrafastexcitationoftheligandfieldstate,suchastheligandfieldtransitionsunder800-nmexcitationaswellastheligandtometalcharge-transferwith400-nmexcitation.Thestrainmodulationsofthesoundvelocityandtheout-of-planeelasticpropertiesaredemonstratedinα-Fe2O3filmondifferentsubstrates.
简介:针对DC/DC的质子位移效应,选取具有抗TID能力的DC/DC器件作为试验样品,在3MeV质子辐照条件下获取了器件的失效位移损伤剂量.结果表明,DC/DC功能失效是PWM控制器输出异常导致的.通过等效^60Coγ辐照及退火试验,排除了TID效应的影响,确定器件功能失效是由位移损伤引起的.高温退火后器件功能恢复,并立即对该器件进行了测试.结果表明,输出电压、电压调整度、负载调整度、交叉调整度、纹波及负载跃变时的输出电压均大幅衰退.利用这些敏感参数,获取了位移损伤导致的电源性能衰退模式.根据位移损伤缺陷类型及退火温度,分析了DC/DC的退火规律,可为DC/DC质子辐射损伤模拟试验方法的建立及其空间应用提供依据.
简介:Two-dimensional(2D)graphitecarbonnitride(g-C3N4)nanosheetshavebeensuccessfullyusedasasaturableabsorber(SA)inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles(g-C3N4-NPs)andthree-dimensionalorderedmesoporousg-C3N4(mpg-C3N4)werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.
简介:运用显式动力学有限元软件LS-DYNA,对环向多点同步起爆条件下装药爆轰波的传播规律、环形药形罩在爆轰波作用下成型过程及环形射流对靶板的侵彻效应进行了数值模拟,分析了起爆点数对侵彻能力的影响。研究结果表明:环向多点同步起爆条件下,爆轰波通过相互碰撞形成统一的波浪形爆轰波前沿,爆轰波前沿到达药形罩顶端的时间沿环向并不同步,压力大小也不一致。环形射流不仅头部和尾部之间存在速度梯度,沿环向也存在一定的速度差异,难以保持形状。环形射流对靶板的破坏形式主要为塑性扩孔或塑性扩孔+剪切冲塞,形成的圆形弹孔孔径与环形药型罩对称面直径相当。环形射流的侵彻能力随起爆点数的增加而增大,当起爆点数大于10时,侵彻深度增大幅度会明显减小。
简介:Thesuppressionoftherecombinationofelectronsandholes(e–h)andtheenhancementofthelightabsorptionofsemiconductorsaretwokeypointstowardefficientphotocatalyticdegradation.Here,wereportafew-layerg-C3N4/α-MoO3nanoneedles(flg-C3N4/α-MoO3NNs)all-solid-stateZ-schememechanismphotocatalystsynthesizedviaatypicalhydrothermalmethodinacontrolledmanner.Therecombinationofthephoto-inducede–hpairscouldbeeffectivelyrestrainedbytheZ-schemepassagewaybetweentheflg-C3N4andα-MoO3NNsinthecomposite,whichcouldalsopromiseahighredoxabilitytodegradepollutants.Anditbecamepossibleforthepreparedphotocatalysttoabsorblightinawiderangeofwavelengths.Thedetailedmechanismwasstudiedbyelectronspin-resonancespectroscopy(ESR).Thelow-dimensionalnanostructureofthetwoconstituents(α-MoO3NNswithone-dimensionalstructureandflg-C3N4withtwo-dimensionalstructure)endowedthecompositewithvarietiesofexcellentphysicochemicalproperties,whichfacilitatedthetransferanddiffusionofthephotoelectronsandincreasedthespecificsurfaceareaandtheactivesites.The10wt%flg-C3N4/α-MoO3NNsshowedthebestphotocatalyticperformancetowardRhBdegradation,therateofwhichwas71.86%,~2.6timeshigherthanthatofα-MoO3NNs.
简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.