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简介：TheeffectofCdionsonsalmonspermDNAwasstudiedbymeansofcirculardichroism(CD),Ramanspectroscopy,X-rayphotoelectronspectroscopy(XPS)andfluorescencespectroscopy.TheCDspectralandfluorescentprobe-acriflavineresultsindicatethattheDNAunderwentaconformationchangeupontheadditionofCdions.XPSandRamanstudiesrevealthatthereexistedinteractionsbetweenCdionsandthephosphategroupsoftheDNA.Inaddition,anewbandappearedat803cm-1intheRamanspectra,whichcanbeattributedtocharacterizing"marker"bandofA-DNA.ItisconcludedthatCdionscanbecoordinatedbythephosphategroupsoftheDNAandinducetheconformationchangesoftheDNAfromB-DNAtoA-DNA.

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简介：Naturalfreshwatersurfacecoatings(biofilmsandassociatedminerals),whichweredevelopedintheNanhuLake,Changchun,P.R.China,wereusedasanefficientbiosorbentfortheremovalofCd(Ⅱ)fromaqueoussolutions.ThebatchexperimentswerecarriedouttodeterminetheadsorptionpropertiesofCd(Ⅱ)ontothenaturalsurfacecoatings.TheclassicalLangmuiradsorptionisothermwasappliedtoestimatingtheequilibriumcoefficientsofCd(Ⅱ)adsorbedonthesurfacecoatings.Theresultsshowthatthemaximumadsorptioncapacityofthesurfacecoatingsis434.78μmolCd/m2(beingequalto0.17mmolCd/gofsurfacecoatingsor10.38mmolCd/gFe)andtheCd(Ⅱ)removalfromsolutionmediabythenaturalsurfacecoatingswasshowntobestronglyaffectedbysolutionpHandionstrength.TheresultedinformationalsoindicatesthatthemaximumCdremovalefficiency(CRE)wasdeterminedtobeapproximately90%atinitialCdmassconcentrationof0.1mg/L(theconcentrationlimitofCd(Ⅱ)inwastewatersfordischargeinaquaticmediainChineselegislation),andthekineticadsorptionofCd(Ⅱ)ontothesurfacecoatingsisfastwitharound70%ofthetotaladsorption-takingplacein150mininsolutionunderthecontrolledlaboratoryconditions(mineralsaltssolutionwithdefinedspeciation,ionicstrength0.05mol/L,and25℃).WiththeadvantageofhighCdadsorptioncapacity,thenaturalsurfacecoatingsappeartobeapotentiallyeffectivebiosorbentfortheremovalandrecoveryofCd(Ⅱ)frompollutedwater.

简介：Ｂｉｎａｒｙ　Ｒｅａｃｔｉｏｎ　Ｍｅｃｈａｎｉｓｍ　ｏｆ　２８Ｓｉ＋２４Ｍｇ　ａｔ　１５６．３　ＭｅＶＢｉｎａｒｙＲｅａｃｔｉｏｎＭｅｃｈａｎｉｓｍｏｆ２８Ｓｉ＋２４Ｍｇａｔ１５６．３ＭｅＶ￥ＷａｎｇＳｈｕｆａｎｇ；ＪｉｎＧｅｎｍ...

简介：新奇分子地印的合成nanofiber被一种简单electrospinning技术准备在哪个polyvinylbutyral(PVB)被选择为矩阵，-cyclodextrin(-CD)作为模板分子被用作功能的单体和naringin(NG)。在由hexamethylenediisocyanate(HMDI)的cross-linked以后，合成nanofiber展出了一个高特定的有约束力的能力。nanofibers的词法结构借助于红外线的光谱(红外)被学习，X光检查衍射(XRD)，和扫描电子显微镜学(SEM)。没有形成阶段，CD分子同类地主要在PVBnanofiber以内被散布分开的水晶的总数。与传统的印的CD聚合物相比，有约束力的实验证明分子地印的合成nanofiber为NG显示出特定的有约束力的地点和选择有约束力的能力。没有任何损失，分子地印的nanofiber能在有约束力的能力被使用至少六次。

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简介：Highlychargedions(HCIs)carryingamountofpotentialenergywillproducesomenewphysicalphenomenabecausethepotentialenergywillbedepositedintoaverysmallvolumewithinaveryshorttime.WewouldapplythecalorimetricmethodtostudytheenergydepositionofHCIs[1;2].Hereinweintroducethenewsetupforcalorimetricmeasurementforthepotentialenergydepositionofhighlychargedionsat320kVHighlyChargedIonsPhysicsExperimentalPlatform.Thesetupwasconstructedby3parts:theDewar,theelectricaltemperaturecontrollerandthemainpart.ThediamondtargetwasconnectedtotheLN2cooledheatsinkby4copperwiresandaPlatinumtemperaturesensorwasgluedtotherearsideofthetarget.AsshowninFig.1.

简介：Duringthepastyear,biophysicsgroupatInstituteofModernPhysics(IMP)obtainedlotsofachievementsintheresearchofheavy-ionmutationbreedingandproductionchainofsweetsorghum.Infundamentalresearchfield,amutantpopulationofArabidopsisthalianainducedbycarbonionbeamradiationwasestablishedinM2generation.Thetotalmutationratewas4.77%.Amutantmarked197#,whichhadfrostbite-like,palegreen,wrinkledandunevenleavesanddisplayedloosebractsandlatematuration,wasobtainedandreportedforthefirsttime.Generoughmappingresultsdemonstratedthatthereweretwomutationsitesinthe1stand4thchromosomeof197#mutant,indicatingheavyionradiationmightinducemorecomplicatedmutationsbeyondourcurrentrecognition.Thewholegenomeresequencingofthismutantisstillinprogress.Inaddition,high-yieldstrainsofmicrobeswhichhavepotentialvalueforcommercialapplication,suchasCorynebacteriumglutamicumandLacbobacillusthermophiles,werescreenedusingheavy-ionmutationtechnique.

简介：Recently,theirradiationeffectsinnanomaterialshavebeenahottopicinnanoscience.Althoughirradiationinduceddamageshavebeenstudyingforalongtime,verylimitedresearchhasbeenperformedonthedamagesinducedbyMeV-energyheavyionsingoldnanowires(NWs).Inthiswork,wereportastudyoftheirradiationeffectsonsinglecrystallinegoldNWs,whicharefabricatedelectrochemicallyintheetchediontracktemplates.Theas-preparedgoldNWsontheAu/CusubstratewerecharacterizedbySEMafterdissolvingthepolycarbonate(PC)template,asshowninFig.1(a).GoldNWswithdiametersfrom20to90nmwerefabricatedtostudythesizedependenceofirradiationdamageinducedbytheheavyions.ToguaranteethatthedifferentNWscouldobtainthesameirradiationfluence,theNWswithdifferentdiametersweremixedtogetherandtransferredtotheTEMgrid,asshowninFig.1(b).

简介：Weperformfirst-principlecalculationsforthestudyoftheorthorhombicRb2Cd2(SO4)3structure.Electronicenergybands,totalandpartialdensitiesofstatesarereportedandanalysed.Itisfoundthatoxygenatomic2pelectronsstronglyhybridizewithRb/orCd4dandS2pstates,resultingintwo-typeionicgroupswithweakcouplings.Itisshownthatmacroscopicdomainwallsoriginatefromsuchweak-couplingionicgroups,arisingatthecellboundaries.Theasymmetriccationbonds(Rb-OandCd-O)andthesubsequentrotationsoftheS04tetrahedracanleadtothedrivingforceoftheferroelectricbehaviour.Thepredictedpyroelectriccurrenteffectsareobservedexperimentallyintheferroelectricphase.

简介：在这份报纸，CD衍生物的三种不同类型作为原子转移激进分子聚合(ATRP)被综合开始者或可逆增加破碎链转移聚合(木排)链转移。为每衍生物的替换的度小心地被描绘通过<啜class=“a-plus-plus”>1H-NMR，<啜class=“a-plus-plus”>13C-NMR光谱学和飞行团spectrometry(MALDI-TOF-MS)的帮助矩阵的激光解吸附作用/电离时间。影响替换的度的因素被讨论。而且，在ATRP和木排之间的比较在N-isopropylacrylamide(NIPAM)的聚合被显示出。

简介：新印离子的聚合物(IIP)被4-vinylpyridine(单体)的copolymerization综合，ethyleneglycoldimethacrylate(cross-linker)和2,2-azobis-isobutyronitrile(开始者)面对Cd2+和quinaldic酸(complexing代理人)。IIP和空白的聚合物的吸附能力分别地是45.0和6.2mgg1，这被发现。为不同二进制混合的印的聚合物的相对选择系数也是计算的。比作非印的聚合物(捏)，IIP为Cd(II)有更高的选择。IIP被使用一个简单的批抽取过程从水样品为镉抽取用作吸着剂。从IIP的Cd2+抽取和它的恢复上的不同参数的效果被使用试验性的设计方法论评估并且优化。优化吸附/解吸附作用过程被申请从真实的水样品的镉移动。获得的恢复证明这IIP能从水样品被用于踪迹镉离子的移动。

简介：以Xilinx公司的28nm系统级芯片（system-on-chip,SoC）Zynq-7000为研究对象,开展了α单粒子效应实验和低能质子单粒子效应实验,测得了系统级芯片的α单粒子效应敏感模块、单粒子效应截面及不同模块质子单粒子效应截面随能量变化的关系曲线。采用软件故障注入技术获得了系统级芯片多个功能单元的敏感单元以及故障表现类型,并且通过建立系统芯片软错误故障树,定量计算了系统芯片及其各功能单元的故障率和不可用度,确定了系统和子系统中的敏感模块。

简介：ＩｎｔｒｏｄｕｃｔｉｏｎＥｌｅｔｒｏｔｈｅｒｍａｌｖａｐｏｒｉｚａｔｉｏｎ（ＥＴＶ）ａｓａｍｅａｎｓｏｆｓａｍｐｌｅｉｎｔｒｏｄｕｃｔｉｏｎｉｎｍｉｃｒｏｗａｖｅｉｎ－ｄｕｃｅｄｐｌａｓｍａ（ＭＩＰ）ｓｏｕｒｃｅｓｐｅｃｔｒｏｍｅｔｒｙｈａｓｂｅｅｎ...

简介：Toexaminetheeffectivenessofirondust-zeolitecompositeasanadsorbentfortheremovalofheavymetalionsfromaqueoussolutions,theadsorptionisotherms,thekinetic,thermodynamicandoptimumconditions,suchasinitialconcentration,pH,contacttime,adsorbentdosageandcompetitiveadsorptionconditionsofheavymetalswereinvestigated.ThecharacterizationofthecompositewascharacterizedviaFTIR,SEM,XRFandXRDmethods.Kineticresultsontheremovalofheavymetalionsfromaqueoussolutionshavebeenwelldescribedbythepseudo-second-ordermodel.TheadsorptiondataforCdandNiionswerefittedwellwiththeLangmuirandFretm-dlichisothermmodels,respectively.Themaximumadsorptioncapacitiesofirondust-zeoliteforCdandNiionswereequalto78.125and76.33mg/g,respectively.Thethermodynamicparameterssuchasenthalpy,entropyandfreeenergyofadsorptionofmetalionsweredetermined.Itwasfoundthattheprocessisendothermic,favorableandspontaneous.ThecompetitiveadsorptionabilityofheavymetalionsinthebinarysystemonthecompositeshowedthatCdionshadasynergisticeffectontheadsorotionofNiandNiionshadthenegativeeffectonCdadsorption.