简介:Frequency-doubledantireflectioncoatingssimultaneouslyeffectiveat1064nmand532nmweredepositedonthelithiumtriborate(LiB3O5orLBO)crystalsusingtheelectronbeamevaporationmethod.Comparingwiththesamplewithoutbufferlayer,itisfoundthattheadhesionofthesamplewithbufferlayerofSiO2betweencoatingandLBOsubstrateisimprovedsignificantlyfrom137.4mNtogreaterthan200mN.Andthelaser-induceddamagethresholdisincreasedby20%from15.1J/cm2to18.6J/cm2.ThestrengtheningmechanismofadhesionofthebufferlayerofSiO2isdiscussedbyconsideringfullplasticindentationandsheartheory.
简介:ZnMn2为抵抗随机存取存储器(RRAM)的O4电影被磁控管劈啪作响与不同设备结构制作。I-V特征,抵抗切换行为,耐力和ZnMn2O4电影被调查。ZnMn2象底部电极的O4电影,使用的希腊语的第二十三个字母和磅,展出双极的抵抗切换(BRS)行为处于低抵抗状态(LRS)处于高抵抗状态(HRS)和细丝传导机制由space-charge-limited传导(SCLC)统治了机制,但是ZnMn2用底部电极展出双极、单极的抵抗切换行为的n-Si的O4电影在幼虫由Poole-Frenkel(P-F)传导机制控制了Ag/ZnMn2O4/p-Si设备拥有最好的耐力和保留特征,交换周期的稳定的重复的数字在是超过1000,保留时间比106秒长。然而,最高的RHRS/R104的LRS比率和最低V在和V离开3.0的,V在Ag/ZnMn2O4/Pt设备。不过Ag/ZnMn2O4/n-Si设备也拥有最高的RHRS/R104,的LRS比率但是V在,V离开,RHRS和R象差的耐力一样的LRS,并且保留特征。
简介:Inthisstudy,theeffectofmulti-walledcarbonnanotubes(MWCNTs)additiveonthedehydridingpropertiesoftheZn(BH4)2/NaCIcompositepreparedbyhighenergyballmillingwereinvestigated.X-raydiffraction(XRD),Fouriertransforminfraredspectroscopy(FTIR)resultsdemonstratedthatZn(BH4)2wasproducedfrommechanochemicalreactionbetweenZnCI2andNaBH4.Comparedwiththeundopedsample,10wt%MWCNTseffectivelyloweredthedecompositiontemperatureofZn(BH4)2by15℃.Thecomplexreleased3.6wt%hydrogenwithin250sat100℃andtotallyreleased4.5wt%hydrogenwithin2500s,indicatingithasaconsiderablepotentialasahydrogenstoragematerial.
简介:TheeffectofPtandCuelectrodesontheresistiveswitchingpropertiesandfailurebehaviorsofamorphousZrO2?lmswereinvestigated.ComparedwithCu/ZrO2/Ptstructures,thePt/ZrO2/PtstructuresexhibitbetterresistiveswitchingpropertiessuchasthehigherresistanceratioofOFF/ONstates,thelongerswitchingcyclesandnarrowdistributionofOFFstateresistance(Roff).TheswitchingmechanisminthePt/ZrO2/Ptstructurecanbeattributedtotheformationandruptureofoxygenvacancy?laments;whileintheCu/ZrO2/Ptstructure,thereexistbothoxygenvacancy?lamentsandCu?laments.TheformationofCu?lamentsisrelatedtotheredoxreactionofCuelectrodeundertheappliedvoltage.TheinhomogeneousdispersiveinjectionofCuionsresultsinthedispersiveRoffandsigni?cantdecreaseofoperatevoltage.Schematicdiagramsoftheformationofconductive?lamentsandthefailuremechanismintheCu/ZrO2/Ptstructuresarealsoproposed.
简介:采用Gleeble-3800热模拟试验机对Zn-10Al-2Cu合金在变形温度为150~330℃、变形速率为0.01~10s-1条件下的流变行为进行研究。结果表明:Zn-10Al-2Cu合金在热压缩变形中,当应变速率一定时,流变应力随变形温度的升高而减小;而当变形温度一定时,流变应力随着变形速率的增大而增大,达到峰值后下降趋势平缓。Zn-10Al-2Cu合金的热压缩流变行为可用双曲正弦形式的本构方程来描述。在本实验条件下,该锌铝铜合金热变形应力指数n为5.4、热变形激活能Q为137kJ/mol,高温流变应力用含Zener-Hollomon参数的Arrhenius方程描述为:σ=123ln{(Z/(1.22×1013))1/5.4+[(Z/(1.22×1013))2/5.4+1]1/2}。
简介:在现在的学习,我们执行了-cyclodextrin的合成(用微波的-CD)functionalized金牌nanoparticles(AuNPs)帮助了在碱的媒介加热方法。CD的稳定的分散稳定的AuNPs在10.5的优化pH被获得。在这pH珍视CD的第二等的氢氧根组显示出的deprotonated向从而导致AuNP聚集的Pb2+离子的最高的chelating亲密关系。Pb2+在-CD-AuNP导致了聚集答案被比色的反应和紫外力的光谱学监视。TEM,DLS和FTIR分析被执行证实Pb2+离子在碱的条件下面导致了-CD-AuNPs的聚集行为。而且当时,在试验性的pH,向Pb2+离子的-CD-AuNP系统的反应是选择的与另外的介入的金属阳离子相比。
简介:利用溶剂热合成法成功制备出了形貌为准球形、棒形、球棒混合型和菱形,粒径在50nm以下、尺寸均一的锐钛矿型TiO2纳米晶,对合成出的纳米晶TiO2用荧光光谱,紫外/可见光吸收光谱进行光学性能表征,结果表明,TiO2纳米晶在330nm的激发光下,分别在345nm、363nm、380nm和402nm处存在4个发光峰位。在实验中,首次发现和证实了理论计算出的锐钛矿型TiO2纳米晶的两种直接跃迁发光,分别对应为X(1b)→X(2b)(345nm)和X(1b)→X(1a)(363nm),主要因为油酸改变了TiO2纳米晶的{001}晶面族晶面的表面态。TiO2纳米晶的紫外吸收峰位于229nm,且与其形貌无关;禁带宽度的计算值接近其理论值3.2eV。
简介:ForimprovingthepropertiesofSiC-mullitecompositeceramicsusedforsolarsensiblethermalstorage,MnO_2wasintroducedassinteringadditivewhenpreparing.ThecompositeceramicsweresynthesizedbyusingSiC,andalusite,α-Al_2O_3asthestartingmaterialswithnon-contactgraphite-buriedsinteringmethod.PhasecompositionandmicrostructureofthecompositeswereinvestigatedbyXRDandSEM,andtheeffectofMnO_2onthepropertiesofSiCcompositeswasstudied.ResultsindicatedthatsamplesSM1with0.2wt%MnO_2additionachievedtheoptimumproperties:bendingstrengthof70.96MPa,heatcapacityof1.02J·(g·K)-1,thermalconductivityof9.05W·(m·K)-1.ProperadditionofMnO_2wasfoundtoweakenthevolumeeffectofthecompositesandimprovethethermalshockresistancewithanincreasedrateof27.84%forbendingstrengthafter30cyclesofthermalshock(aircoolingfrom1100℃toRT).
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简介:为了研究Ca的含量对MgZnMnCa四元生物镁合金的组织和性能的影响,制备了Mg2Zn0.2MnxCa(x=0.1,0.4,0.7)合金,比较不同Ca含量的Mg2Zn0.2MnxCa的组织和腐蚀性能。结果表明,Mg2Zn0.2Mn0.4Ca合金的显微组织较好,平均晶粒尺寸约为100μm,第二相含量适中;Mg2Zn0.2Mn0.4Ca的镁合金耐腐蚀性较好,腐蚀速率为0.569mm/a。