简介:用微波高温固相法合成了Er^3+单掺Lu2O3,Li^+与Er^3+共掺Lu2O3及Li^+,Zn^2+,Mg^2+掺杂Lu2O3∶Er^3+的荧光粉。实验表明金属离子Li^+、Zn^2+、Mg^2+、Er^3+掺杂Lu2O3,不影响Lu2O3的立方晶相。扫描电子显微镜测量表明,Li^+掺杂可以有效改善粉体的分散性和形貌,Li^+,Zn^2+,Mg^2+共掺杂获得的粉体颗粒分布更加均匀,粒径范围为80~100nm。379nm激发下,Li^+与Er^3+共掺样品发光较单掺Er^3+样品在565nm处的发光增强了4.5倍,而Li^+、Zn^2+、Mg^2+与Er^3+共掺样品较其发光增强5.3倍。980nm激发下,Li^+与Er^3+共掺样品,Li^+、Zn^2+、Mg^2+与Er^3+共掺样品的发光分别比单掺Er^3+样品在565nm处发光增强23倍与39倍,在662nm处发光强度分别增强20倍与43倍。379nm激发下,较单掺Er3+的样品,掺杂Li^+的样品和Li^+,Zn^2+,Mg^2+和Er^3+共掺的样品荧光寿命均有所增加,而Zn^2+、Er^3+共掺及Mg^2+、Er^3+共掺样品的荧光寿命则有所缩短。
简介:Nuclearmassisoneofthefundamentalquantityofatomicnucleus.Thetotalbindingenergyofanucleusderivedfromtherelatedmassvaluesreflectsalltheinteractionsamongtheconstitutingnucleons.Massesofshort-livedA=2Z+3nucleiof112SnprojectilefragmentshavebeenmeasuredattheexperimentalcoolerstorageringCSRe,employingtheIsochronousmassspectrometry(IMS).TheexperimentwasconductedattheHeavyIonResearchFacilityinLanzhouatthebeginningof2016.Theprimarybeamof112Sn35+wasaccumulatedinthesynchrotronCSRmandacceleratedto467.91MeV/u.Secondarybeamwereproducedbyimpingingthehighintensity112Sn35+beamontoa10mmberylliumtargetwhichwaslocatedattheentranceoftheradioactivebeamlineRIBLL2.Theprojectilefragmentsof112Snemergedfromthetargetwerethentransmitted,separatedinflightthroughRIBLL2andfinallyinjectedintoCSRe.
简介:Weperformfirst-principlecalculationsforthestudyoftheorthorhombicRb2Cd2(SO4)3structure.Electronicenergybands,totalandpartialdensitiesofstatesarereportedandanalysed.Itisfoundthatoxygenatomic2pelectronsstronglyhybridizewithRb/orCd4dandS2pstates,resultingintwo-typeionicgroupswithweakcouplings.Itisshownthatmacroscopicdomainwallsoriginatefromsuchweak-couplingionicgroups,arisingatthecellboundaries.Theasymmetriccationbonds(Rb-OandCd-O)andthesubsequentrotationsoftheS04tetrahedracanleadtothedrivingforceoftheferroelectricbehaviour.Thepredictedpyroelectriccurrenteffectsareobservedexperimentallyintheferroelectricphase.
简介:研究了YBaCu3O6~7超导催化剂上CO2的加氢制醇反应。考察了温度、压力和空速等条件对催化剂反应性能的影响。反应的主要产物是甲醇、CO和少量甲醚。利用XPS、XRD和AFM等技术对催化剂的结构、铜的存在状态和反应活性位进行表征发现,在反应过程中,YBa2Cu3O6~7由orthombic相转变为tetragonal相。反应活性位可能是Cu(I)物种。反应后催化剂颗粒的分散程度明显提高
简介:Amolybdenumdisulfide(MoS2)saturableabsorberwasfabricatedbythermallydecomposingtheammoniumthiomolybdate.ByusingtheMoS2absorber,acompactdiode-pumpedpassivelyQ-switchedTm:GdVO4laserhasbeendemonstrated.AstableQ-switchedlaserwithrepetitionratesfrom25.58to48.09kHzwasachieved.Maximumaverageoutputpowerwas100mWwiththeshortestpulsedurationof0.8μs.Maximumpulseenergyis2.08μJatcenterof1902nm.
简介:Theroleofpulseparametersonnanoparticlepropertyisinvestigatedself-consistentlybasedonacoupleoffluidmodelandaerosoldynamicsmodelinacapacitivelycoupledparallel-plateacetylene(C2H2)discharge.Inthismodel,themasscontinuityequation,momentumbalanceequation,andenergybalanceequationforneutralgasaretakenintoaccount.Thus,thethermophoreticforceariseswhenagastemperaturegradientexists.Thetypicalresultsofthismodelarepositiveandnegativeiondensities,electronimpactcollisionsrates,nanoparticledensity,andchargedistributions.Thesimulationisperformedfordutyratio0.4/0.7/1.0,aswellaspulsemodulationfrequencyfrom40kHzto2.7MHzforpureC2H2dischargesatapressureof500mTorr.Wefindthatthepulseparameters,especiallythedutyratio,haveagreataffectonthedissociativeattachmentcoefficientandthenegativedensity.Moreimportantly,bydecreasingthedutyratio,nanoparticlesstarttodiffusetothewall.Undertheactionofgasflow,nanoparticledensitypeakiscreatedinfrontofthepulseelectrode,wherethegastemperatureissmaller.
简介:Thenotionofmultibandsuperconductivitywithdominanttwo-gapfeatureshasbeenrecentlyappliedtotheunconventionalsuperconductorCeCu2Si2forchallengingthepreviouslyacceptedconceptofnodald-wavepairing.Intheproposedstudy,therealisticmultibandFermisurfacetopologyofCeCu2Si2wasobtainedthroughfirst-principlescalculations,andanalysiswasconductedwithaneffectivetwo-bandhybridizationmodelincludingdetailedbandstructure.WithintheT-matrixapproximation,theobtainedcalculationresultsshowthatdifferentpairingcandidates,includingfullygappeds-wave,loop-nodals-wave,andd-wavepairings,couldyieldqualitativelydistinctfeaturescharacterizedbyimpurity-inducedboundstates.Thesefeaturescanbeverifiedthroughhigh-resolutionscanningtunnelingmicroscopyorspectroscopyandprovidecorroborativejustificationthatwouldbebeneficialfortheongoingresearchregardingthesuperconductinggapsymmetryofCeCu2Si2atambientpressure.
简介:Lifetimemeasurementsoflow-lyingexcitedstatesin^87Zrhavebeenperformedviaβ-γcoincidences.The127MeV^32SbeamwasdeliveredfromtheSector-FocusingCyclotron(SFC)oftheHeavyIonResearchFacilityinLanzhou(HIRFL).Theparentnuclei^87Nbwereproducedbythereaction58Ni(32S,2p1n),atabeamenergy127MeVthrougha8umAldegrader.A200ug/cm^2layerof58Nievaporatedontoa200ug/cm^2thickcarbonfoilwasemployedasthetarget.Afterevaporationresidueswereseparatedfromtheprojectilebeamsbythegas-filledrecoilseparatorSHANS[1],thenucleiofinterest87Zrcanbeobtainedwithahigherpurityandthenwereimplantedintoa300umsilicondetector.
简介:HL-2AisanewdivertortokamakunderconstructionatSouthwesternInstituteofPhysics(SWIP),Chengdu,China,basedontheexperiencefromHL-1andHL-1M.HListheshorttermofaChinesewordthatmeans"ToroidalCurrentDevice".ThemainobjectivesofHL-2Aaretoproducemoreadaptabledivertorconfigurationstostudyenergyexhaustandimpuritycontrol(thefirstdivertortokamakplasmainChina),andtostudyenhancedplasmaconfinementbyprofilecontrolandmoderateplasmashaping.
简介:Atokamakplasmadischargeinvolvesaseriesofcomplexandconcertedactionsconductedbyitscontrolsystem.TheHL-2Acontrolsystemcanbedividedintotwopartst,themachinecontrolsystemandthedischargecontrolsystem.Themachinecontrolsystem,whichconsistsofindustrialPC(IPC),configuresandoperatesthetokamak'svarioustechnicalsubsystems.Timingsys-temisintegratedintomachinecontrolsystemgivingabsolutetimeforallsubsystems.Thedischargecontrolsystem,