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500 个结果
  • 简介:主要考虑11维Boussinesq系统的一个Darboux变换,反复利用该Darboux变换,可以从该系统的一个已知解出发,通过代数运算和求导运算得到系统的新解.

  • 标签: 1+1维Boussinesq系统 可积系统 DARBOUX变换
  • 简介:Theinsertionof1,1-bis(1′-naphthyl)ethylenemonomerunitintotheactivepolystyrenechainendgreatlydecreasedthereactivityoftheactivechainendtothecarbonylgroup,andallowedthepolymericchainendtoreactonlywiththedoublebondinN-methacryloylcaprolactam,resultinginN-acylcaprolactamfunctionalizedpolystyrenein100%conversion.Newdiblockcopolymerofpolystyrenewithpolycaprolactamwassynthesizedbydirectreactionofthefunctionalizedpolymerwithcaprolactamwithoutaddingadditionalalkalimetalortheircaprolactamsalts.

  • 标签: 1 1-bis (1’ -naphthyl) ETHYLENE N-methacryloylcaprolactam
  • 简介:Aseriesofnovel1H-benzimidazol-1-ylacetatesand1H-benzimidazol-1-ylpropionatescontaining1H-1,2,4-triazolemoietyweresynthesizedundermicrowaveirradiationbymulti-stepreactions,inyieldsof87-94%.TheirinvitroantifungalactivitiesagainstBotrytiscinereaandSclerotiniasclerotiorumwereevaluatedbymycelialgrowthratemethod.AllthetargetcompoundsexhibithighactivitiesagainstB.cinereawiththeEC50valuesof7.96-21.74μg/mL,higherthanthatofcarbendazim.

  • 标签: 抗真菌活性 苯并咪唑 乙酸酯 体外 合成 基团
  • 简介:<正>Inthispaper,weapplythesolitontheorytothecaseofisometricimmersionindifferentialgeometryandobtainafamilyofisometricimmersionsfromMn1(c1)×Mn2(c2)tospaceformsMn(c)byintroducing2-parameterloopalgebra.

  • 标签: SOLITON THEORY ISOMETRIC immersion Riemaniann product
  • 简介:Thehydrolysisreactionof(±)-2-acetamido-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-1],anintermediateofchloramphenicol,wasstudiedandthreedifferentproductswereobtainedrespectivelyunderdifferentreactionconditions.Theresolutionofhydrolysisproduct(±)-2-amino-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-3]wascarriedout.Aprocessofcrystallization-inducedasymmetrictransformationwasobservedandupto76%oftheopticallypureenantiomerwasobtainedintheresolutionof(±)-3.

  • 标签: Hydrolysis Resolution EPIMERIZATION
  • 简介:Therelativisticproblemofspin-1/2fermionssubjecttovectorhyperbolic(kink-like)potential(~tanhkx)isinvestigatedbyusingtheparametricNikiforov-Uvarovmethod.TheenergyeigenvalueequationandthecorrespondingnormalizedwavefunctionsareobtainedintermsoftheJacobipolynomialsintwocases.

  • 标签: 狄拉克方程 相互作用 向量 束缚态 三角 三维
  • 简介:本文研究E^n+1的中闭超曲面上的Lr(0≤r≤n)算子,得到其第一非零特征值心的两个上界估计,改进和推广了Alias等人的相应结论。

  • 标签: 第一非零特征值 闭超曲面 r-平均曲率
  • 简介:Anewseriesofliquidcrystalscomprisingeightheterocyclicisoflavoneesters,7-alkanoyloxy-3-[4’-(3-methylbutyloxyphenyl)]-4H-1-benzopyran-4-onesexhibitingenantiotropicnematic(N)andsmecticC(SmC)phasesweresynthesizedandinvestigated.Themesomorphicpropertiesofallderivativeswereinvestigatedbymeansofdifferentialcalorimetryandpolarizedopticalmicroscopy.WideangleX-raydiffractiontechniquewasemployedtoinvestigatethemolecularpackingassociatedwiththeintermolecularinteractionaswellasthecorrelationbetweenthethermalbehaviourofthesecompoundswiththeiranisotropypropertieswithinamesophase.

  • 标签: X射线衍射技术 黄酮衍生物 合成 杂环 液晶 表征
  • 简介:ThispaperconstructstheinteractionpotentialoftheSH(X2Π)radicalbyusingthecoupled-clustersinglesdoubles-approximate-triplestheorycombiningthecorrelation-consistentquintuplebasissetaugmentedwiththediffusefunctions,aug-cc-pV5Z,inthevalencerange.Employingthepotential,itaccuratelydeterminesthespectroscopicparameters.ThepresentDe,Re,ωe,ωeχe,αeandBevaluesareof3.7767eV,0.13424nm,2699.846cm?1,47.7055cm-1,0.2639cm-1and9.4414cm-1,respectively,whichareinexcellentagreementwiththoseobtainedfromthemeasurements.Atotalof19vibrationalstateshasbeenfoundwhenJ=0bysolvingtheradialSchrdingerequationofnuclearmotion.Thecompletevibrationallevels,classicalturningpoints,initialrotationandcentrifugaldistortionconstantswhenJ=0arereportedforthefirsttime,whichareingoodaccordwiththeexperimentalresults.Thetotalandvariouspartial-wavecrosssectionsarecomputedfortheelasticcollisionsofsulfurandhydrogenintheirgroundstatesatlowtemperatureswhentwoatomsapproacheachotheralongtheSH(X2Π)potentialenergycurve.Overtheimpactenergyrangefrom1.0×10-11to1.0×10-4a.u.,eightshaperesonanceshavebeenfoundinthetotalelasticcrosssections.Foreachshaperesonance,theresonantenergyisaccuratelycalculated.Carefulinvestigationshavepointedoutthattheseresonancesresultfromthel=0,1,2,3,4,6,7,8partial-wavecontributions.

  • 标签: 原子碰撞 弹性碰撞 基态 激发态
  • 简介:采用X射线衍射技术(XRD)对白云石原矿和不同温度煅烧的白云石原矿进行了物相分析,白云石原矿中主相CaMg(CO3)2,相对含量约为98.6%,杂质相SiO2,相对含量约为1.4%。白云石原矿经过300和500℃,煅烧2h未见主相CaMg(CO3)2分解,在750℃煅烧2h,主相CaMg(CO3)2部分分解碳酸钙和氧化镁,在1000℃煅烧2hCaMg(CO3)2全部分解氧化镁和氧化钙。

  • 标签: X射线衍射法 煅烧白云石 物相组成
  • 简介:由用计算机模拟调查的相对论的电子过时的人或物短脉搏激光散布的线性Thomson。它被看那~3的强烈激光脉搏散布3fs在半最大值的完整的宽度,与γ_的一个电子0=10起始的精力,在向后的方向与2.5nm的光子波长产生76attoseconds的超短波的、搏动的放射。一个高度相对论的电子产生的散布放射与更低的相对论的精力电子产生的那相比以它的脉搏宽度和尖分发有优异质量。

  • 标签: X射线脉冲 线性汤姆森散射 强激光束 相对论性电子
  • 简介:TheelectronicpropertiesandtopologicalphasesofThXY(X=Pb,Au,Pt,PdandY=Sb,Bi,Sn)compoundsinthepresenceofspin–orbitcoupling,usingdensityfunctionaltheoryareinvestigated.TheThPtSncompoundisstableintheferromagneticphaseandtheotherThXYcompoundsarestableinnonmagneticphases.Bandstructuresofthesecompoundsintopologicalphases(insulatorormetal)andnormalphaseswithingeneralizedgradientapproximation(GGA)andEngel–Voskogeneralizedgradientapproximation(GGAEV)arecompared.TheThPtSn,ThPtBi,ThPtSb,ThPdBi,andThAuBicompoundshavetopologicalphasesandtheotherThXYcompoundshavenormalphases.Bandinversionstrengthsandtopologicalphasesofthesecompoundsatdifferentpressurearestudied.Itisseenthatthebandinversionstrengthsofthesecompoundsaresensitivetopressureandforeachcompoundasecond-orderpolynomialfittedonthebandinversionstrengths–pressurecurves.

  • 标签: 结构拓扑 化合物 电子性质 PB AU BI
  • 简介:应用波长色散X射线荧光光谱法对中低合金钢、电工钢、高锰钢、不锈钢中锰元素进行测定。采用经验系数法校正元素间的增强-吸收效应和光谱重叠干扰,元素检测限为2.1μg/g,线性相关系数大于0.9998。考察了分析方法的精密度和准确度,元素的测定结果与认定值一致,相对标准偏差小于2%。

  • 标签: X射线荧光光谱法 锰元素
  • 简介:Acompositebeamissymmetricifboththematerialpropertyandsupportaresymmetricwithrespecttothemiddlepoint.Inordertostudythefreevibrationperformanceofthesymmetriccompositebeamswithdifferentcomplexnonsmooth/discontinuousinterfaces,wedevelopanR(x)-orthonormaltheory,whereR(x)isanintegrableflexuralrigidityfunction.TheR(x)-orthonormalbasesinthelinearspaceofboundaryfunctionsareconstructed,ofwhichthesecond-orderderivativesoftheboundaryfunctionsareaskedtobeorthonormalwithrespecttotheweightfunctionR(x).WhenthevibrationmodesofthesymmetriccompositebeamareexpressedintermsoftheR(x)-orthonormalbaseswecanderiveaneigenvalueproblemendowedwithaspecialstructureofthecoefficientmatrixA:=[aij],aij=0ifi+jisodd.Basedonthespecialstructurewecanprovetwonewtheorems,whichindicatethatthecharacteristicequationofAcanbedecomposedintotheproductofthecharacteristicequationsoftwosub-matriceswithdimensionshalflower.Hence,wecansequentiallysolvethenaturalfrequenciesinclosed-formowingtothespecialtyofA.Weusethispowerfulnewtheorytoanalyzethefreevibrationperformanceandthevibrationmodesofsymmetriccompositebeamswiththreedifferentinterfaces.

  • 标签: SYMMETRIC composite beams R(x)-orthogonality of second-order
  • 简介:建立了X射线荧光光谱法测定矿石样品中铀、钍含量的快速分析方法。采用高压粉末制样法,对不同含量的放射性样品的压片压力、粒径、含水率、用量等处理条件到进行单因素实验。在400MPa压力下压制,克服了低压制样的弊端,制备的样片表面光滑、致密,大幅改善了制样重现性,有效地减少了部分基体效应,铀校准曲线的标准偏差从0.053%降到0.0071%,钍校准曲线的标准偏差从0.062%降到0.0057%。经国家一级标准物质验证,表明方法准确、可靠,能满足样品中铀、钍含量日常分析要求。

  • 标签: X射线荧光光谱法 同时测定 粉末制样