简介:Inthisresearch,alucunaryKegginstructure,[PMo2W9O39]7-wasselectedasanefficienthomogenouscatalystfordegradationofanazodye(directblue71)andasimplemethodwasdevelopedfordegradationofDB71.ThemethodisbasedontheoxidationofazodyeinthepresenceofalucunaryKegginformofpolyoxometalates,K7[PMo2W9O39]?19H2O,asahomogenouscatalystatroomtemperature.Thereactionismonitoredspectrophotometricallybymeasuringtheabsorbanceofdyeatλ=585nm.Someparametersincludingconcentrationofcatalyst,concentrationofH2O2,pHandreactiontimewereinvestigatedandoptimized.ResultsshowthatK7[PMo2W9O39]?19H2Oismoreefficientinthepresenceofhydrogenperoxide.DegradationofdyeinthepresenceofthecatalystandH2O2couldleadtothedisappearanceapproximately65%ofdyeafter60min.ButdegradationforthesameexperimentperformedintheabsenceofcatalystorintheabsenceofH2O2was22%or5%respectively.Approximately87%azodyeshasbeeneliminatedafter90mininthepresenceofcatalyst,H2O2andoptimizeconditions(0.6g/LofK7[PMo2-W9O39H9H2O,0.08mol/Lhydrogenperoxideandroomtemperature).
简介:TheprecursoryprojectofADSprotonlinearacceleratoristhedevicetoprovideintenseprotonbeamsfortheentiretransmutationsystem,whichhasthefiguresofintensebeamandhighenergy.Asaresult,acontinuousdeflectedbeamwithacertainintensitywoulddeclinetheperformanceoftheacceleratordevicesorevenmakedamageswithin20s.Inordertopreventthiskindofproblem,anintegratemachineprotectionsystemwithfunctionsofstatemonitoringandtimelybeamcuttingisrequiredtoprotectacceleratordevices.
简介:DigitaldecayspectroscopyofactinideisotopesatthegasfilledseparatorSHANSAlloverthechartofnuclides,theregiontothe“north-east”of208Pb,withZ≥84andN=128~130,hoststheshortest-livedαradioactivities,withhalf-livesintherangeofnanosecondstomicroseconds.Synthesisanddetectionofneutron-deficientisotopesabovethoriuminthisregionarechallengingduetotheirlowproductioncrosssectionsandshorthalf-lives.
简介:Thestrategyofsequentiallyspin-coatingaperovskitefilmfromtheperovskiteprecursorandanelectrontransportinglayerof[6,6]-phenyl-C71-butyricacidmethylester(PC71BM)isdevelopedtosimplifythefabricationprocedureofperovskitesolarcells.X-raydiffractionandscanningelectronmicroscopyindicatethatPC71BMfilmonperovskitelayercanretardtheevaporationofdimethylsulfoxide(DMSO)efficiently,thusprolongingthetransformationofintermediatephasetoperovskitecrystals,leadingtoahighqualityperovskitethinfilm.Thesolarcellswiththestructureofindiumtinoxides(ITO)/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)/CH3NH3PbI3/PC71BM/bathocuproine(BCP)/Agmadefromthissimplifiedmethodexhibitahigherefficiency(12.68%)thanthosefromtheconventionalone-stepmethod(9.49%).
简介:获得了HilbertC^*-模之间的两个同构定理.作为推论,证明了C^*-代数上每个可数生成的HilbertC^*-模均稳定酉等价于A。
简介:Thephotonpolarizationtensorcarriesthefundamentalinformationofmagnetizedvacuumormedium[1{5].Acompletedescriptionofthevacuumpolarizationtensorisparticularlycomplicatedtoapproach,sincethevacuumphotonpolarizationtensorisexpressedintermsofadoublesummationofinfiniteserieswithrespecttotwoLandaulevelsoccupiedbyvirtualchargedparticles.MostworkswerefocusingonthestrongfiledlimitwithanassumptionofLowestLandauLevel(LLL)[2,6]InRef.[7]weobtainedafulldescriptionofvacuumpolarizationtensorinresponsetoalltheLandaulevelsatanyfieldstrengthofBforthefirsttimebeyondLLLapproximation,andwefoundoutthattheimaginarypartofthephotonpolarizationtensorξΠbecomesnonzeroatthetimelikemomentaregionQ2>4(M2+2neB)atT=0,i.e..,theLLLapproximationisanalyticallysatisfied[3,7].
简介:Thenovelcomplex[K(18-C-6)]2[Cd(mnt)2][18-C-6-18-crown-6,nmt=1,2-dicyanoethene-1,2-dithiolate,C2S2-(CN)2^2-]wassynthesizedandcharacterizedbyelementalanalysis,IRspectrumandX-raydiffractionanalysis.Thecomplexdisplaystwo-dimensionalnetworkstructureof[K(18-C-6)]complexsegmentsand[Cd(nmt)2]complexsegmentbridgedbyS-K-S,S-K-NandN-K-Ninteractionsbetweenadjacent[K(18-C-6)]and[Cd(mnt)2]units.
简介:HIRFL-CSRacceleratorfacilityhasbeenoperatingwith3ionsources,whichareLAPECR1,LECR3andSECRAL.Theseionsourcescanprovidedifferentkindsofionswithdifferentenergy.Forexample,LAPECR1mainlyprovidesH+andHe+witheextractionvoltageabove25keV,LECR3canprovidetheionbeamswithlowtomediumchargestates,includingthemetallicionswithlowmass,suchasC^4+,Ar^11+,B^3+,Mg^7+,etc.,whileSECRALaimstoproduceintenseandhighlychargedionbeams,especiallymetallicones,suchlikeKr^19+,Xe^31+,Ni^19+,Bi^31+,U^33+,andsoon.
简介:Thestudyonthedecaypropertiesofnewisotopeslocatedfarfromthebetastabilitylineiscurrentthefocusofnuclearphysics.ForisotopesintheregionZ>82andN<126,-emissionprevailsasradioactivedecaymodeand-spectroscopyisthemostimportanttooltoobtaininformationonthenuclearstructure.IntheheavynucleiregionwithN=124and126isotones,anintruderstate(h9=2.f7=2)8+basedontheattractiveinteractionoff7=2protonsandf5=2neutronshasbeensignificantlyobserved,whichincreasesthebindingenergyofthisconfigurationwithincreasingprotonnumber.