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简介：Thestudyofoperatorssatisfyingσja(T)=σa(T)isofsignificantinterest.Doesσja(T)=σa(T)forn-perinormaloperatorT∈B(H)ffThisquestionwasraisedbyMecheriandBraha[Oper.Matrices6(2012),725–734].Inthenoteweconstructacounterexampletothisquestionandobtainthefollowingresult:ifTisan-perinormaloperatorinB(H),thenσja(T)\{0}=σa(T)\{0}.Wealsoconsidertensorproductofn-perinormaloperators.

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简介：采用HF/DFT的混合泛函PBE0和UPBE0优化了配合物[Os（PH3）2（CN）2（N^N）]（其中N^N=2,2′-吡啶）的基态和激发态结构.在基态和激发态结构的基础上,利用含时密度泛函理论（TD-DFT）方法,结合极化连续介质（PCM）模型分别计算了它在二氯甲烷（1）、甲醇（2）、气态（3）和乙腈（4）溶液中的吸收和发射光谱.研究结果表明：优化得到的几何结构参数和相应的实验值符合得非常好.在极性较大的溶剂（2和4）中Os—P（1）和Os—C（1）键较长,Os—N（3）键较短,溶剂的极性会影响配合物的电子云分布.配合物在1-4溶剂中的最低能吸收和发射均来自分子轨道68→71的激发,该激发被指认为[d（Os）＋π（CN）＋π（N^N）→π＊（N^N）]的跃迁具有混合的MLCT/LLCT特征.配合物在1-4溶剂中的最低能吸收和发射分别在471,410,488和445nm以及598,536,634和545nm,表明随着溶剂极性的逐渐增大（3〈1〈4〈2）,最低能吸收和发射发生明显的蓝移.这显示出通过改变溶剂极性可以调节配合物的发光颜色.

简介：以乙酰丙酮和1R，2R-环己二胺进行缩合得到N，N＇-双（乙酰丙酮）-1R，2R-环己二胺的Schiff碱配体L’，以乙酰丙酮和1S，2S-环己二胺进行缩合得到N，N＇双（乙酰丙酮）-1S，2S-环己二胺的Schiff碱配体L^2，然后将L^1和L^2与AgClO4，AgBF4，AgSbF6进行配位反应，得到了3个配合物Ag2（L^1）（L^2）ClO4）2n（1），Ag2（L^1）（L^2）（BF4）2n（2）和Ag2（L^1）（L^2）（SbF6）2n（3），并用元素分析，FT—IR和X-射线单晶衍射进行了表征。结果表明，配合物1-3都属于单斜晶系，空间群P21/n，配合物1的中心Ag（I）离子采用扭曲四面体的配位构型，配合物2和3的中心Ag（I）离子都是近似平面三角形的配位构型。配合物1—3都通过配位作用向空间扩展形成2D网状结构。

简介：利用密度泛函理论（DFT）中的B3LYP方法,在6-311G（d）基组的水平上系统研究了CaSin（n=1-10）团簇的几何构型、稳定性与光谱（红外与拉曼）性质.研究结果表明,CaSin团簇构型是在CaSin-1构型上戴帽1个原子而形成的;当n≥4,CaSin团簇的最低能量结构均为立体构型;Ca原子的掺杂降低了体系的化学稳定性;CaSi3与CaSi5是幻数结构;在相同的观察频段内,CaSi3团簇的红外与拉曼活性在低频段均表现较好,而在高频段拉曼活性则表现较差,与之不同的是CaSi5团簇的红外与拉曼活性在整个频段内都表现的较好.

简介：Inthispaper,theauthorsconstructaφ-groupfornsubmodules,whichgeneralizestheclassicalK-theoryandgivesmoreinformationthantheclassicalones.Thistheoryisrelatedtotheclassificationtheoryforindecomposablesystemsofnsubspaces.

简介：Inthepresentwork,theLEDchipwasirradiatedbyusing59.6MeVNionsinaterminalchamberoftheSector-focusedcyclotron(SFC)intheNationalLabortaryofHeavy-ionAcceleratorsinLanzhou.The63MeVNionspenetratedthroughagoldfoilandscatteredinalargearea.Theenergyofionwasreducedto59.6MeVafterscatteringofthegoldfoil.TheLEDwasprovidedbytheSemiconductorLightingCenterinInstituteofSemiconductorinBeijing.TheluminencesoftheLEDbefore/afterirradiationweretestedthroughaintegratingsphereinSemiconductorLightingCenterinInstituteofSemiconductorinBeijing.Theluminancewastestedunderacurrentof350mA.Fig.1showstherelationshipbetweentheluminencesandtheirradiationfluences.Theirradiationledto

简介：10mol%CuIcombinedwiththeDMEDAligandcanefficientlycatalyzetheN-arylationof2-arylindoleswitharyliodidesandarylbromidesingoodtoexcellentyields.Thearylhalidesbearingelectron-richorelectron-deficientfunctionalgroupscanbewelltoleratedunderthismildreactionconditions.

简介：采用密度泛函理论的B3LYP方法、从头算的MP2方法和自洽反应场极化连续模型（PCM）,在6-311＋＋G（2d,2p）基组水平上研究了N,N’-二甲基-S-异苯并呋喃在气相和溶液中发生S→N烷基重排反应的机理、溶剂效应和取代基效应.结果表明：该反应通过四元环机理和双位迁移机理生成产物,在气相和溶剂水中,双位迁移途径的能垒均比四元环途径低,反应主要通过双位迁移途径生成产物.在气相,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在MP2/6-311＋＋G（2d,2p）水平上比没有取代时分别低4.18,7.61,4.96kJ/mol,反应的取代基效应不明显.而在溶剂水中,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在PCM-MP2/6-311＋＋G（2d,2p）水平上比气相时分别低37.73,39.96和37.17kJ/mol,反应的溶剂化效应非常明显.理论研究结果与实验观察结果一致.

简介：Thebaryonspectrumandthebaryoncouplingsaretwoofthemostimportantissuesinhadronicphysicsandtheyareattractingmuchattention.Bothontheexperimentalandtheoreticalsides,thenucleonexcitedstatesbelow2.0GeVhavebeenextensivelystudied[1].However,thecurrentinformationforthepropertiesofstatesaroundorabove2.0GeVisscarce.Ontheotherhand,inthisenergyregion,manytheoreticalapproacheshavepredictedmissingNstates,whichhavenotbeensofarobserved.Hence,thestudyofthepossibleroleplayedbythe2.0GeVregionnucleonresonancesintheavailableaccuratedataistimelyandcouldshedlightintothecomplicateddynamicsthatgovernsthehighexcitednucleonspectrum.

简介：Inthispaper,weintroducetheclassofn-normedgeneralizeddifferencesequencesrelatedtolp-space.Somepropertiesofthissequencespacelikesolidness,symmetricity,convergence-freeetc.arestudied.Weobtainsomeinclusionrelationsinvolvingthissequencespace.

简介：Anumbilicalfreeorientedhypersurfacex:M→Rnwithnon-zeroprincipalcurvaturesiscalledaLaguerreisoparametrichypersurfaceifitsLaguerreformC=iCiωi=iρ1(Ei(logρ)(rri)Ei(r))ωivanishesandLaguerreshapeoperatorS=ρ1(S1rid)hasconstanteigenvalues.Hereρ=i(rri)2,r=r1+r2+···+rn1n1isthemeancurvatureradiusandSistheshapeoperatorofx.{Ei}isalocalbasisforLaguerremetricg=ρ2IIIwithdualbasis{ωi}andIIIisthethirdfundamentalformofx.Inthispaper,weclassifyallLaguerreisoparametrichypersurfacesinRn(n>3)withtwodistinctnon-zeroprincipalcurvaturesuptoLaguerretransformations.

简介：LargeapertureNd:phosphatelaserglassisakeyopticalelementforaninertialconfinementfusion(ICF)facility.N31,onetypeofneodymiumdopedphosphateglasses,wasdevelopedforhighpeakpowerlaserfacilityapplicationsinChina.ThecompositionandmainpropertiesofN31glassaregiven,togetherwiththoseofLHG-8,LG-770,andKGSS-0180Nd:phosphatelaserglasses,fromHoyaandSchott,andfromRussia.Thetechnologiesofpotmelting,continuousmelting,andedgecladdingoflargesizeN31phosphatelaserglassarebrieflydescribed.ThesmallsignalgainprofilesofN31glassslabsfrombothpotmeltingandcontinuousmeltingatvariousvaluesofthepumpingenergyofthexenonlamparepresented.N31glassischaracterizedbyastimulatedemissioncrosssectionof3.8×10-20cm2at1053nm,anabsorptioncoefficientof0.10–0.15%cm-1atlaserwavelength,smallresidualstressaroundtheinterfacebetweenthecladdingglassandthelaserglass,opticalhomogeneityof～2×10-6ina400mmaperture,andlaserdamagethresholdlargerthan42J/cm2fora3nspulsewidthat1064nmwavelength.

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简介：Inthispaper,theconductionband-edgenon-parabolicity(NP)andthecircularcross-sectionradiuseffectsonhydrogenicshallow-donorimpurityground-statebindingenergyinzinc-blende(ZB)InGaN/GaNcylindricalQWWsarereported.Thefinitepotentialbarrierbetween(In,Ga)NwellandGaNenvironmentisconsidered.Twomodelsoftheconductionband-edgenon-parabolicityaretakingintoaccount.Thevariationalapproachisusedwithintheframeworkofsinglebandeffective-massapproximationwithone-parametric1S-hydrogenictrialwave-function.ItisfoundthatNPeffectismorepronouncedinthewireofradiusequaltoeffectiveBohrradiusthaninlargeandnarrowwires.Moreover,thebindingenergypeakshiftstonarrowwireunderNPeffect.Agoodagreementisshowncomparedtothefindingsresults.

简介：运用变分方法和临界点理论研究2n阶差分方程边值问题非平凡解的存在性，推广和完善了近期的一些结果．

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简介：研究了—（p,q）-Laplacian拟线性椭圆方程组.当连续函数V和W在两种情形下,利用Moser迭代技巧和Ljusternik-Schnirelmann畴数理论,建立了方程组正解的存在性和多重性结果.