学科分类
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28 个结果
  • 简介:Theefficiencyofthepoly(3-hexylthiophene)(P3HT)and[6,6]-phenylC61-butyricacidmethylester(PC61BM)basedorganicsolarcellswasenhancedbyusing1,2,4-trichlorobenzene(TCB)asaprocessingadditivetocontroltheblendmorphology.TheadditionofTCBimprovedthearrangementofP3HTwhichresultedingoodphaseseparatedblendfilms.Correspondingly,theoptimizedsolarcellsshowedapowerconversionefficiency(PCE)of4.17%withafillfactor(FF)of0.69,whichwerehigherthanthoseofcommonthermalannealingdevices(PCE3.84%,FF0.67).Theefficiencywasfurtherimprovedto4.74%bythermalannealingat150°Cfor10minwithahigherFFof0.74.

  • 标签: 器官的太阳能电池 CRYSTALLINITY 添加剂 形态学
  • 简介:一个非水暂停polycondensation方法被建议继续为准备p-phenylenediamine和terephthaloyl氯化物反应poly(p苯撑terephthalamide)(PPTA)。系统与NMP-CaCl被操作<潜水艇class=“a-plus-plus”>是的2答案驱散阶段和是的惰性液体石蜡连续阶段。每NMP-CaCl<潜水艇class=“a-plus-plus”>在石蜡推迟2答案microdroplet用作polycondensation发生了microreactor。根据TGA,XRD,红外,SEM和EA结果,有好质量PPTA通过这个新奇方法被获得,并且影响这个过程很多个主要因素被调查为PPTA准备决定最佳条件。而且,这个二阶段polycondensation系统与常规解决方案polycondensation方法相比带给许多唯一优点,包括使反应物离开氧和水封上反应环境,HCl到容易移动支持更少精力花费了工具反应,控制得好温度和低粘性。

  • 标签: 对苯二甲酰胺 液体石蜡 水悬浮 亚苯基 系统 制备
  • 简介:Two-dimensional(2D)materialshavebeendemonstratedtoexhibituniquepropertiesoriginatingfromits2Dnature.Inrecentyears,theconstructionof2Dmaterialshasbecomeatopicofgreatinterest.Thisarticlesummarizestherecentadvanceof2Dsupramolecularorganicframeworks(SOFs)whicharehomogeneouslyconstructedinsolutionphasethroughself-assemblyofrationallydesignedbuildingblocks.These2DSOFsaresolubleandstillmaintainstablenetworkstructuresinsolutions,whichexhibituniquenessnotonlyinstructuresbutalsoinproperties.Inthisconcisereview,theSOFs-relatedbackgroundisbrieflyintroducedfirstly,followedbyoutliningtheresearchprogressofsoluble2DSOFsfromtheperspectiveofmonomerdesign,assembly,andstructuralcharacterization.Thearticleendswithapersonaloutlookonthefuturedevelopmentofthisnewclassofsupramolecularpolymers.

  • 标签: SUPRAMOLECULAR organic frameworks(SOFs) SELF-ASSEMBLY TWO-DIMENSIONAL SUPRAMOLECULAR
  • 简介:N-acetyl-D-methionine,NaAcandtheremainsofN-acetyl-L-methioninedramaticallyaffectthepurificationofL-methioninewhenpurifiedfromthemixtureofenzymaticallydeacylatedN-acetyl-DL-methionine,leadingtoalowyieldconventionally.Here,thispaperreportsasuccessfulseparationandpurificationofbothL-methionineandN-acetyl-D-methioninebyanHion-exchangecolumn.ThepH,L-Metconcentrationandtheratiobetweenthecontentofsodiumcationandtheion-exchangecapacitywereoptimizedtoobtainthemaximumyield.Experimentalresultsindicatethat,undertheoptimizedconditions,theyieldsofL-methionineandN-acetyl-D-methioninecanreachashighas85%and75%,respectively.

  • 标签: L-蛋氨酸 N-乙酰基-D-蛋氨酸 N-乙酰基-DL-蛋氨酸 分离 纯化 脱酰作用
  • 简介:TheexchangebehaviorsofWO4^2-,MoO4^2-,H2W12O46^6-andMo8O26^4-anionswithinmacroporousexchangeresin(D290)phaseshavebeenstudied.Thevaluesofdiffusionconstant(B),innerdiffusioncoefficient(D^-),retartedtime(τd)half-exchange-period(t1/2),andactivationenergy(ΔE)werefoundfromthekineticanalyses.AnewmethodtoseparateW(VI)andMo(VI)fromeachotherwasalsosuggested.

  • 标签: 动力学 交换反应 钨(VI) 钼(VI) 大孔阴离子交换树脂(D290)相
  • 简介:无论是以前村民代表大会,还是现在议事会,其面临主要问题,都是如何解决决策权虚设问题高仁天被逼着做了一次"官"。这个已经做了14年司机邛崃市油榨乡马岩村农民,去年3月底被同组村民推举

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