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简介:AnincreasingnumberofgeologistsinSouthAmericahaveturnedtheirattentiontoisotopegeologyasatoolinthewidercontextoftheEarthSciences.Asaresult,aseriesofsymposiaontheSouthAmericanisotopegeology(SSAGI)hasbeenorganizedeverytwoyearstoprovideanappropriateforumfordiscussionofmethodsandapplicationsofstableandradiogenicisotopes.
简介:ThispaperdealswiththestructureoftheY^Ⅲcomplexwithaminopolycarboxylicacids,synthesisandstructuraldeterminationofthecomplex(NH4)[YⅢ(edta)(H2O)3]·3H2O(edta=ethylenediaminetetraaceticacid).Thecrystalandmolecularstructuresofthe(NHO[YⅢ(edta)(H2O)3]·3H20complexhavebeendeterminedbysingle-crystalX-raystructureanalysis.Thecrystalofthecomplex(NH4)[YⅢ(edta)(H2O)3]·3H2Obelongstoorthorhombiccrystalsystemandfdd2spacegroup.Thecrystaldataareasfollows:a=1.9441(9)nm,b=3.5459(18)nm,c=1.2196(6)nm,V=8.407(7)nm3,Z=16,M~=503.25,Dc=1.590g.cm3,μ=2.844mm-1andF(000)=4160.ThefinalRandRware0.0486and0.1332for3388(I>2σ(I))uniquereflections,respectively.Thecomplexanion[YⅢ(edta)(H2O)3]hasapseudo-mono-cappedsquareantiprismaticnine-coordinatestructureinwhichthesixcoordinateatoms(twoNandfourO)arefromanedtaligandandthreewatermoleculescoordinatetothecentralYⅢiondirectly.Fromtheresultsitcanbepredictedthattheymioncanalsoformanine-coordinatecomplexwithttha(=triethylenetetraminehexaaceticacid)ligand,sotheradioactivecomplexanion[99YⅢ(Httha)]2-cansupplyafreecarboxylgroup(-CH2COOH)beingusedformolecularembellishmenttoformtheTDDSforthetreatmentofcancers.
简介:EDGERECONSTRUCTIONOFPLANARGRAPHSWITHMINIMUMDEGREEATLEASTTHREE-(IV)¥FANHongbing(DepartmentofMathematics,ShandongUniversity,Ji'...
简介:TheauthorsconsidertheEulerequationsforacompressiblefluidinonespacedimensionwhentheequationofstateofthefluiddoesnotfulfillstandardconvexityassumptionsandviscosityandcapillarityeffectsaretakenintoaccount.Atypicalexampleofnonconvexcon-stitutiveequationforfluidsisVanderWaals'equation.Thefirstordertermsofthesepartialdifferentialequationsformanonlinearsystemofmixed(hyperbolic-elliptic)type.Foraclassofnonconvexequationsofstate,anexistencetheoremoftravelingwavessolutionswitharbitrarylargeamplitudeisestablishedhere.Theauthorsdistinguishbetweenclassical(compressive)andnonclassical(undercompressive)travelingwaves.ThelatterdonotfulfillLaxshockinequali-ties,andarecharacterizedbytheso-calledkineticrelation,whosepropertiesareinvestigatedinthispaper.
简介:ThispaperreportsasimpleandhighlyselectivemethodforpreconcentratingandseparatingoftracePd(II)andPt(IV)withsilicagelbondedbyaminopropyl-benzoylazo-4-(2-pyridy-lazo)-resorcinol(ABPR-SG).ABPR-SGisstableinsolutionfrom6mol/LHCltopH7.0andincommonorganicsolvents.ThemaximumadsorptivecapacityofPd(n)onABPR-SGis362μmol/g.AfterpreconcentrationandseparationbyusingABPR-SGcolumn,Pd(II)andPt(IV)ofμg/Llevelinartificialwatersamplescanbemeasuredreliablybycommonspedrophotometry.ThemaximumconcentrationfactorsofPd(II)andPt(IV)onABPR-SGcolumnare143and125respectively.ThechromatographiccolumnpackedwithABPR-SGcanbereused.Themethodissimpleandefficient.