简介:Thecrystalstructureof[Ni(TAAB)(py)2](BF4)2,whereTAABisthetetradentatemacrocyclicligandtetrabenzo[b,f,j,n][1,5,9,13]tetraazacyclohexadecine,hasbeendeterminedfromX-raydiffractionanalysis.Thecrys.taibeiongstomonoclinic,spacegroupP21/nwithcellparameters
简介:Highlyselectivedimerizationofα-methylstyrene(AMS)waseffectedusingaBroenstedacidicionicliquid,[Hmim]^+BF4^-,assolventaswellascatalyst,providingtheindustrialhigh-valueolefin,2,4-diphenyl-4-methyl-1-pentene(1-PT).Thedesireddimer1-PTcouldbeobtainedin90%yieldat96%conversioninthedimerizationofAMSunderoptimizedconditions.Featuresoftheprocedureincludeuseofreadilyavailableionicliquid-catalyst,exclusionofvolatileorganicsolvents,higherselectivityandefficiencyfor1-PT.
简介:Themonomericcobalt-phosphite-thiolatocomplex[Co(mpt)2{P(OCH3)3}2]BF4(Hmpt=2-mercaptothiazoline)hasbeenpreparedandcharacterizedbyX-raycrystallography.ThecomplexcrystallizesinthemonoclinicspacegroupC2/cwitha=0.8078(5),b=2.6020(18),c=1.2191(7)nm,β=99.38(1)°,V=2.528(3)nm3,andZ=4.Thestructurecomprisesdiscretecations[Co(mpt)2{P(OCH3)3}2.]+andanionsBF4-,inwhichthecobalt(Ⅲ)atomiscoordinatedtotwochelatempt-andtwoas-orientedmonodentateP(OCH3)3ligandsinahighlydistortedoctahedralgeometry.ThemostdistortedanglesareS(2)-Co(1)-S(2a)of162.23(10)°andN(1)-Co(1)-S(2)of71.47(13)°,thelatteriscausedbythegeometricconstraintofthebidentateligandmpt-.CyclicvoltammetryhasbeenusedtostudytheelectrochemicalbehaviorofthetitlecomplexontheRelectrodeinMeCNsolutionwith0.1mol·L-1ofBun4NBF4aselectrolyte.TheresultsindicatethatthetitlecomplexisunstableinMeCN.
简介:ThephysicalandelectricalpropertiesofBF2+implantedpolysiliconfilmssubjectedtorapidthermalannealing(RTA)arepresented.ItisfoundthattheoutdiffusionofFanditssegregationatpolysilicon/siliconoxideinterfaceduringRTAarethemajorcausesofFanomalousmigration.FluorinebubbleswereobservedinBF2+implantedsamplesatdosesof1×1015and5×1015cm-2afterRTA.
简介:[1]BASFUSP4479906[2]BASFBP1443541[3]BASFDE3618265[4]WangL.,WuZ.,ChinaLeather,26(8),11,(1997)[5]YuanL.,DinY.,ChineseChemistryBulletin,(2),19(1988)[6]KurokiH.,ChemistryofDyeingTheory(ChineseTranslation),TextileIndustryPress,Beijing,89(1982)[7]WangS.,LiP.,WuZ.DyestuffIndustry(Chinese),34(4),1,(1997)[8]Tian,Y.,Wu,Z.,Wang,G.,Zhang,S.J.ChineseChem.Eng.,46,156(1995)[9]Tian,Y.,Wang,G.,Wu,Z.,J.ChineseChem.Eng.,47,75(1996)[10]Lycka,A.,DyesandPigment,32,11(1996)[11]Griffith,J.,ColourandConstitutionofOrganicMolecules,AcademicPress,London,191(1976)
简介:Dibromobiphenylreactedwithcynomethylanioninammoniaunderirradiationtoformnucleophilicbis-substitutedproductinhighyieldwithoutsubstantialmonosubstitutedproduct.Quantumyieldsfortheformationsofbis-andmonosubstitutedproductswerefoundtobe85.6and2.3×10-6respectively,whilethecorrespondingpseudo-first-orderrateswere6.9×10-3and5.2×10-10mol.L-1.S-1.Blockupthepossibleelectrontransferof4-brome-4’-cyanomethylbiphenylylradicalanionto4-cyanometbyl-biphenylylradicalandbromineion.
简介:Theoperationprincipleofanarrayedwaveguidegrating(AWG)multiplexerisintroducedandthe4×4AWGwithfollowingdesignparametersisdiscussedindetail,suchasthechoiceofwavelength,theneighboringarrayedwaveguidedistanceΔL,thechannelfrequencyintervalΔf,andthefreespectralrange.Thestructureof4×4AWGisdesignedandtheresultofstimulatedtestisalsogiven.Analysisshowsthatthe4×4AWGischaracterizedbyawidedynamicrange,lowcrosstalk,betterspectrumproperties,andacompactstructure.
简介:Thetitlecompounds4,4'-oxobis(propham)((?)n)(C20H24N2O5,Mr.=372.41)wassynthesizedbytheadditionreactionofcorresponding4,4'-oxobisphenyldiisocyanatewithisopropanol.ThecrystalstructurewasdeterminedbyX-raydiffractionmethod.Thecrystalistriclinicsystem,spacegroupP-1witha=8.5107(17),b=9.1164(18),c=14.5701(3)A,α=80.44(3),β=85.25(3),γ=62.88(3)°,V=992.2(3)A3,Z=2,Dc=1.247g/cm3,F(000)=396,R=0.0520,wR2=0.1434for4336observedreflectionswith[I>2σ(I)].X-rayana...
简介:一些资料上要求学生解这样一类方程"32÷4x=4".学生中往往出现两种解法,第一种是把原方程看成"32÷(4×x)=4"去解,得x=2;第二种则是将原方程看作"(32÷4)×x=4"去解,得x=0.5.教师要求学生检验方程的解.采用第一种解法的学生,先把4与x的值相乘,得如下检验式: