简介:Theabinitiomolecularorbitalmethodisemployedtostudytheenantioselectivereductionofacetophenonewithboranecatalyzedbythiszolidino[3,4-c]oxazaborolidine.Computationresultshowsthatthecontrollingstepforthereductionisthedecompositionofthecatalyst-alkoxyboraneadductandthereductionleadstoS-alcohols.ThetransitionatateofthehydridetransferfromtheboranemoietytothecarbonylcarbonofacetophenoneisatwistedchairstructurewithaB(2)-N(3)-BBH3-HBH3-CCo-OCO6-memberedring.
简介:Grapheneistwodimensionalmaterialswhichismadeofhoneycombedcarbonatoms.Itattractsextensiveinterestsforitswonderfulcharacteristicsthatmakethegrapheneapotentialcandidateinfieldsofmicroelectronicsproduction,moleculedetection,desalinationandDNAsequencing.Highlychargedion(HCI)hashugepotentialenergyforpeelingoffelectrons.Wheninteractingwithsolidsurface,theHCIdistortedthesolidlatticeviapotentialdepositionandthenthenanostructureswereformedonthesolidsurface.TheHCIwasexpectedasatoolforsurfacemodification.Inthiswork,HOPGandgraphemewereirradiatedwithXeq+andArq+ions.ThetypicalRamanspectraofgrapheneandHOPGirradiatedwithhighlychargedionswereshowninFig.1.TheDpeakappearedat1335cm??1onthespectraofgrapheneirradiatedwithhighlychargedions.TheintensityofDpeakincreasedwithfluence.TheratioofintensityofDpeaktothatofGpeakvariedwithfluenceinFig.2.Theratioroselinearlywiththesquarerootoffluencewhenfluencewaslow.Theratiosaturatedwhentheirradiationfluencewashigh.Thecriticalfluencedependedonthechargestateofion.Thehigherchargestateitwas,thelowercriticalfluenceitwouldbe.
简介:MicrodosimetricSpectrumandRadialDoseDistributionof239PnorRayinCH4Gas¥ZhuLianfang;LiXuekan;ChenXuebing;HeYusheng;SuYouwuand...
简介:Duetolowactivationcharacteristics,desirablehigh-temperaturestrength,goodresistancetoradiationdamageandusablefabricationproperties,vanadium(V)alloysareattractivecandidatestructuralmaterialsforfusionreactors[1].Irradiationinducedhardening/embrittlementatlowtemperatureisamajorproblemforthematerialsapplicationinfusionreactor[2].Inthisstudy,H/Heionswithvariousenergieswereusedtoirradiateapurevanadium(V)andaValloy(V-4Ti)toobtainadamageplateaufromsamplesurfacetothedepthof1.5m,asshowninFig.1[3].Thedetailsofirradiationparameters(energies,fluences)forHandHeionsareshowninTable1.NanoindentationwasperformedtoinvestigatethehardeningbehaviorofV-4TialloyandpureVunderirradiation.
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简介:Recently,Cristofaro-GardinerandHutchingsprovedthatthereexistatleasttwoclosedcharacteristicsoneverycompactstar-shapedhypersufaceinR~4.ThenGinzburg,Hein,Hryniewicz,andMacarinigavethisresultasecondproof.Inthispaper,wegiveitathirdproofbyusingindexiterationtheory,resonanceidentitiesofclosedcharacteristicsandaremarkabletheoremofGinzburgetal.
简介:SYNTHESISOF3-ARYL-1(2H,4H)ACRIDONESANDTHEIRDERIVATIVES¥RongYIN;GuangFanHAN;YuTianLI(DepartmentofMedicalLaboratory,JilinMediea...
简介:Thenanomaterialsoftenexhibitveryinterestingelectrical,optical,magnetic,andchemicalproperties,whichcannotbeachievedbytheirbulkcounterparts[1-7].Thedevelopmentofuniformnanometersizedparticleshasbeenintensivelypursuedbecauseoftheirtechnologicalandfundamentalscientificimportance[8-15].Itissignificantthatnanostructuredmaterialscanbecontrollablyassembledintotherequiredgeometryontosubstrates,becomingthebasisofthenextgenerationofcomponentsanddevices[16-31].Thedevelopmentofnewmethodsandstrategiesfororganizingthenanoparticlebasicbuildingblocksintothedesiredstructuresisrequired.Superlatticesmadefromthesebuildingblocksgiveustheopportunitytostudynotonlythepropertiesoftheindividualbuildingblocks,butalsocollectiveeffects.Thesuperparamagneticironoxidenanocrystals(NCs)havebeenusedinthefieldsofbio-medicine,ferrofluids,refrigerationsystem,catalysis,particularlyinmagneticresonanceimaging,tissueengineering,anddrugdeliveryapplications[32-42].
简介:Graphitic碳氮化物(g-C3有向在可见轻照耀下面的4-nitrophenol的降级的高photocatalytic活动的N4)被蚀刻的HCl准备由氨中立化列在后面。准备样品的结构,形态学,表面区域,和photocatalytic性质被学习。在处理以后,g-C3N4从几测微计减少了到几百纳米,和g-C3N4从11.5 增加了;m2/g到115 ;m2/g。同时,g-C3N4显著地在可见的光下面向4-nitrophenol的降级在处理以后被改进照耀。小粒子g-C3N4是5.7次体积g-C3为水处理和环境补习为未来应用使它成为有希望的可见轻光催化剂的N4,。
简介:TheenergyresponsesofKaoftwotypesofcylindricalG-Mcountertubeswerecalculatedusinganelectron-photoncascadeMonteCarlocode,EGS4.OnetypeoftheG-McountertubeswasGJ4401(sensitivelength9cm,diameter1cm),theotherwasJ5(sensitivelength2cm,diameter0.3cm),therestrictedsamplingtechniqueofsourcephotonwasused.Goodtendencyagreementsbetweenthesimulationsandexperimentswereachievedforgammaradiationwithenergiesrangingfrom40keVto1.25MeV.ForGJ4401,thedifferenceofresponsebetweensimulationsandexperimentsat662keVwas34%andforJ5thedifferencewas27%.
简介:Highlychargedions(HCIs)carryingamountofpotentialenergywillproducesomenewphysicalphenomenabecausethepotentialenergywillbedepositedintoaverysmallvolumewithinaveryshorttime.WewouldapplythecalorimetricmethodtostudytheenergydepositionofHCIs[1;2].Hereinweintroducethenewsetupforcalorimetricmeasurementforthepotentialenergydepositionofhighlychargedionsat320kVHighlyChargedIonsPhysicsExperimentalPlatform.Thesetupwasconstructedby3parts:theDewar,theelectricaltemperaturecontrollerandthemainpart.ThediamondtargetwasconnectedtotheLN2cooledheatsinkby4copperwiresandaPlatinumtemperaturesensorwasgluedtotherearsideofthetarget.AsshowninFig.1.
简介:Two-dimensional(2-D)BiVO4nanosheets-graphene(GR)compositeswithdifferentweightadditionratiosofGRhavebeenpreparedviaafacilewetchemistryprocess.X-raydiffraction(XRD),Ramanspectra,X-rayphotoelectronspectra(XPS),UV-visdiffusereflectancespectra(DRS),field-emissionscanningelectronmicroscopy(FE-SEM),transmissionelectronmicroscopy(TEM),nitrogenadsorption-desorption,transientphotocurrentresponseandphotoluminescence(PL)spectrawereemployedtodeterminethepropertiesofthesamples.ItisfoundthatBiVO4nanosheetscouldpavewellonthesurfaceofgraphenesheets.BiVO4nanosheets-GRcompositeswithaproperadditionamountofGRexhibitedhigherphotocatalyticactivitythanbareBiVO4nanosheetstowardliquid-phasedegradationofrhodamineB(RhB)andmethylorange(MO)undervisiblelightirradiation.TheenhancementofphotocatalyticactivitiesofBiVO4nanosheets-GRcompositescanbeattributedtotheeffectiveseparationofphotoexcitedelectron-holepairs.Thisworknotonlyprovidesasimplestrategyforfabricatingspecific2-Dsemiconductor-2-DGRcomposites,butalsoopensanewwindowofsuch2-Dsemiconductor-2-DGRcompositesasvisiblelightphotocatalyststowardanimprovedvisiblelightphotoactivityinpurifyingpollutedwaterresources.
简介:Thedifferentregioselectiveandstereoselectiveproductswereobtainedbythereductionofstigmast-4,22-dien-3,6-dionewithNaBH4-CH3OHwhendifferentkindsofmetalionswasaddedtothereaction.
简介:Well-dispersedBaSO4nanoparticlesweresynthesizedinthepresenceofsodiumpolyacrylate(PAAS)byasimpleprecipitationmethod,withBaCl2and(NH4)2SO4asreactants.ThedifferentrolesperformedbyPAASinthesynthesisofBaSO4nanoparticleswereinvestigatedusingX-raydiffractometry,Fouriertransforminfraredspectroscopy,andtransmissionelectronmicroscopy.TheresultsindicatethattheassynthesizedBaSO4nanoparticlesweresphereswithanaveragediameterof30nmandthattheirsurfaceswereaffectedbythePAAS.Underatypicalprocedureemployed,PAASreactedwithBaCl2toyieldanintermediate,servingasacontrolreleasingagentandseparatingthenucleationandcrystalgrowthprocessesoftheBaSO4nuclei.DuringformationoftheBaSO4nanospheres,theintermediateslowlydissolvedandreleasedbariumandpolyacrylateions,inhibitingthegrowthandaggregationofnewlyformedBaSO4seedsandresultinginparticlesofnarrowdiameterdistributionandimproveddispersibility.Moreover,thesepolyacrylateionsfurthermodifiedthesurfacesoftheBaSO4nanoparticles.
简介:SYNTHESIS AND SPECTRA STUDIES OF TRANSITION METAL COMPLEXES DERIVED FROM 2, 4-DINITROPHENYL HYDRAZINESYNTHESISANDSPECTRASTUDI...