学科分类
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9 个结果
  • 简介:Thisresearchreportsthepreparationandcharacterizationofcoppernanoparticlesmodifiedbydidecylbenzenesulfonate(DBS),TheCunanoparticles'sizewasdeterminedtobe40nmbytransmissionelectronmicroscope(TEM).TheX-rayphotoelectronspectrometry(XPS)resultsshowthatthereareinteractionsbetweenthecoppernanoparticlesandDBSfunctiongroup.Thenonlinearopticalpropertieswerestudiedbythefour-wavemixingmethod.Thevalueofx^(3)/α0wasfoundtobe6.9×10^-11esucm.

  • 标签: 纳米颗粒 非线性光学特性 实验
  • 简介:Ti-dopedW03filmswerepreparedbythemid-frequencydual-targetmagnetronsputteringmethod.ThestructureandelectrochromicpropertiesoftheTi-dopedWO3filmswereanalysedbyX-Raydiffraction(XRD),Ramanspectroscopy,spectrophotometer,cyclicchronoam-perometryandatomicforcemicroscopy(AFM).Theresultsindicatethatthecrystallinitydecreaseafterthedopingoftitanium,thechannelsforioninjectionandextractionincrease,therespondingspeedwith5.1%titaniumdopedbecomesfaster,anditscirclelifeincreasesmorethanfourtimescomparedwiththeundopedWOafilm.Inthecolouredstate,theW-O-Wbondsdecrease,buttheW=Obondsincrease.SincetheW-O-WbondsbreakdownforLi~+ions'injectionandmoreW=Obondsform,itismoreconvenienttoinjectLi~+ionsintotheTi-dopedfilmthanundopedfilmbecausemoreW-O-Wbondsbreakdowninthecolouredstate.

  • 标签: 磁控管溅射 等离子体 钛掺杂三氧化钨薄膜 电质变色薄膜
  • 简介:ZnOnanowiresdepositedonSisubstrateswerepreparedbythermalevaporationofamixtureofZnOandcarbonpowder.Agionswithanenergyof63keVandadoseof5×1015ions/cm-2wereimplantedintotheas-preparedZnOnanowires.Afterionimplantation,theAg-implantedZnOnanowireswereannealedinairatdifferenttemperaturesfrom600℃to1000℃.Effectsofionimplantationandthermalannealingonthestructuralandphotoluminescent(PL)propertiesoftheZnOnanowireswereinvestigatedbytransmissionelectronmicroscopy(TEM),selectedareaenergydispersiveX-rayspectroscopy(SAEDX),X-raydiffraction(XRD),andfluorescencespectrophotometry.TEM,HR-TEM,andSAEDXanalysesdemonstratedthatefficientdopingofAgwasachievedbyionimplantationandthesubsequentannealingprocess.XRDpatternsrevealedthatthehexagonalwurtzitestructureofZnOnanowireswasmaintainedafterionimplantation.PhotoluminescentemissionsofZnOnanowiresweredecreasedsignificantlybyAgimplantationbutcouldberecoveredbythermalannealing.ThemechanismoftheinfluenceofionimplantationandannealingonthePLintensitywasassessed.

  • 标签: 氧化锌纳米线 银离子注入 纤锌矿结构 发光性能 热退火 制备
  • 简介:ThetransientopticalpropertiesofnovelPbSnanoparticlescoatedwith2.6-O-diallyl-β-cyclodextrines(CDs)werestudiedbythefemtosecondpump-probetechnique.Theresultsshowthattheultrafasttransient-inducedabsorptionforthenovelcase.ComparedtothePbSnanoparticlesstabilizedwithpolyvinylalcohol(PVA),wefindthattheprocessforthenovelcaseisdifferentfromthePbS(PVA),WesuggestthattheCDssurfacemodificationcantrapholesonthesurfaceofPbSnanoparticles.ThiscaninduceanefficientchargeseparationbetweenthePbSnanoparticlesanditssurfaceandresultinanultrsafast-inducedabsorptionfornovelPbSnanoparticles.

  • 标签: PBS 纳米颗粒 表面化学处理 非线性光学特性
  • 简介:Electricalpropertyofamicro-plasmaspraysystemwithdifferentworking-gasfeedingschemeswastestedtooptimizetheplasmasprayprocess.Thearcvoltagewithanintegratedgasinjectionmodeishigherthanthatwithradialinjectionoraxialinjectionmodes.Thus,anintegratedgasinjectionmodewithanexcellentelectricalcharacteristicwasadoptedtodepositalumina-titaniacoating.Themicrostructure,bondingstrengthandhardnessoftheplasmasprayedalumina-titaniacoating,asafunctionofthesprayingparameters,e.g.,plasmacurrent,gasflowrateandgaspressure,werestudied.Itwasshownthatthesprayingparametersaffectedremarkablyontheinicrostructureofthecoating.Differenttendenciesinbondingstrengthandhardnesswerealsoshownfordifferentsprayingparameters.Atanarccurrentof250A,agasflowrateof20L/rninandagaspressureof0.5MPa,thebondingstrengthandmicro-hardnessofthecoatingsreach40.6MPaandHV1406.1,respectively.

  • 标签: 二氧化钛涂层 微观结构参数 等离子体喷涂 喷涂参数 氧化铝 力学性能
  • 简介:Ananalyticalstudyispresentedonthemodaldispersioncharacteristics,groupvelocity,andeffectivegroup,aswellasthephaseindexofaternaryonedimensionalplasmaphotoniccrystalforanobliquelyincidentelectromagneticwaveconsideringtheeffectofcollisionsinplasmalayers.Thedispersionrelationisderivedbyusingthetransfermatrixmethodandtheboundaryconditionsbasedonelectromagnetictheory.Thedispersioncurvesareplottedforboththenormalphotonicbandgapstructureandtheabsorptionphotonicbandgapstructure.Itisfoundthattheincreaseintheangleofincidenceshiftsthephotonicbandgaptowardhigherfrequencies.Also,thecutofffrequencyisindependentofcollisions.

  • 标签: 倾斜入射 等离子体 电磁波 碰撞 晶体性能 一维