简介:在云南省的巨大的HuizeZn-Pb矿石地,西南的中国,包括Qilinchang和Kuangshanchang存款。存款在等级在规模(Zn和Pb的超过5山)和高度大(全部的Zn和Pb的平均等级是30%)。在这报导纸是Rb-Sr的结果从这块矿石地的闪锌矿的同位素的标明日期。二精确年龄(223.5±3.9妈和226±6.4妈)从二isochrons被获得了。这二年龄在这个区域接近与Emeishan洪水暗岩有关的本国的铜矿化作用的报导年龄,它是到228妈的226妈。以前的研究证明大小高举从Emeishan洪水暗岩结果比1000m大,显示Kuangshanchang和Qilinchang扔在一样的地质的事件期间被形成并且在高举期间由液体移植发源从Emeishan洪水暗岩结果。
简介:StudyontheavoidanceresponseofPenaeuschinensistoheavymetals(Pb,Cr,Zn)andheavymetalmixtures(Pb-Cr,Pb-Zn)iscarredoutusingaY-modelavoidanceapparatus.Theconcentrationscalculatedtoinduce50%avoidanceratebyPenaeuschinensisare11.4,33.2and238.1mg/LforPb,CrandZn,respectively.MixturesofPb-CrandPb-ZnproduceadditiveeffectintheavoidancetestusingPenaeuschinesis.ButwhenthemixedPb-Znsolutionhas0.5toxicunitPband0.5toxicunitZn,themixtureseemstohavesynergisticeffect.
简介:Thesuper-largePb-ZndepositatFankouisverycomplexinmetallogenicmechanism.Syngeneticbrinesedimentation,hotsubmarinespringeruption-accumulation,syngeneticsedimentation-vadosebrinereplacementhadbeensupposedasthegeneticmodelsbefore.Underthesemodels,syngeneticmineralizationshouldbedominantinoreformation.However,aseriesofgeologicalandgeochemicalpropertiesinvestigatedbyauthorsofthispaperarecontrarytothesemodels.Therefore,theauthorsheresuggestthatthisdepositisatypicalpolygeneticcompoundoredepositwhichsharethepropertiesofmultistagesofgeotectonicevolution,multifactorsofmineralizationcontrol,multisystemofmaterialderivationofmineralization,multimodesofmineralizationandmultitypesofgenesis.
简介:Tianqiaocarbonate-hostedPb-Zndeposit,controlledbyNW-trendingF37thrustfaultandNW-trendingTianqiaoanticline,islocatedintheeasternpartofSichuan-Yunnan-Guizhou(SYG)Pb-Znmetallogenicprovince,southwesternYangtzeBlock,southwestChina.OrebodiesinthisdepositarehostedintheDevonian-Carboniferouscarbonaterocks,andoremineralsincludesphalerite,galenaandpyrite,whiletheganguemineralsaredominatedbycalciteanddolomite.Usinghigh–precisionsolidthermalionizationmassspectrometry(TIMS),thispaperreportsthestrontiumisotopiccompositions(0.7119to0.7167)ofsulfidesamplesfromtheTianqiaodepositinordertotracetheoriginofhydrothermalfluids.Comparedwiththecountryrocks,thecalculated87Sr/86Sr200Mavaluesofsulfiderangefrom0.7118to0.7130,higherthanthoseoftheage-correctedDevoniantoPermiansedimentaryrocks(0.7073to0.7101)andtheMiddlePermianEmeishanfloodbasalts(0.7078to0.7039),butlowerthanthoseoftheage-correctedProterozoicbasementrocks(suchastheKunyangandHuiliGroups,87Sr/86Sr200Ma=0.7243to0.7288).Thisimpliesamixedstrontiumsourcebetweentheolderbasementrocksandtheyoungercoversequences.Togetherwithgeologicandpreviousisotopicevidences,weconsideredthatthefluids'mixingisapossiblemechanismforsulfideprecipitationintheTianqiaodeposit.
简介:摘要:本文采用原子吸收光谱法和ICAP6300电感耦合等离子体发射光谱仪原子光谱法测定了铜合金中Pb、Zn、Sn元素,研究了主量元素对分析元素的干扰,选择适当的分析线及工作条件,ICAP6300电感耦合等离子体发射光谱仪原子光谱法主要优点是能够准确、快速、简便,能满足国内外常见牌号铜合金中多种元素的分析。全国材料检测与质量控制学术会议 电感耦合等离子体发射光谱仪同时测定铜合金中 主量、常量、微量元素的方法探讨。通过对仪器分析谱线的研究及测试条件的优化,建立了铜合金中主量、常量、微量元素同时测定的ICAP6300电感耦合等离子体发射光谱仪分析方法,应用于铜合金中所有元素的测定。方法具有抗干扰能力强、线性范围宽、精密度高、结果准确等特点。
简介:Onthebasisofmineralparagenesisandthechemistryandhomogenizationtemperaturesoffluidinclusions,thephysicochemicalparameterswerecalculatedfortheformationoftheDalingkouAg-Pb-ZudepositinZhejiang.Fromtheearlytothelatestageofmineralizationtheore-formingtemperatureveriationwasfoundtobe298.5℃→267.0℃→217.6℃→167.3℃,withacorrespondingpHchangeof3.0-5.8→6.1→6.7→5.0→7.3.Thepressurechangedfrom403.8to128.5atm,andlogfS2-9.9→-11.2→<-15;logfO2<-44→-45.6--42.6→>-44.2;andlogfCO2around-1.55.Inconjunctionwithgeologicalobservations.thedepositisconsideredtobeofmeso-epithermalorigin,i.e.,itwasformedaftercontinentalvolcanic-subvolcanicactivity.ThemajorfactorsaffectingoreprecipitationarethedecreasingtemperatureandtheincreasingpHofore-formingsolutions.
简介:摘要;本设计采用电感耦合等离子发射光谱法(ICP—OES)对岩石样品中的Cu,Pb,Zn,Mn,Ni进行了测定,样品用四酸()熔矿,不经分离杂质,即可直接测定。该方法选择Cu,Pb,Zn,Mn,Ni的测定分析波长分别为324.7nm,220.3nm,202.5nm,257.6nm,221.6nm分析了用HCl提取与用王水提取,样品首先经磨样机碎至200目,用去离子水湿润后,用四酸熔矿,再将坩埚放置恒温电热板上加热,最后分别用王水或盐酸提取再定容,对其中的Cu,Pb,Zn,Mn,Ni做探究实验。
简介:1IntroductionDengfuxianorefieldliesattheintersectionoftheQin-HangCombinedZone(QCZ)andtheNanlingMetallogenic,andcomprisesXiangdongW-Sndeposit(AlsoknownasDengfuxianW-Sndeposit),Jiguanshi
简介:ThreelogarithmiclinearequationsbetweenDMeV/Land[mNaCl],andtherelationshipofDMeV/LversusF/ClorK/NamoleratioshavebeenestablishedbytheexperimentsofthepartitioningofPbandZnbetweengraniticsilicatemeltandaqueousfluid.Theseresultshavebeenusedtoquantitativelystudysomeessentialproblems,suchasthepossibilityanddegreeofPb-Znmineralizationinthesystemofgraniticmagmaandhydrothermalfluid,andtheinfluenceoftherelativecontentsofalkaliandvolatilesonthePb-Znmineralizationinthesamesystem.Somenewpointshavebeenputforwardinthispaper.
简介:1IntroductionTheMaozuPb–Zndeposit,locatedintheNortheastofYunnanProvince,southwestChina,isatypicalcarbonate-hosteddepositintheNortheastofYunnanPb–Znmetallogenicprovince.Fluoriteisthemaingangue
简介:Dustemissionsfromsmelters,asamajorcontributortoheavymetalcontaminationinsoils,couldseverelyinfluencesoilquality.Downwindsurfacesoilswithin1.5kmofazincsmelter,whichwasactivefor10yearsbutceasedin2000,inMaguTown,GuizhouProvince,ChinawereselectedtoexaminePb,Zn,andCdconcentrationsandtheirfractionationalongadistancegradientfromazincsmelter,andtostudythepossiblee?ectsofPb,Zn,andCdaccumulationonsoilmicroorganismsbycomparingwithareferencesoillocatedatadownwinddistanceof10kmfromthezincsmelter.Soilswithin1.5kmofthezincsmelteraccumulatedhighlevelsofheavymetalsZn(508mgkg-1),Pb(95.6mgkg-1),andCd(5.98mgkg-1)withlowratiosofZn/Cd(59.1-115)andPb/Cd(12.4-23.4).Compositepollutionindices(CPIs)ofsurfacesoils(2.52-15.2)were3to13timeshigherthanthereferencesoils.Inmetalaccumulatedsoils,exchangeablepluscarbonate-boundfractionsaccountedformorethan10%ofthetotalZn,Pb,andCd.Thesaturationdegreeofmetals(SDM)insoilswithin1.5kmofthesmelter(averaging1.25)wassixtimeshigherthanthatofthereferencesoils(0.209).Asmallersoilmicrobialbiomasswasfoundmorefrequentlyinmetalaccumulatedsoils(85.1-438μgCg-1)thaninreferencesoils(497μgCg-1),andanegativecorrelation(P<0.01)ofsoilmicrobialbiomasscarbontoorganiccarbonratio(Cmic/Corg)withSDMwasobserved.Microbialconsumptionofcarbonsourceswasmorerapidincontaminatedsoilsthaninreferencesoils,andashiftinthesubstrateutilizationpatternwasapparentandwasnegativelycorrelatedwithSDM(R=-0.773,P<0.01).Consequently,dustdepositedPb,Zn,andCdinsoilsfromzincsmeltingwerereadilymobilized,andweredetrimentaltosoilqualitymainlyinrespectofmicrobialbiomass.
简介:ThePengshanSn-Pb-ZnpolymetallicorefieldislocatedintheJiujiang-Ruichangregion,whichisasegmentofthemiddle-lowerYangtzeRivermetallogenicbelt.ThePengshanlateYanshanianburiedplutonwithgraniticcompositionisacalc-alkalinepluton,intrusionofwhichisresponsiblefortheformationoftheSn-Pb-Znpolymetallicdepositthroughprovidingthermodynamicconditionandore-formingmaterial.Thelong-activebasementriftsinitiallyformedintheJinningperiodandthedomalstructurewithinducedsecondaryorderfaultsformedbyemplacementofthepluton,suchasring-detachmentfault,top-detachmentfaultandjointfissure,actasthepassage-wayformagmaandore-formingfluidandimpoundingstructurefororedeposit.ThemagmatoformtheplutonwithDI>90isintensivelydifferentiated.Thevariationoftheore-formingfluidincompositionwithfallingintemperaturecausedbyactionofmagmatichydrothermalconvectionsystemcombinedwithgroundwaterconvectionsystemattributestomineralizationofvarioustypesintheorefield.Themineralizationprocesscanbedividedintosixstages,i.e.,greisenization,skarnizationofearlystage,fluorite-stanniferoussilicationstage,skarnizationofadvancedstage,quartzandcassiterite-sulfurationstageandcarbonationstage.Themineralassemblagesformedindifferentmineralizationstagesaredifferentowingtotemperaturechangingandmaybeoverlappedinspace.Malayaiteisrecognizedfromthemineralassemblageformedinthefluorite-stanniferoussilicationstage.TheoresinthePengshanSn-Pb-ZnpolymetallicdepositarespatiallyzonedwithvariationfromAs-SnmineralassemblageofhightemperatureintheinnerzonethroughSn-PbandPb-Zn-Agmineralassemblageofmiddletemperatureinthemiddlezonetofluoritemineralassemblageoflowtemperatureintheouterzone.TheexchangingofSn,MgandFebetweenbiotiteandhydrothermalfluidresultedfromvariationofphysicochemicalconditionduringevolutionprocessesofthehydrothermalflu
简介:ThisstudyinvestigatedthevolatilizationkineticsofleadinpelletsmadeofZn-Pb-bearingdustsmixedwithcoalpowder,inanitrogenatmosphereandinthetemperaturerangebetween1100℃-1300℃,andshowedthatthereductiontemperaturehasasignificanteffectonthevolatilizationrateofleadandthatneithertheparticlesizeofthecoalpowdernortheextracarboncontenthasanyeffectonthevolatilizationrate.Theobtainedactivationenergyforthevolatilizationofleadis88.74kJ/mol.Thevolatilizationrateofleadiscontrolledbyboththeleadevaporationreactionandthediffusionofgaseousleadthroughthegasboundarylayercoveringthesurfaceofthereducedliquidlead.
简介:为研究煤炭地下气化灰渣的环境效应,主要是对地下水的影响,以洛阳半焦煤为研究对象,进行煤炭地下气化的模型实验。取气化后的灰渣浸泡,测定浸出液中Zn、Cd、Pb和As4种元素的质量浓度。浸出液中Zn、Cd和As的质量浓度均低于地下水Ⅲ级标准,在饮用水允许的浓度范围内,不会对地下水造成多大污染;Pb的质量浓度在地下水V类标准内,可能会对地下水造成一定污染,现场应考虑采取适当处理措施。4种元素的质量浓度均远低于浸出毒性鉴别标准值,因而不属于具有浸出毒性的危险废物。研究表明洛阳半焦煤地下气化灰渣中的Zn、Cd、Pb和As对环境的影响较小,不会对地下水产生多大影响。但在现场的工业试验中,由于长期的积累作用,也可能使元素的累积浓度超过地下水允许浓度,应定期监测。
简介:InNanlin,alargenumberofPb-ZndcpositsandSbdcpositsincludingtheworldfamousgiantSbdepositcalledXikuangshanmineareDevoniancarbonaterock-liosted,Ourjnvcstigationsuggcststhatmanyofthcscdcpositswercmineraljzcdbyorc-bcaringgroundwater.IMajorProoIsofOre-BearingGroundwatcrMincralisationTherearcmanyproofiofgro