简介:Aneffectivedispersion-strengtheningphaseinAl-8Fe-2Mo-2Zr-2Nd-0.7Ti-1.6SialloywasidentifiedtobeanagedprecipitatephasewithpossiblechemicalstoichiometryofAl20(Ti,Mo)2Ndandfcccrystalstructurewithao=1.455nm.ThestructurewasdeterminedtobeFm3mspacegroup.
简介:Pb-B-Si系低熔点玻璃是一种具有较好封接性能的玻璃粉,将其应用在不锈钢真空保温容器无尾封接中存在真空烧结时气泡消除缓慢、强度不够等问题。通过对Pb-B-Si系玻璃进行配方优化调节后,对玻璃粉进行性能检测,对焊点形貌等进行研究,采用扫描电镜分析了烧结层的微观结构。结果表明,优化后的配方体系为Pb-B-Si-ZnAl-CuO,其中Pb为83%,CuO为3.5%(质量分数)时,可以显著提高无尾封接时的强度,提高真空度。使用该玻璃粉生产的不锈钢真空容器的焊点饱满、光亮,接头强度好,无明显缺陷,显示其对不锈钢容器良好的封接强度。
简介:Sodiumparanitrophenolatedihydrate(NPNa·2H2O)isanexcellentsemiorganicnonlinearoptical(NLO)material,crystallizesbothinwaterandmethanolwithhighdegreeoftransparency.Goodopticalqualitysinglecrystalsofdimensionupto18mmx6mmx3mmareobtainedbyisothermalsolventevaporationtechnique.Thesolubilityofthecrystalindifferentsolventswasmeasuredgravimetrically.ThesinglecrystalsofNPNa·2H2Oshowvariationinphysicalpropertiesandgrowthrateindifferentsolvents.Methanolorethanolsolutionyieldscrystalsofbipyramidalshapewithclearmorphology.However,methanolgrowncrystalisexhibitingimprovedhardnessparametersandpossessesexcellentthermalstabilityascomparedtowatergrowncrystals.TheeffectsofsolventonhardnessparameteralongwiththermalandopticalpropertiesofNPNa·2H2Owasrevealedinthispaper.
简介:Ag-TiAlintermetallicalloy,Tie45Ale2Nbe2Mn(at.%)e0.8vol.%TiB2,hasbeenprocessedfromgasatomizedprealloyedpowderbyfieldassistedhotpressing(FAHP).Aninitialanalysisoftheprealloyedpowderhelpedontheunderstandingoftheintermetallicsinteringbehavior.Atomizedpowderconsistedofametastablephasethattransformedintoa2tgequilibriumphasesbythermaltreating.Differentpowderparticlemicrostructureswerefound,whichinfluencethemicrostructuredevelopmentoftheFAHPg-TiAlmaterialdependingonthesinteringtemperature.Duplex,nearlylamellarandfullylamellarmicrostructureswereobtainedatthesinteringtemperaturesabove1000C.Lowerconsolidationtemperatures,below1000C,ledtotheformationofanAlrichphaseatpowderparticleboundaries,whichisdeleterioustothemechanicalproperties.Highcompressiveyieldstrengthof1050MPawasobservedinsampleswithFAHPduplexmicrostructuresatroomtemperature.Whereasnearlylamellarandfullylamellarmicrostructuresshowedyieldstrengthvaluesof655and626MPaatroomtemperatureand440and425MPaat750C,respectively,whicharesuperiorincomparisontosimilaralloysprocessedbyothertechniques.Theseexcellentpropertiescanbeexplainedduetothedifferentvolumefractionsofthea2andgphasesandtherefinementofthePMmicrostructures.
简介:以3种煤沥青为研究对象,采用元素分析、平均分子量、核磁共振氢谱(1H—NMR)以及红外光谱分别对其进行表征和分析,使用改进Brown-Ladner法对煤沥青的结构参数进行计算,并构建出各煤沥青的平均分子结构模型。结果表明,煤沥青的基本结构单元是稠环芳烃连接烷基侧链并含杂原子,结构单元之间形成缔合体,缔合数为5~9。3种煤沥青的烷基侧链都很短,且均不包含环烷烃。构建的分子模型为煤沥青提供了形象的化学结构,有助于从分子水平加深对其认识和研究。
简介:研究了NaCl—MnO2改性沸石填料柱对水中Zn^2+的动态吸附性能。探讨了填料厚度、Zn^2+的初始质量浓度和流速对穿透曲线的影响。结果表明,NaCl-MnO2改性沸石能有效去除水中的zn^2+,填料层增厚,穿透曲线上的穿透点向右移动,穿透时间延长;而流速、Zn^2+的初始浓度增大,穿透曲线上的穿透点向左移动,穿透时间缩短;用Thomas模型描述Zn^2+初始质量浓度为50mg/L、滤速为4mL/min时改性沸石对Zn^2+的吸附动力学,相关系数为0.9994,平衡吸附容量为12.04mg/g。