简介:Wateristhemostactivecomponentinallgeologicalsystems.Ithasanimportanteffectonthephysicalpropertiesofmineralsandmelts.ItalsoplaysakeyroleintheevolutionoftheEarth.Accuratethermodynamicsdataonwaterarecurrentlyconfinedtopressuresbelow1.0GPaandtemperaturesbelow900℃.PresentedinthispaperarenewdataavailableontheP-Tpropertiesofwateratpressuresupto5.0GPa,develogedfromdifferentialthermalanalysisandultrasonicwaveamplitudeanalysis.Ithasbeenfoundthattheremayexistanotherternarypointat3.0GPaandthatultrasonicwaveamplitudechangeofice-watertransitionshowstwoinflectionpointsabove2.0GPa,consistentwiththetwopeaksofdifferentialthermalcurvesabove2.0GPa.Itmaybeanewphenomenonwhichneedsfurtherstudy.
简介:Theanalysisofstableisotopesofcarbonandoxygenindifferentcarbonaterocksbythephosphoricacidmethodisnoteasierthanthatbythelasersamplingmethoddevelopedinrecentyears,whichopticallyfocuseslaserbeamswithsufficientenergyonamicroareaofathinsectioninavacuumsampleboxviamicroscope.CO2producedbyheatingdecompositionofcarbonatewaspurifiedbythevacuumsystem,andthestableisotopicvaluesofcarbonandoxygenwerecalculatedandanalyzedonamassspectrometer.Thispaperadoptedthelasermicro-samplingtechniquetoanalyzethestableisotopesofcarbonandoxygenindolomite,carbonatecement,stromatoliteanddifferentformsofdawsonite(donbassite).Resultsindicatedthatthelasermicro-samplingmethodiseffectiveinanalyzingcarbonatecompositionandcouldbeaconvincingproofforjustificationoncarbonatecompositionanalysis.
简介:WithwellsPuguang2and6inthePuguanggasfieldastheresearchobjectsbychoosingorganiccarbonascharacterizationreservoircarbon(indirectlyreflectingthebitumencontents),thispaperdiscussestherelationshipbetweenbitumencontentsandlithologiccharacteristics,reservoircharacteristics,andcalculatesthevolumeofpaleo-oilandoilcrackedgas.Thestudyshowsthattheorganiccarboncontentsofthereservoirsarerelatedtolithologiccharacteristics.Duetovariationsintheparticlesizeorstructureofrocks,theporosityofthereservoirsvaries,furthermore,itwillinfluencethecontentsoforganiccarbon.Andtherelationshipbetweenthesetwoparametersispositive.Basedontheanalysis,therelationshipbetweentotalorganiccarbon(TOC)andthecontentsofreservoirbitumenalsoappearstobepositive.Thevolumeofpaleo-oilandcrackedgasoftheChangxing-Feixian’guanFormationarerespectively495milliontonsand360.4billionm3throughthecalculationofreservoir’sorganiccarbon.Therefore,therelationshipbetweencarbon-bearingrateandcharacteristicsofthereservoirscanbeusedtoindirectlyevaluatereservoirtypes.Besides,thecarbon-bearingrateofthereservoirsalsoreflectsthecontentsofreservoirbitumen,paleo-oilaswellasnaturalgas.Itmakesanewapproachforthestudyofthetypesofreservoirsandtheamountsofpaleo-oilandoilcrackedgasinnortheasternSichuanBasin.
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