简介:以Ni0.5Co0.2Mn0.3(OH)2和Li2CO3为原料,TiO2和ZnO为掺杂剂,制备出不同含量钛锌离子复合掺杂的锂离子电池正极材料LiNi0.5Co0.2Mn0.3O2。用XRD、SEM、恒电流充放电、交流阻抗法和循环伏安方法分别研究了不同掺杂量对LiNi0.5Co0.2Mn0.3O2的结构、形貌和其电化学性能的影响。结果表明3%(摩尔分数)的Ti、Zn离子复合掺杂能有效提高LiNi0.5Co0.2Mn0.3O2的倍率放电能力和循环性能。在1C和2C的充放电倍率下,首次放电容量分别为170.4mAh/g和164.8mAh/g,经过50次充放电循环后容量保持率分别为96.3%和94.7%,具有优良的电化学性能。
简介:摘要院为了研究铅Pb2+在自由流电泳中的运动轨迹,通过COMSOL仿真软件研究滋-FFE中外加电场大小、进液流速对铅离子分离富集的影响,并找出较优的参数与方案。首先建立了矩形芯片结构仿真模型,加入模拟需要的速度、浓度、电场三个物理场。此次参数设定在考虑以往实验的基础上选择外加电压大小为110V至150V之间,进液流速在6.3*10-5m/s到7.8*10-5m/s之间。从仿真结果来看,外加电压大小为150V左右进液流速为7.3*10-5m/s即0.08ml/min时铅离子偏转比较明显。该研究对工业废水排污重金属分离提供了借鉴。
简介:以1,8-萘二甲酸酐、二乙烯三胺(DETA)、N-甲基哌嗪及丙烯基氯为原料,通过酰胺化、季胺化、SN2亲核取代以及丙烯酰胺共聚合等反应,合成了水溶性1,8-萘酰亚胺高分子荧光探针。用紫外光谱、荧光光谱等手段研究它们在水、四氢呋喃和乙醇溶液中光物理化学性质,同时考察浓度和溶剂极性及取代基对荧光性能影响及对金属离子的识别作用。结果表明,此高分子荧光探针的光稳定性及荧光量子产率明显提高,随着溶剂极性增大,荧光量子产率增大,波长红移;当浓度超过8×10^-4g/mL时出现荧光浓度自猝灭;该探针在水中能对Cu^2+在392nm处进行高选择性识别。
简介:Tianqiaocarbonate-hostedPb-Zndeposit,controlledbyNW-trendingF37thrustfaultandNW-trendingTianqiaoanticline,islocatedintheeasternpartofSichuan-Yunnan-Guizhou(SYG)Pb-Znmetallogenicprovince,southwesternYangtzeBlock,southwestChina.OrebodiesinthisdepositarehostedintheDevonian-Carboniferouscarbonaterocks,andoremineralsincludesphalerite,galenaandpyrite,whiletheganguemineralsaredominatedbycalciteanddolomite.Usinghigh–precisionsolidthermalionizationmassspectrometry(TIMS),thispaperreportsthestrontiumisotopiccompositions(0.7119to0.7167)ofsulfidesamplesfromtheTianqiaodepositinordertotracetheoriginofhydrothermalfluids.Comparedwiththecountryrocks,thecalculated87Sr/86Sr200Mavaluesofsulfiderangefrom0.7118to0.7130,higherthanthoseoftheage-correctedDevoniantoPermiansedimentaryrocks(0.7073to0.7101)andtheMiddlePermianEmeishanfloodbasalts(0.7078to0.7039),butlowerthanthoseoftheage-correctedProterozoicbasementrocks(suchastheKunyangandHuiliGroups,87Sr/86Sr200Ma=0.7243to0.7288).Thisimpliesamixedstrontiumsourcebetweentheolderbasementrocksandtheyoungercoversequences.Togetherwithgeologicandpreviousisotopicevidences,weconsideredthatthefluids'mixingisapossiblemechanismforsulfideprecipitationintheTianqiaodeposit.
简介:Asoneofcandidatesforthefuelcladdingorstructurematerialusedinfourthgenerationfissionandfusiondemonstratereactor,MAXphasehasthepropertiesofbothceramicandmetal,suchashighmeltingpoint,hightemperaturestability,gooderosionresistanceandradiation-damagetolerance[1;2].Maxphaseisaseriesofceramicsofnanolamellarandhexagonalstructure.Mrepresentstransitionelement.Arepresentsthethirdorfourthmaingroupelement.XrepresentNandC.Inthedesignoflead-cooledfastreactor,itisrequiredthatthematerialshouldendurethecorrosionofliquidPb-Bialloy.Therefore,understandingoftheoxidelayersandtheirgrowthmechanismsinLBEisfundamentallyimportantforthedevelopmentofcandidatematerials.
简介:210Pbwasmeasuredduringthe3rdChineseNationalArcticResearchExpeditioncruisetoinvestigateitsspatialpatterninthewesternArcticOcean,aswellasitsrelationwiththethermoclineintheCanadianBasin.Thespecificactivitiesvariedfrom0.04to2.72,<0.013to4.37,and0.1to4.85Bq/m3fordissolved,particulate,andbulk210Pb,respectively,correspondingtorespectiveaveragesof0.65,0.43,and1.08Bq/m3.IntheCanadianBasin,theminimum210Pbactivitiesoccurredinthethermocline,whichwascharacterizedbylowtemperatureof-1.52°Candsalinityof33.1.Combiningthespatialdistributionof210PbandhydrographicalcharacteristicsinthewesternArcticOcean,thisscenariowasascribedtotheeffectivescavengingof210PbwhenthePacificwaterflowedacrosstheChukchiShelf.Quantitatively,thisinterpretationwassupportedbyboththeshorterresidencetimesandhigherscavengingefficiencies(SE)ofdissolved210PbovertheChukchiShelf.ThehighestSEvalueswereobservedintheHeraldShoalandbottomwatersovertheslope.
简介:ThisstudyinvestigatedthevolatilizationkineticsofleadinpelletsmadeofZn-Pb-bearingdustsmixedwithcoalpowder,inanitrogenatmosphereandinthetemperaturerangebetween1100℃-1300℃,andshowedthatthereductiontemperaturehasasignificanteffectonthevolatilizationrateofleadandthatneithertheparticlesizeofthecoalpowdernortheextracarboncontenthasanyeffectonthevolatilizationrate.Theobtainedactivationenergyforthevolatilizationofleadis88.74kJ/mol.Thevolatilizationrateofleadiscontrolledbyboththeleadevaporationreactionandthediffusionofgaseousleadthroughthegasboundarylayercoveringthesurfaceofthereducedliquidlead.
简介:Geza岛弧是一个著名矿化作用集中区域,在西藏的高原的东方边缘的Sanjiang领域的部分。在最近的年里,几迟了的Yanshanian花岗石的侵入和联系存款在这个区域被发现了,在桃花源,区域是其一最大Laba铝存款。以前的研究建议预定Laba矿化作用是85±2妈。然而,granodioritic斑岩的年龄仍然保持未知。在这研究,从忍受辉钼矿的granodioritic斑岩的三件样品锆石标明日期的LA-ICP-MSU-Pb与85.00±的产生日期一起被进行了0.23妈(MSWD=0.58),85.28±0.28妈(MSWD=1.12),并且84.83±0.26妈(MSWD=0.79)分别地,显示这些granodioritic斑岩在∼85附近在迟了的Yanshanian形成了妈。与矿化作用的地质的特征结合了,时间地,Laba存款遗传上空间地与granodioritic斑岩被联系。另外,Laba存款的年龄与另外的迟了的Yanshanian侵入和矿化作用一致,建议矿化作用可能在在迟了的白垩纪期间的intra板extensional环境下面被产生。
简介:摘要院在分析印刷企业库存管理业务流程基础上,采用三层C/S分布式体系结构,以SQLServer2000为后台数据库平台,采用PowerBuilder开发工具,设计并开发了印刷企业库存管理信息系统,实现了印刷企业库存管理信息化,提高了管理效率和经济效益。
简介:Thiscontributionanalyzesthesimilaritiesanddifferencesbetweenthemeasuredactivitiesof137Csandexcess210Pb(210Pbex)inthecultivatedbrownandcinnamonsoilsoftheYimengMountainarea,discussestheinfluenceofsoiltextureonthemeasurementof210Pbex,andpresentsdifferencesbetweenthetwotypesofsoils.FieldsAandBwereselectedtorepresentthefieldsthatcontaincultivatedbrownandcinnamonsoils,respectively.Fromeitherstudyfield,onesiteofsectionedcoreandsixbulkcoreswerecollectedtomeasure137Cslevels,210Pbexlevels,andtheparticle-sizecompositionofsoilsamples.Threeundisturbedsoilsampleswerecollectedtomeasurecapillaryandaerationporosities.The137Csinventoriesforthetwostudyfieldsareverysimilar.The137Csisaman-maderadionuclide,whichmeansthatitsmeasuredlevelsforsoilsareunaffectedbysoiltexture.Incontrast,levelsofthenaturallyoccurring210PbexofsoilsfromFieldAwerelowerthanthoseofFieldBbyabout50%.Incontrasttoaquaticsediments,levelsof210Pbexinterrestrialsurfacesoilsareaffectedbytheemanationof222Rnfromthesoils.Itcanbeassumedthatthecoarserthesoils,thegreatertheemanationof222Rn;inaddition,thelowerthemeasured210Pbex,thegreatertheunderestimateofthisvalue.ThecultivatedbrownsoilsinFieldAarecoarserthanthecultivatedcinnamonsoilsinFieldB.Asaresult,222RninFieldAwilldiffusemoreeasilyintotheatmospherethanthatinFieldB.Asaconsequence,themeasured210PbexinsoilsfromFieldAismuchlowerthantheactualvalue,whereasthevaluemeasuredforFieldBismuchclosertotheactualvalue.
简介:博格达三个山地区基性岩墙地球化学研究显示,该岩墙属亚碱性系列,为岩浆高度演化产物,轻稀土富集,不相容元素Ba,La,K相对富集,高场强元素Nb,Th,Yb相对亏损,Ti亏损不明显,Nb/Ta(平均14.1)、Zr/Hf(平均35.99)比值与原始地幔Nb/Ta(17.8)、Zr/Hf(37)比值相似,(Th/Nb)N的值大于1,Nb/La比值小于1,表明该岩墙的岩浆源自地幔,且在侵位过程中受到地壳物质的混染。本区基性岩墙的LA-ICP-MS锆石U-Pb加权平均年龄为(322.1±6.5)Ma,表明是博格达造山带岩石圈拉张减薄时的产物,反映晚石炭世早期博格达造山带处于岩石圈拉张的构造环境与动力学背景。
简介:Mg-Al-Pb合金是一种新开发的海水激活电池材料。采用熔炼浇注法制备Mg-6Al-5Pb-0.5Mn系列合金和Mg-6Al-5Pb合金。其中,Mg-6Al-5Pb-0.5Mn系列合金是以Al-15%Mn、Al-30%Mn和Al-50%Mn中间合金为添加剂制备的。采用金相显微镜和扫描电子显微镜表征其组织,采用电化学方法、析氢法和失重法研究其性能。结果表明:以Al-50%Mn中间合金为添加剂制备的Mg-6Al-5Pb-0.5Mn合金具有最负的放电电位(-1.66V),最小的腐蚀电流密度(7μm/cm2)和自腐蚀速率(0.51mg·h-1·cm-2)。这可能是因为Al11Mn4相的存在,不仅有利于腐蚀产物的脱落和增大电化学反应面积,而且也提高电化学活性。