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500 个结果
  • 简介:电子结构和硫在钾dihydrogen磷酸盐(KDP)代替的黄磷的几何分发被第一原则的计算调查。点缺点在精力差距下面变窄到大约4.9eV,相应于在修正以后的355nm的二光子的吸收。这能在KDP晶体解释激光损坏抵抗的减少。而且,缺点扭曲水晶结构并且削弱契约,特别O-H契约,这些契约可以因此是第一个地点在激光照耀下面裂开。[从作者抽象]

  • 标签: KDP晶体 晶体缺陷 第一性原理 磷酸二氢钾 第一原理计算 双光子吸收
  • 简介:该规划的目的是重新研究物理教育的内容和结构,这是由于在三个方面有了重大的发展:①过去的三十年里,物理知识爆炸性地增长;③认知心理学的研究,对学习进程有了新的认识,③计算机技术及其功能不断提高。

  • 标签: 课程发展 示范性 教育技术 物理知识 物理教育 大学物理
  • 简介:Uptothisdate,researchersarestillfacingdifficultiestoexpandthetechnologyofdirectmethanolfuelcells(DMFCs)becauseofthehighoverpotentialrequiredtooxidizethemethanolanditsrelativelypoorperformanceduetoCOpoisoningoftheleading-highcostanodecatalyst.Inlinewiththis,wehavesuccessfullymodifiedthemorphologicalstructureandcompositionoflowcostcobaltbased-metaloxides,MCo2O4(M=ZnandNi),withthesimpleandnobleuseofpolyvinylpyrrolidone(PVP)asgrowthmodifierandsurfacestabilizerduringthesynthesisofnanoparticlesinourpreviousreports,whichshownhighelectrocatalyticactivityandstrongstability.DuetothegoodperformanceofourPVPmodifiedMCo2O4towardspseudocapacitorandoxygenevolutionreactionapplications,wedecidedtoextendourresearchstudytomethanoloxidationreaction.Remarkably,PVPmodifiedNiCo2O4electrodedirectlygrownonnickelfoamsubstrateviaasimplehydrothermalprocessexhibitedbetterperformancecomparedwithPVPmodifiedZnCo2O4andNiCo2O4withoutPVP.Ithadobtainedaremarkablylowonsetpotentialof0.285Vandhighcurrentdensityof280mAcm-2,andshowngreatstabilityandhighpoisontoleranceduringacontinuousCVcyclingandChronoamperometrytest,whichattainedhighefficiencyof86.86%and98.52%,respectively.ThesepositiveresultsofPVPmodifiedNiCo2O4electrodetowardsMORmightbeattributedtoitshierarchical3Dnanostructureswithhighlymesoporoussurfaceandlargesurfaceareawhichmayhaveprovidednumerouselectroactivesites,andtheexceptionalcorrosionstabilityofNiCo2O4electrodeinalkalinesolution.

  • 标签: NiCo2O4 3D NANOSTRUCTURE ELECTROCHEMICAL METHANOL oxidation
  • 简介:Wehavedevelopedanewradiographysetupwithashort-pulselaser-drivenx-raysource.Usingaradiographyaxisperpendiculartobothlong-andshort-pulselasersallowedoptimizingtheincidentangleoftheshort-pulselaseronthex-raysourcetarget.Thesetuphasbeentestedwithvariousx-raysourcetargetmaterialsanddifferentlaserwavelengths.Signaltonoiseratiosarepresentedaswellasachievedspatialresolutions.ThehighqualityofourtechniqueisillustratedonaplasmaflowradiographobtainedduringalaboratoryastrophysicsexperimentonPOLARs.

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  • 简介:Itisimpossibletodirectlyanalyzethemicrostructureofspin-valvemultilayersbasedonNi,F,CuandMnbyaconventionalX-raydiffractiontechniquebecausethelatticeparameterandatomicsatteringfactorsofthemareveryclose.Tosolvethisproblem,weuseanx-rayanomalousdiffractiontechniquetocharacterizethemicrostructuresofthe[Ni80Fe20/Fe50Mn50]15and[Ni80Fe20/Cu]15superlatticesystems.Theresultsshowthatmorediffractionpeaksandhigherinternsityinthereflectivetyprofileareobservedwhentheincidentenergyisclosetotheabsorptionedgeofthelighterelement(Mn)in[Ni80Fe20/Fe50Mn50]15multilayersystemsandtotheabsorptionedgeoftheheavierelement(Cu)inthe[Ni80Fe20/Cu]15multilayersystems.Theinterfaceandperiodicstructureof[Ni80F20/Fe50Mn50]15aremoreperfectthanthatofthe[Ni80Fe20/Cu]15superlattices.Theaboveresultsaredisussedinthispaper.

  • 标签: X射线衍射分析 微观结构 超晶格 原子分布
  • 简介:Small-angleX-rayscattering(SAXS)usingsynchrotronradiationasX-raysourcehasbeenemployedtocharactcizcthemicroscopicstructrureoforgano-modifiedmesoporousmolecularsieves(organo-MSU-X)preparedbyaone-pottemplate-directedsynthesis.ItisshownthattheSAXSprofileishardlyconstantwithPorod’slawshowinganegativeslope,i.e.,negativedeviation.Thissuggeststhatthereisdiffuseinterfaciallayerlocatedbetweentheporesandthematrix.Thissuggeststhattheorganicgroupsremaincovalentlylinkedtothematrix,asindicatedby^29SiCPMASNMRandFT-IR.Theaveragethicknessoftheinterfaciallayerwasfoundtobeabout1nmforeachofthethreesampleswithdifferentkindsandthesameamounts(20?oforganicgroups.Thiskindofmaterialhasalsobeenprovedtopossessbothsurfaceandmassfractalstructureoftheamophousporoussilicamaterials.2001ElsevierScienceB.V.Allrightsreserved.

  • 标签: 中孔材料 SAXS 小角X射线散射分析 界面层 结构特征 有机中孔分子筛
  • 简介:ThispaperprovidesareviewonsampleinjectorswhichareprovidedatSPring-8AngstromCompactfreeelectronLAser(SACLA)forconductingserialmeasurementina‘diffract-before-destroy'schemeusinganx-rayfreeelectronlaser(XFEL).VersatileexperimentalplatformsatSACLAareabletoacceptvarioustypesofinjectors,amongwhichliquidjet,dropletandviscouscarrierinjectorsarefrequentlyutilized.Theseinjectorsproducedifferentformsoffluidtargetssuchasaliquidfilamentwithadiameterintheorderofmicrometer,micro-dropletsynchronizedtoXFELpulses,andslowlyflowingcolumnofhighlyviscousfluidwitharatebelow1μLmin-1.Characteristicsandapplicationsoftheinjectorsaredescribed.

  • 标签: SACLA 样品注射者连续剧 femtosecond 晶体学 X 光免费电子激光
  • 简介:O434.122006065468强脉冲软X光辐照薄塑料闪烁体发光特性研究=LinearluminescenceforthinplasticscintillatorsunderintensesoftX-rayirradiation[刊,中]/宁家敏(中物院核物理与化学研究所.四川,绵阳(621900)),蒋世伦…//强激光与粒子束.—2006,18(7).—1215-1218介绍了Z-pinch实验用软X光功率仪的测量原理,利用“强光一号”产生的强脉冲软X光对薄塑料闪烁体((?)40min×0.1mm)进行了辐照。实验中,采用两套软X光功率仪并安装在同一个大法兰面上.其中一套作为标准系统,参数保持不变,另一套系统的狭缝宽度逐渐增加,以改

  • 标签: 射线 强脉冲 塑料闪烁体 玻璃毛细管 强激光 光辐照
  • 简介:在北京同步辐射装置上应用同步辐射X射线小角散射技术研究TATB样品微孔状况,分析了微孔结构参数的变化。采用不同制备工艺(机械研磨、化学合成、气流细化、全结晶、粉碎)和不同存放时间的TATB粉末样品共计7份。

  • 标签: TATB钝感炸药 小角X射线散射 结构参数 制备工艺 逐步回归法
  • 简介:介绍了辐射模拟加速器辐射场中脉冲X射线能谱的几种常用测量方法,阐述了基本原理、测量装置的典型系统组成、主要参数特性、技术发展状况和研究进展,描述了各种方法的优缺点和适用范围。以吸收法为例,综述了解谱技术的发展状况,并描述了多种解谱方法的特点。最后,重点介绍了西北核技术研究所脉冲X射线能谱测量的进展,并对测量系统抗噪和散射控制技术进行了评述。结合现有条件和技术成熟度,对今后工作的发展方向进行了展望。

  • 标签: 脉冲X射线 能谱 吸收法 解谱方法