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简介:Viaseveraltechniquestomodifysensitivematrixforinhabitingtheleakageoffluorescentindicator,anewstablesensingmaterialformonitoringphosphateshasbeenpreparedandappliedtothemeasurementofphosphatesinartificialseawater.ItisbasedonthereactionofPO3-4withAl(Ⅲ)-Morinthatleadstothefluorescencequenchingofthecompositematrix.AtpHvalue4.0andthesalinityvalue25.0,theresponsetimeofoutputsignalhavingreachedthesteadystateislessthan300seconds.ItscalibrationgraphisgainedintherangeofH2PO-4massconcentrationfrom1.50to7.00μg/mLwiththelimitofdetection(3σ/K)0.02μg/mL.Whenitwasusedtomeasurephosphatesinartificialseawater,therecoveryrangedfrom96.78%to102.09%.Beingstoredunderthepropercondition,themembranesmaintainsensitivefor90-120days,andareabletobeusedfor50-80timeswithindicatorsupplement.
简介:Astudyonthetransportcharacteristicsofzincinlousoilwithphosphateatdifferentconcentrationswascarriedoutbythemethodofstepinput.Theeffectsofphosphateandtemperatureonzinctransportwerestudiedthroughanalysingthediffusion-dipsersioncoefficients(D)andtheretardationfactor(R)obtainedbytheprogramCXTFIT.TheresultsshowedthatDdecreasedandRincreasedwithincreasigconcentrationofphosphatesothativwasdifficultforzinctobreakthroughthesoilcolumn,andzincstoppedtobreakthroughthecolumnathightemperature.Oneorderequation,doubleconstantequationandtheElovichequationwereallsuitablefortheescriptionofzincdynamics.Effectsofphosphateandtemperatureonzinctransportwerefurtherconfirmedbytheanalysisonpseudo-thermodynamicparametersofzinctransport.