简介：我们综合了一系列Nb2Pd1xRuxS5多晶的样品由一固态反应方法并且系统地由运输和磁性的大小在超导性上调查了做Ru效果。超导性被提高，Ru做并且在混乱之上是相当柔韧的，这被发现。霍尔系数大小显示费用运输被类似于做的红外的案例的洞类型费用搬运人统治，建议多乐队超导性。在Ru或红外做之上，Hc2/Tc展出重要改进，超过泡利不相容原理由约4的一个因素的顺磁的限制价值。Tc和上面的关键字段的比较(在Pd地点上的不同的做元素之中的Hc2)，揭示联合的纺纱轨道的一个重要角色。

简介：通过DSC和同步辐射WAXS技术测定了结晶温度对iPP和TMB-5/iPP结晶行为的影响.结果表明,随等温结晶温度升高,iPP总结晶度变化不大,但是β晶型含量降低的同时α晶型含量增加.TMB-5是一种具有温度依赖的选择性成核剂,当等温结晶温度高于140℃时,含TMB-5成核剂的iPP的β晶型的含量急剧降低.本文进一步探讨了TMB-5对iPP结晶行为影响的机理.

简介：Zn/ZSM-5（NZ2）andZn/Ni/ZSM-5（NZ3）asthecatalystsformethanoltoaromatics（MTA）weresynthesizedbyasimpleultrasonicimpregnation.ThetexturalandacidpropertiesofallcatalystswerecharacterizedusingXRD,HRTEM,NH3-TPD,Py-IR,XPS,XRFandTGtechniques.TheXRDandHRTEMresultsshowedthatthebasiczeolitestructureswerenotaffectedmuchwiththeincorporationofZnandNispecies.However,greatchangeshavetakenplaceinacidproperties.ThePy-IRandXPSresultsindicatedthattheZn-Lewisacidsites（ZnOH+species）,whichhavestrongerinteractionwiththezeoliteframeworkcomparedwithZnOspecies,weregeneratedattheexpenseofBacidsiteswiththeincorporationofzincspecies.Moreover,theproductanalysisresultsshowedthattheincorporationofzincspeciespromotedtheprimaryaromatizationbyenhancingthedehydroaromatizationandsuppressingthecrackingandsubsequentH-transferreaction.Furthermore,theadditionofNispecieswellinhibitedthelossofzincspeciesbyconvertingpartialZnOspeciestoZnOH+species,andthusimprovedthearomatizationactivityandcatalyststability.ThecatalyticperformanceresultsshowedthattheNZ3possesshigherconversionofmethanolinalongertimeandloweraveragerateofcokeformationcomparedwithNZ2.Inaddition,theNZ3alsoexhibitedthehighestyieldofBTXasthereactionproceeds.

简介：CarbondepositionduringmethanoltohydrocarbonsleadstothequickdeactivationofZSM-5catalystanditisoneofthemajorproblemsforthistechnology.DecreasingthecrystalsizeorintroducingmesoporesintoZSM-5zeolitescanimproveitsdiffusionpropertyanddecreasethecokeformation.Inthispaper,nano-sizedZSM-5zeolitewithintercrystallinemesoporescombiningthemesoporousandnanosizedstructurewasfabricated.Forcomparison,themesoporousZSM-5andnano-sizedZSM-5werealsoprepared.ThesecatalystsampleswerecharacterizedbyXRD,BET,NH3-TPD,TEM,Py-IRandTGtechniquesandusedontheconversionofmethanoltogasolineinafixed-bedreactoratT=405°C,WHSV=4.74h-1andP=1.0MPa.Itwasfoundthattheexternalsurfaceareaofthenano-sizedZSM-5zeolitewithintercrystallinemesoporesreached104m2/g,largerthanthatofmesoporousZSM-5(66m2/g)andnanosizedZSM-5(76m2/g).Catalyticlifetimeofthenano-sizedZSM-5zeolitewithintercrystallinemesoporeswas93h,whichwasonlylongerthanthatofmesoporousZSM-5(86h),butshorterthanthatofnanosizedZSM-5(104h).Strongaciditypromotedthecokeformationandthusdecreasedthecatalyticlifetimeofthenano-sizedZSM-5zeolitewithintercrystallinemesoporesthoughitpresentedlargeexternalsurfacethatcouldimprovethediffusionproperty.Thespecialzeolitecatalystwasfurtherdealuminatedtodecreasethestrongacidity.Afterthis,itscokeformationratewasslowedandcatalyticlifetimewasprolongedto106hbecauseofthelargeexternalsurfaceareaanddecreasedweakacidity.Thisspecialstructuralzeoliteisapotentialcatalystformethanoltogasolinereaction.

简介：一系列1,3二度(2-alkyltetrazol-5-yl)triazenes被钠亚硝酸根的处理在高收益综合了并且盐酸有substituted-5-aminotetrazoles的酸。所有混合物充分用红外光谱学被描绘，1HNMR和13CNMR光谱学和高分辨率团分光计(HRMS)。大多数这些triazenes展出与TNT可比较、低的好爆炸性能融化从81的点??????獩硯穡汯湩吗？

简介：Two-dimensional（2D）graphitecarbonnitride（g-C3N4）nanosheetshavebeensuccessfullyusedasasaturableabsorber（SA）inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles（g-C3N4-NPs）andthree-dimensionalorderedmesoporousg-C3N4（mpg-C3N4）werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.

简介：Inthispaper,weintroducetheconceptofgeneralizedg-quasi-contractionsinthesettingofconeb-metricspacesoverBanachalgebras.Byomittingtheassumptionofnormalityweestablishcommonfixedpointtheoremsforthegeneralizedgquasi-contractionswiththespectralradiusr(λ)oftheg-quasi-contractiveconstantvectorλsatisfyingr(λ)∈[0,1/s)inthesettingofconeb-metricspacesoverBanachalgebras,wherethecoefficientssatisfiess≥1.Themainresultsgeneralize,extendandunifyseveralwell-knowncomparableresultsintheliterature.

简介：Unlikeorganic–inorganichybridperovskites,all-inorganiccesiumleadhalideperovskitesholdgreatpromisefordevelopinghigh-performanceoptoelectronicdevices,owingtotheirimprovedstability.Herein,weinvestigatetheperovskite-relatedCsPb2Br5nanoplatelets（NPLs）withtunableemissionwavelengthsviachangingthereactiontemperaturesto100°C,120°C,and140°C.ReactiontemperatureplaysakeyroleindeterminingtheshapesandthicknessesoftheresultingCsPb2Br5NPLs.AhighertemperatureisinfavoroftheformationofsmallerandthickerNPLs.Todeveloptheirpotentialapplicationsinoptoelectronicdevices,greenlightemittingdiodes（LEDs）andphotodetectorsbasedonCsPb2Br5NPLsarefabricated.ThegreenLEDsbasedonCsPb2Br5NPLssynthesizedat140°Cexhibitanexcellentpuregreenemission（fullwidthathalf-maximumof<20nm）anddisplayaluminousefficiencyof34.49lm∕Wunderanoperationcurrentof10mA.Moreover,thephotodetectorbasedonCsPb2Br5NPLssynthesizedat100°Chasbetterperformancewitharisetimeof0.426s,adecaytimeof0.422s,andaratioofthecurrent（withandwithoutirradiation）of364%.

简介：Aserialofprotonatedandlayeredtransitionmetaloxides,includinglayeredHTaWO6,HNbMoO6aswellasHNbWO6,weresynthesizedbysolid-statereactionandion-exchange.ThelayeredHTaWO6hasbeensystematicallystudiedasasolidacidtorealizethedehydrationoffructoseto5-hydroxymethylfurfural（HMF）.ThetransitionmetaloxidesampleswerecharacterizedwithICP-OES,EDS,XRD,XPS,SEM,TGA,FT-IR,N2adsorption–desorptionandNH3-TPD.Theinfluentialfactorssuchasreactiontemperature,reactiontime,solvent,catalystamountandsubstrateconcentrationweredeeplyinvestigated.Theoptimizedfructoseconversionrateof99%withHMFyieldof67%wereachievedafter30minat140°Cindimethylsulfoxide.

简介：

简介：NanosizedGa-containingZSM-5zeoliteswerepreparedviaisomorphoussubstitutionandimpregnationfollowedbycharacterizedusingvarioustechniques.Thecatalyticperformanceofthezeolitesforthearomatizationof1-hexenewasinvestigated.TheresultsindicatethatisomorphoussubstitutionpromotestheincorporationofGaheteroatomsintotheframeworkalongwiththeformationofextra-frameworkGaO+species（[GaO+]a）thathavestrongerinteractionswiththenegativepotentialoftheframework.Inaddition,basedonthePy-IRresultsandcatalyticperformance,the[GaO+]aspecieswithstrongerLewisacidsitesproducedabettersynergismwithmoderateBr?nstedacidsitesandthusimprovedtheselectivitytoaromaticcompounds.However,theimpregnationresultsintheformationofGa2O3phaseandsmallamountsofGaO+speciesthataremainlylocatedontheexternalsurface（[GaO+]b）,whichcontributetoweakerLewisacidsitesduetoweakerinteractionswiththezeoliteframework.During1-hexenearomatization,thenanosizedGaisomorphouslysubstitutedZSM-5zeolitesamples（Gax-NZ5）exhibitedbettercatalyticperformancecomparedtotheimpregnatedsamples,andthehighestaromaticyield（i.e.,65.4wt%）wasachievedovertheGa4.2-NZ5sample,whichcontainedwiththehighestGacontent.

简介：建立了一种电感耦合等离子体质谱（ICP-MS）法测定环境水样中Cu、Zn、Mn、Pb、Cd5种重金属元素含量的方法。经过仪器条件优化和干扰校正后,方法中5种元素的工作曲线的相关系数均大于0.999,检出限为0.014-0.22μg/L。对加入国家标准物质作为质控样15个批次的环境水样进行统计分析并绘制质控图。同时与原子吸收光谱法测定结果进行对比分析,测定值与标准值基本一致,质控样的测定值基本都在控制线范围之内。结果表明,方法精密度和准确度均能满足环境水样的分析,ICPMS法更适用于大批量、多样化环境水样的监测分析。

简介：Theneworganic-inorganiccompound,[C_6H_7N_2O_2]_3TeCl_5·2Clwassynthesizedanditsstructurewasdeterminedatroomtemperatureinthetriclinicsystem(P~-1)withthefollowingparameters:a=10.5330(11)?,b=10.6663(11)?,c=15.9751(16)?,α=82.090(2)°,β=71.193(2)°,γ=68.284(2)°andZ=2.ThefinalcycleofrefinementledtoR=0.057andRw=0.149.ThecrystalstructurewasstabilizedbyanextensivenetworkofN--H···Clandnon-classicalC--H···Clhydrogenbondsbetweenthecationandtheanionicgroup.Severalthermalanalysistechniquessuchasthermogravimetricanalysis,differentialscanningcalorimetricanalysisandevolvedgasanalysiswereused.Weusedisoconversionalkineticsmethodstodeterminethekineticsparameters.Weobservethatthedecompositionof[C_6H_7N_2O_2]_3TeCl_5·2Clentailstheformationhydrochloricacidofnitroanilineasvolatiles.Theinfraredspectrawererecordedinthe4000–400cm~(-1)frequencyregion.TheRamanspectrawererecordedintheexternalregionoftheanionicsublatticevibration50–1500cm~(-1).TheopticalbandgapwascalculatedfromtheUV-VisabsorbancespectrausingclassicalTaucrelationwhichwasfoundtobe3.12and3.67eV.

简介：为了充分利用原有机电控制技术试验台,满足机电控制技术课程实践教学的需要,并为先进控制系统研究提供实验平台,改造了原有的机电控制综合实验装置.该装置以电机为实验对象,增加实验对象加载装置,用VC＋＋编写了控制界面,通过PC及PLC两级控制,完成电机特性测试、机电传动系统控制等实验内容.经使用表明,该套实验装置操作简单、开放性好、实战性强.通过本实验台,可提髙学生动手能力,完成了工程实践能力的培养.

简介：基于百千安快脉冲直线变压器驱动源（fastlineartransformerdriver,FLTD）平台,设计了一种负载电流倍增结构（loadcurrentmultiplier,LCM）,并进行了实验验证。在电容器充电电压为±30kV,LCM电感为25nH的条件下,实现了负载电流的有效倍增,电流倍增系数κ为1.5,与理论估算值1.6接近。负载电流倍增技术可用于实验室现有脉冲功率装置的改造升级和后续装置的设计中,以提高负载电流。

简介：MatlabGUI是强大的科学计算软件Matlab的可视化编程平台,一种类似C＋＋的面向对象的开发语言,可以进行互动式界面开发,完成实验输入数据的自动化读取、参数的个性化设定以及输出结果的快速可视化.在进行网络版实验平台开发前期,可以用其进行数据流程的测试和优化.本文在阐述GUI试验建设的关键技术框架的基础上,完成Excel数据读取、基于文本框的参数设置、Click事件调用函数,Table、Ax输入及输出结果的可视化.通过本文,可以帮助具备.m文件的科学实验者,掌握开发Matlab界面的关键技术,实现快速本地化试验平台的搭建.

简介：在低Reynolds数条件下,翼型绕流的上表面边界层由于抗逆压梯度能力变差容易发生流动分离,从而形成长层流分离泡.分离泡通常是非定常的,会诱发边界层的转捩、再附并形成湍流边界层.这个过程会使翼型的气动性能急剧下降,并伴随着强非线性效应.转捩后形成的湍流边界层也会产生高摩擦阻力.针对这种现象,文章以NACA0012翼型为例,通过隐式大涡模拟研究了有效的主动控制方案.为了统一分离控制技术和湍流边界层减阻技术,研究了在平板或槽道湍流中取得较好控制效果的壁面垂向反向控制方案.首先利用隐式大涡模拟研究了低Reynolds数条件下NACA0012翼型绕流的流场特征.其次分析并验证了反向控制方案在分离区控制流场的可行性,发现反向控制在分离区的作用相当于基于流场信息的壁面抽吸控制,且控制具有实时性和高效性,控制抽吸了前缘的低能流体,使得翼型前缘附面层变薄,并增强了其抗逆压梯度的能力,较大程度提高了翼型的气动性能.最后在湍流边界层验证了其减阻控制效果,发现反向控制阻断了流向涡的法向输运,抑制了涡结构的发展,并减弱了猝发过程,使得湍流的高摩阻力得到了有效降低.

简介：超市的繁荣发展对我国经济的发展有着极大的影响,确保成本与效益的优化平衡对于超市的持续发展至关重要。通过推进电子订货系统,优化存货配置,使用网络资源自动补货系统,增强储存产品的管理,能够帮助企业实现预期的治理控制目标。

简介：以近代物理实验中的微波技术实验为例,详细介绍了用Origin9.0软件进行绘图和非线性拟合处理实验数据的方法,对实验测定的数据进行绘图、计算、拟合.该软件的应用,能够有效避免人工计算处理所带来的误差,大大简化实验数据处理过程,获得人工绘图难以获得的更多的信息量,且运用软件结果高效准确.

简介：http：//www.csoe.org.cn/aopc2017/June4-6,2017中国光学工程学会（CSOE）联合国际光学工程学会（SPIE）定于2017年6月4-6日在北京国际会议中心举办2017年国际应用光学与光子学技术交流会（AOPC2017）。大会分8个分会,规模近千人,国内外知名专家200余位被特邀出席。大会期间将举办中国光学工程学会第二届光学工程优博和第三届科技创新奖颁奖盛典!