简介:Thisresearchreportsthepreparationandcharacterizationofcoppernanoparticlesmodifiedbydidecylbenzenesulfonate(DBS),TheCunanoparticles'sizewasdeterminedtobe40nmbytransmissionelectronmicroscope(TEM).TheX-rayphotoelectronspectrometry(XPS)resultsshowthatthereareinteractionsbetweenthecoppernanoparticlesandDBSfunctiongroup.Thenonlinearopticalpropertieswerestudiedbythefour-wavemixingmethod.Thevalueofx^(3)/α0wasfoundtobe6.9×10^-11esucm.
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简介:Ti-dopedW03filmswerepreparedbythemid-frequencydual-targetmagnetronsputteringmethod.ThestructureandelectrochromicpropertiesoftheTi-dopedWO3filmswereanalysedbyX-Raydiffraction(XRD),Ramanspectroscopy,spectrophotometer,cyclicchronoam-perometryandatomicforcemicroscopy(AFM).Theresultsindicatethatthecrystallinitydecreaseafterthedopingoftitanium,thechannelsforioninjectionandextractionincrease,therespondingspeedwith5.1%titaniumdopedbecomesfaster,anditscirclelifeincreasesmorethanfourtimescomparedwiththeundopedWOafilm.Inthecolouredstate,theW-O-Wbondsdecrease,buttheW=Obondsincrease.SincetheW-O-WbondsbreakdownforLi~+ions'injectionandmoreW=Obondsform,itismoreconvenienttoinjectLi~+ionsintotheTi-dopedfilmthanundopedfilmbecausemoreW-O-Wbondsbreakdowninthecolouredstate.
简介:ZnOnanowiresdepositedonSisubstrateswerepreparedbythermalevaporationofamixtureofZnOandcarbonpowder.Agionswithanenergyof63keVandadoseof5×1015ions/cm-2wereimplantedintotheas-preparedZnOnanowires.Afterionimplantation,theAg-implantedZnOnanowireswereannealedinairatdifferenttemperaturesfrom600℃to1000℃.Effectsofionimplantationandthermalannealingonthestructuralandphotoluminescent(PL)propertiesoftheZnOnanowireswereinvestigatedbytransmissionelectronmicroscopy(TEM),selectedareaenergydispersiveX-rayspectroscopy(SAEDX),X-raydiffraction(XRD),andfluorescencespectrophotometry.TEM,HR-TEM,andSAEDXanalysesdemonstratedthatefficientdopingofAgwasachievedbyionimplantationandthesubsequentannealingprocess.XRDpatternsrevealedthatthehexagonalwurtzitestructureofZnOnanowireswasmaintainedafterionimplantation.PhotoluminescentemissionsofZnOnanowiresweredecreasedsignificantlybyAgimplantationbutcouldberecoveredbythermalannealing.ThemechanismoftheinfluenceofionimplantationandannealingonthePLintensitywasassessed.
简介:ThetransientopticalpropertiesofnovelPbSnanoparticlescoatedwith2.6-O-diallyl-β-cyclodextrines(CDs)werestudiedbythefemtosecondpump-probetechnique.Theresultsshowthattheultrafasttransient-inducedabsorptionforthenovelcase.ComparedtothePbSnanoparticlesstabilizedwithpolyvinylalcohol(PVA),wefindthattheprocessforthenovelcaseisdifferentfromthePbS(PVA),WesuggestthattheCDssurfacemodificationcantrapholesonthesurfaceofPbSnanoparticles.ThiscaninduceanefficientchargeseparationbetweenthePbSnanoparticlesanditssurfaceandresultinanultrsafast-inducedabsorptionfornovelPbSnanoparticles.
简介:Electricalpropertyofamicro-plasmaspraysystemwithdifferentworking-gasfeedingschemeswastestedtooptimizetheplasmasprayprocess.Thearcvoltagewithanintegratedgasinjectionmodeishigherthanthatwithradialinjectionoraxialinjectionmodes.Thus,anintegratedgasinjectionmodewithanexcellentelectricalcharacteristicwasadoptedtodepositalumina-titaniacoating.Themicrostructure,bondingstrengthandhardnessoftheplasmasprayedalumina-titaniacoating,asafunctionofthesprayingparameters,e.g.,plasmacurrent,gasflowrateandgaspressure,werestudied.Itwasshownthatthesprayingparametersaffectedremarkablyontheinicrostructureofthecoating.Differenttendenciesinbondingstrengthandhardnesswerealsoshownfordifferentsprayingparameters.Atanarccurrentof250A,agasflowrateof20L/rninandagaspressureof0.5MPa,thebondingstrengthandmicro-hardnessofthecoatingsreach40.6MPaandHV1406.1,respectively.
简介:Ananalyticalstudyispresentedonthemodaldispersioncharacteristics,groupvelocity,andeffectivegroup,aswellasthephaseindexofaternaryonedimensionalplasmaphotoniccrystalforanobliquelyincidentelectromagneticwaveconsideringtheeffectofcollisionsinplasmalayers.Thedispersionrelationisderivedbyusingthetransfermatrixmethodandtheboundaryconditionsbasedonelectromagnetictheory.Thedispersioncurvesareplottedforboththenormalphotonicbandgapstructureandtheabsorptionphotonicbandgapstructure.Itisfoundthattheincreaseintheangleofincidenceshiftsthephotonicbandgaptowardhigherfrequencies.Also,thecutofffrequencyisindependentofcollisions.