简介:Toimprovetheharvestingofvisiblelightandreducetherecombinationofphotogeneratedelectronsandholes,Ti3+self-dopedTiO2nanoparticlesweresynthesizedandassembledintophotoanodeswithhighvisiblelightphotoelectrochemicalproperties.X-raydiffraction,transmissionelectronmicroscopy,X-rayphotoelectronspectra,electronresonancespectroscopyandenergydispersiveX-rayspectrawereusedtocharacterizethestructure,crystallinity,morphologyandotherpropertiesoftheobtainednanoparticles.UV–visiblediffusereflectancespectrashowedthattheTi3+self-dopedTiO2nanoparticleshadastrongabsorptionbetween400and800nm.Moreover,whenhydrothermaltreatmenttimewasprolongedto22h,theheterogeneousjunctionwasformedbetweentheanataseandrutileTiO2,wheretheanataseparticlesexposedhighlyactive{001}facets.Undervisiblelightirradiation,theTi3+self-dopedTiO2electrodeexhibitedanexcellentphotoelectrocatalyticdegradationofrhodamineB(RhB)andwatersplittingperformance.Intriguingly,byselectinganappropriatehydrothermaltime,thehighphotoconversionefficiencyof1.16%wasachieved.
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简介:AlterationsinDNArepair,cellcycle,andapoptoticpathwaysareoftenassociatedwithcancerriskandradiationsensitivity.IndividualswithreducedDNAdamageresponsefaceagreatersensitivitytomutagenchallenge.Interindividualvariabilityinmutagenorradiationsensitivityandincancersusceptibilitymayalsobetracedbacktopolymorphismsofgenesaffectinge.g.DNArepaircapacity[1].
简介:适用的一本有限投出的杂志的短暂流动上的杂志错误排列的效果在这研究被介绍。新3D计算液体动力学(CFD)分析方法被使用。另外,在杂志适用和转子动力学的油电影的短暂液体动力学的联合伪的计算在分析被考虑。基于结构化的网孔,当杂志在一部油电影的液体动力学模拟期间移动时,为网孔运动的一条新途径被建议更新网孔体积。存在动态网孔模型提供了由流畅不对在杂志轴承的短暂的油流动合适。杂志的运动被作为负担的边界条件与计算电影压力解决忍受转子的系统的动人的方程获得。在液体动力学和转子动力学之间的数据交换被数据文件认识到。从CFD模型获得的结果与没有对齐的杂志轴承上的以前的试验性的结果一致。电影压力,油电影力量,磨擦转矩,错误排列时刻和态度角度为没有对齐并且排列的杂志轴承计算、比较。结果显示适用的表演被被失衡的刺激,和CFD方法基于技术能有效地预言的液体结构相互作用(FSI)引起的错误排列极大地影响在一个忍受转子的系统适用的一本没有对齐的杂志的短暂流动域。
简介:Non-smallcelllungcancer(NSCLC)accountsfor85%oflungcancer,whichistheleadingcauseofdeathinlungcancerpatient.RoutinetreatmentofNSCLCcannoteffectivelychangethesurvivalrateofpatients,oneimportantreasonistheincreasedradioresistanceoftumorcellsafterconventionalradiotherapy.
简介:InsituhighpressureenergydispersiveX-raydiffractionmeasurementsonlayeredperovskite-likemanganateCa3Mn2O7underpressuresupto35GPahavebeenPerformedbyusingdiamondanvilcellwithsynchrotronradiation.Theresultsshowthatthestructureoflayeredperovskite-likemanganateCa3Mn2O7isunstableunderpressureduetotheeasycompressionofNaCl-typeblocks.ThestructureofCa3Mn2O7underwenttwophasetransitionsunderpressuresintherangeof0-35GPa.Onewasatabout1.3GPawiththecrystalstructurechangingfromtetragonaltgoorthorhombic.Theotherwasatabout9.5GPawiththecrystalstructurechangingformorthorhombicbacktoanothertetragonal.
简介:Removalofcarbonylsulfide(COS)fromCO2streamissignificantfortheproductionandutilizationoffoodgradeCO2.ThisstudyinvestigatestheadsorptionperformanceofAg/NaZSM-5asadsorbentpreparedbyincipientwetnessimpregnationfortheremovalofCOSfromaCO2streaminafixed-bedadsorptionapparatus.Effectsofvariousconditionsonthepreparationofadsorbent,adsorptionanddesorptionwereintensivelyexamined.TheresultsrevealedthatCOScanberemovedtobelow1×10-9fromaCO2stream(1000ppmCOS/CO2)usingAg/NaZSM-5(10wt%AgNO3)withanadsorptioncapacityof12.86mg·g-1.Theadsorbentcanbefullyregeneratedusinghotairat450C.Theadsorptionabilityremainedstableevenaftereightcyclesofregeneration.
简介:Chemical-loopingcombustion(CLC)isanovelcombustiontechniquewithinherentCO2separation.Magnetite(Fe3O4)wasselectedastheoxygencarrier.Shenhuacoal(InnerMongolia,China),strawcokeandnaturalcokewereusedasfuelsforthisstudy.Influencesofoperationtemperatures,coaltoFe3O4massratios,anddifferentkindsoffuelsonthereductioncharacteristicsoftheoxygencarrierwereinvestigatedusinganatmospherethermogravimetricanalyzer(TGA).Scanningelectronmicroscopy(SEM)wasusedtoanalysethecharacteristicofthesolidresidues.Experimentalresultsshownthatthereactionbetweenthecoalandtheoxygencarrierbecomestrongatatemperatureofhigherthan800℃.Astheoperationtemperaturerises,thereductionconversionrateincreases.Atthetemperaturesof850oС,900℃,and950℃,thereductionconversionrateswere37.1%,46.5%,and54.1%respectively.However,SEMimagesshowthatatthetemperatureofhigherthan950℃,theironoxidesbecomemeltedandsintered.Thepossibleoperationtemperatureshouldbekeptaround900℃.WhenthemassratiosofcoaltoFe3O4were5/95,10/90,15/85,and20/80,thereductionconversionrateswere29.5%,40.8%,46.5%,and46.6%respectively.Withtheincreaseofcoal,theconversionrategoesup.Butthereexistanoptimalratioaround15/85.Comparisonsbasedondifferentkindsoffuelsshowthatthesolidfuelwithahighervolatileandamoredevelopedporestructureisconducivetothereductionreactivityoftheoxygencarrier.