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200 个结果
  • 简介:对化合物[Na_2(H_2O)_(10)][Cu_4(H_2O)_(12)(H_2W_(12)O_(42))]·15H_2O(简称Na_2Cu_4W_(12))进行了体外抗肿瘤活性研究.应用四甲基偶氮唑盐(3-[4,5-dimethylthiazo-2-y]-2,5-diphenyltetrazoliumbromide,MTT)比色法分析Na_2Cu_4W_(12)对人肝癌细胞(HepG2)、人神经母细胞瘤细胞(SHY5Y)增殖抑制活性.采用光学显微镜观察肿瘤细胞的凋亡形态变化,用流式细胞术分析细胞周期和细胞凋亡,计算各期细胞比例及细胞凋亡率.结果表明,Na_2Cu_4W_(12)对HepG2和SHY5Y2肿瘤细胞增殖半数抑制浓度IC_(50)值分别为5.3和10.2μmol·L~(-1),且呈剂量依赖性.光学显微镜下处理组细胞出现皱缩、变圆、缩小等形态变化,不同浓度Na_2Cu_4W_(12)处理12h早期凋亡细胞所占的百分比显著增加且呈剂量依赖性.综上所述,Na_2Cu_4W_(12)能够抑制胞瘤细胞增殖,诱导细胞凋亡.

  • 标签: 仲钨酸盐化合物 抗肿瘤 体外研究
  • 简介:Inthispaper,wefirstshowtheglobalexistence,uniquenessandregularityofweaksolutionsforthehyperbolicmagnetohydrodynamics(MHD)equationsinR~3.ThenweestablishthatthesolutionswithinitialdatabelongingtoH~m(R~3)∩L~1(R~3)havethefollowingtimedecayrate:║▽~mu(x,t)║~2+║▽~mb(x,t)║~2+║▽~(m+1)u(x,t)║~2+║▽~(m+1)b(x,t)║~2≤c(1+t)~(-3/2-m)forlarget,wherem=0,1.

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  • 简介:Firstly,theRiemannboundaryvalueproblemforakindofdegenerateellipticsystemofthefirstorderequationsinR~4isproposed.Then,withthehelpoftheone-to-onecorrespondencebetweenthetheoryofCliffordvaluedgeneralizedregularfunctionsandthatofthedegenerateellipticsystem’ssolution,theboundaryvalueproblemasstatedaboveistransformedintoaboundaryvalueproblemrelatedtothegeneralizedregularfunctionsinCliffordanalysis.Moreover,thesolutionoftheRiemannboundaryvalueproblemforthedegenerateellipticsystemisexplicitlydescribedbyusingakindofsingularintegraloperator.Finally,theconditionsfortheexistenceofsolutionsoftheobliquederivativeproblemforanotherkindofdegenerateellipticsystemofthefirstorderequationsinR~4arederived.

  • 标签: 退化椭圆型方程 黎曼边值问题 广义正则函数 椭圆系统 奇异积分算子 一阶方程
  • 简介:Westudytheconsistencyconditionsofthegeneralizedf(R)gravitybyextendingf(R)gravitywithnon-minimalcouplingtothegeneralizedf(R)witharbitrarygeometry-mattercoupling.Specifically,wediscussthetwoparticularmodelsofgeneralizedf(R)bymeansofconsistencyconditions.Itisfoundthatthesecondmodelisnotphysicallyviablesoastoberuledout.Moreover,wefurtherconstrainthefirstmodelusingtheDolgovKawasakistabilitycriterion,andgivethevaluerangesoftheparametersinthefirstmodel.Itisworthstressingthatourresultsincludetheonesinf(R)gravitywithnon-minimalcouplingasthespecialcaseofQ(L_m)=L_m.

  • 标签: 一致性条件 几何体 耦合 广义 二次模型 相容性条件
  • 简介:以“闪光二”加速器硬X射线为辐照源,对腔体内系统电磁脉冲(systemgeneratedelectromagneticpulse,SGEMP)磁场环境的验证方法进行了研究。根据测量的“闪光二”二极管的电压、电流,模拟了发射电子束能谱参数;结合辐射靶物理设计,建立了二极管阳极靶蒙特卡罗粒子输运计算模型,模拟了轫致辐射X射线场参数;采用时域有限差分(finitedifferencetimedomainmethod,FDTD)和粒子模拟(particleincell,PIC)方法,模拟了该射线环境的腔体SGEMP磁场环境;将轫致辐射X射线参数及腔体SGEMP磁场环境的模拟结果与实验结果进行了比较。结果表明:从X射线源参数模拟开始的腔体内SGEMP数值模拟计算模型的实验验证方法是合理可行的。

  • 标签: 闪光二号 系统电磁脉冲 粒子输运 粒子模拟 验证
  • 简介:依据量子信息学和量子计算基本理论,在研究低剂量I射线与神经细胞的相互作用规律及物理机理时,将神经细胞骨架微管的两种蛋白构型视为两能级原子体系,使用密度矩阵描述脑神经系统中信息位的状态,建立并求解系统的动力学方程。结果表明:随密度矩阵非对角元素的减小,系统的量子相干性迅速降低。因此,低剂量I辐射可以影响受照者的脑神经功能。

  • 标签: BI辐射 神经细胞 物理机理 两能级原子
  • 简介:Recently,Cristofaro-GardinerandHutchingsprovedthatthereexistatleasttwoclosedcharacteristicsoneverycompactstar-shapedhypersufaceinR~4.ThenGinzburg,Hein,Hryniewicz,andMacarinigavethisresultasecondproof.Inthispaper,wegiveitathirdproofbyusingindexiterationtheory,resonanceidentitiesofclosedcharacteristicsandaremarkabletheoremofGinzburgetal.

  • 标签: 封闭特征 星形 紧凑 封闭特性 超曲面 证明
  • 简介:AnewlayeredCu-basedoxychalcogenideBa3Fe2O5Cu2S2hasbeensynthesizedanditsmagneticandelectronicpropertieswererevealed.Ba3Fe2O5Cu2S2isbuiltupbyalternativelystacking[Cu2S2]2-layersandironperovskiteoxide[(FeO2)(BaO)(FeO2)]2-layersalongthecaxisthatareseparatedbybariumionswithFe3+fivefoldcoordinatedbyasquare-pyramidalarrangementofoxygen.Fromthebondvalencearguments,weinferredthatinlayeredCuCh-based(Ch=S,Se,Te)compoundsthe+3cationinperovskiteoxidesheetprefersasquarepyramidalsite,whilethelowervalencecationprefersthesquareplanarsites.Thestudiesonsusceptibility,transport,andopticalreflectivityindicatethatBa3Fe2O5Cu2S2isanantiferromagneticsemiconductorwithaNe′eltemperatureof121Kandanopticalbandgapof1.03eV.Themeasurementofheatcapacityfrom10Ktoroomtemperatureshowsnoanomalyat121K.TheDebyetemperatureisdeterminedtobe113K.TheoreticalcalculationsindicatethattheconductionbandminimumispredominantlycontributedbyO2pand3dstatesofFeionsthatantiferromagneticallyarrangedinFeO2layers.TheFe3dstatesarelocatedatlowerenergyandresultinanarrowbandgapincomparisonwiththatoftheisostructuralSr3Sc2O5Cu2S2.

  • 标签: 钙钛矿型氧化物 铁磁半导体 光学带隙 德拜温度 电子性质 阳离子
  • 简介:Inthisarticle,theSm-dopingsinglecrystalsCa1-xSmxFe2As2(x=00.2)werepreparedbytheCaAsfluxmethod,andfollowedbyarapidquenchingtreatmentafterthehightemperaturegrowth.Thesampleswerecharacterizedbystructural,resistive,andmagneticmeasurements.ThesuccessfulSm-substitutionwasrevealedbythereductionofthelatticeparameterc,duetothesmallerionicradiusofSm3+thanCa2+.SuperconductivitywasobservedinallsampleswithonsetTcvaryingfrom27Kto44KuponSm-doping.ThecoexistenceofacollapsedphasetransitionandthesuperconductingtransitionwasfoundforthelowerSm-dopingsamples.ZeroresistivityandsubstantialsuperconductingvolumefractiononlyhappeninhigherSm-dopingcrystalswiththenominalx>0.10.Thedopingdependencesofthec-axislengthandonsetTcweresummarized.Thehigh-TcobservedinthesequenchedcrystalsmaybeattributedtosimultaneoustuningofelectroncarriersdopingandstraineffectcausedbylatticereductionofSm-substitution.

  • 标签: 掺杂晶体 超导电性 SM 单晶 晶格参数 淬火温度
  • 简介:TostudytheintramolecularDiels-Aldercycloadditonof2H-chromen-2-oneasadiene,aseriesofchiralN-allyl-N-benzylamidesthatcontaina2H-chromen-2-onemoietyweredesignedforthesynthesisofbenzo[f]isoindol-l-onesviaanintramolecularDiels-Alderandasubsequentretro-Diels-AldercycloadditionwiththeexpulsionofCO2.Boththeyield(80%-89%)andabsolutestereocontrolofthetandemreactionwerehighwhenanelectron-withdrawinggroupwasattachedtothedienophile.Thedoublebondinthestyrenesubstructureremainedintheproductscouldbefurtherderivatizedbydihydroxylation.

  • 标签: 环加成反应 串联反应 二烯烃 CO2 分子内 吸电子基团
  • 简介:对“春雷”有界波电磁脉冲模拟装置的传输线进行了设计改造,新传输线长27m,宽10m,高6m,采用锥板接分布式负载结构。对模拟装置新传输线的传输性能进行了实测与仿真计算。结果表明:新传输线负载电阻链形成的反射波叠加在波形后延,引起宽脉宽HEMP波形的畸变。同时,新传输线工作空间的电场分布不均匀,与仿真结果相差较大,最大偏差可达18%。

  • 标签: “春雷”号 高空核电磁脉冲 电磁脉冲模拟器 有界波 传输线
  • 简介:Takingadvantageofthelargeγ-detectorarrayGammasphereandtherecoilmassseparatorFMA,highspinstatesin117Bawereinvestigatedthroughtherecoil-β-delayedprotondecaytaggingtechniqueviatheheavy-ioninducedfusion-evaporationreaction64Zn(58Ni,2p3n)117Ba,atabeamenergyof305MeV.Promptγraysbelongingto117Bahavebeenidentifiedfurthermore,arotationalbandhasbeenidentifiedforthefirsttimeandpresentedasbandAinFig.1.

  • 标签: ADVANTAGE FMA VIA HAS
  • 简介:Anewmethodforfabricatingorderedporoussiliconisreported.Atwo-dimensionalsilicananospherearrayisusedasatemplatewithahydrofluoricacid-hydrogenperoxidesolutionforetchingthenanospheres.Theinitialdiameteranddistributionoftheholesintheresultingporoussiliconlayeraredeterminedbythesizeanddistributionofthesilicananospheres.Thecorrosiontimecanbeusedtocontrolthedepthsoftheholes.ItisfoundthatthepresenceofaSiO_2layer,formedbytheoxidationoftheroughinternalsurfaceofthehole,istheprimaryreasonallowingthecorrosiontoproceed.Ultravioletreflectionandthermalconductivitymeasurementsshowthatthediameteranddistributionoftheholeshaveagreatinfluenceonpropertiesoftheporoussilicon.

  • 标签: 二氧化硅层 制备方法 多孔硅 有序 模板 二维
  • 简介:我们揭示并且解释thermopowerS/T的可伸缩的行为展出了由典型重费米子(HF)金属YbRh2在在温度T的磁场B的申请下面的Si2。我们证明一样的可伸缩被不同HF混合物例如表明?-YbAlB4和强烈相关的分层的钴氧化物[BiBa0.66K0.36O2]CoO2。用YbRh2是的Si2一个例子,,我们证明S/T的可伸缩的行为在antiferromagnetic阶段转变被违背剩余抵抗力0和状态的密度,N,经验在阶段转变跳,引起thermopower做二跳并且改变它的符号。我们的说明基于深刻地影响0和N的单个粒子的光谱变平。描绘S/T行为的主要特征,我们构造TBYbRh2Si2。我们为HF混合物的计算S/T在对试验性的事实的好同意并且支持我们的观察。

  • 标签: 标度行为 重费米子 热电势 金属 原型 铁磁相变
  • 简介:Twofamiliesofcatalysts,basedonPdnanoparticlessupportedonceramicasymmetrictubularaluminamembranes,arestudiesinthedirectsynthesisofH_2O_2.TheyarepreparedbydepositingPdintwoways:(i)reductionwithN_2H_4inanultrasonicbathand(ii)byimpregnation-deposition.Thefirstpreparationleadstolargerparticles,withaveragesizeofaround11nm,whilethesecondpreparationleadstosmallerparticles,withaveragesizearound4nm.Thecatalyticmembranesweretestedasprepared,afterthermaltreatmentinairandafterfurtherpre-reductionwithH_2inmild(100℃)conditions.SampleswerecharacterizedbyTEM,CO-chemisorptionmonitoredbyDRIFTSmethodandTPR,whilecatalytictestshavebeenperformedinasemi-batchrecirculationmembranereactor.Experimentalcatalyticresultswereanalysedusingtwokineticsmodelstoderivethereactionconstantsfortheparallelandconsecutivereactionsofthekineticnetwork.SmallerparticlesofPdshowlowerselectivityduetothehigherrateofparallelcombustion,evenifthebetterdispersionofPdandthushighermetalsurfaceareainthesampleleadtoaproductivityinH_2O_2similarorevenhigherthanthesamplewiththelargerPdparticles.IndependentlyonthepresenceofsmallerorlargerPdnanoparticles,anoxidationtreatmentleadstoasignificantenhancementintheproductivity,althoughthecatalystprogressivelyreducesduringthecatalyticprocess.Theinhibitionoftheparallelcombustionreaction(towater)inducedfromthecalcinationtreatmentremainsafterthein-situreductionoftheoxidizedPdspeciesformedduringthepre-treatment.Thisislikelyduetotheeliminationofdefectsiteswhichdissociativelyactivateoxygen,andtentativelyattributedtoPdsitesabletogivethree-andfour-foldcoordinationofCO.

  • 标签: 钯纳米粒子 过氧化氢 直接合成 预处理 TEM样品 动力学模型
  • 简介:Nuclearmassisoneofthefundamentalquantityofatomicnucleus.Thetotalbindingenergyofanucleusderivedfromtherelatedmassvaluesreflectsalltheinteractionsamongtheconstitutingnucleons.Massesofshort-livedA=2Z+3nucleiof112SnprojectilefragmentshavebeenmeasuredattheexperimentalcoolerstorageringCSRe,employingtheIsochronousmassspectrometry(IMS).TheexperimentwasconductedattheHeavyIonResearchFacilityinLanzhouatthebeginningof2016.Theprimarybeamof112Sn35+wasaccumulatedinthesynchrotronCSRmandacceleratedto467.91MeV/u.Secondarybeamwereproducedbyimpingingthehighintensity112Sn35+beamontoa10mmberylliumtargetwhichwaslocatedattheentranceoftheradioactivebeamlineRIBLL2.Theprojectilefragmentsof112Snemergedfromthetargetwerethentransmitted,separatedinflightthroughRIBLL2andfinallyinjectedintoCSRe.

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  • 简介:Lifetimemeasurementsoflow-lyingexcitedstatesin^87Zrhavebeenperformedviaβ-γcoincidences.The127MeV^32SbeamwasdeliveredfromtheSector-FocusingCyclotron(SFC)oftheHeavyIonResearchFacilityinLanzhou(HIRFL).Theparentnuclei^87Nbwereproducedbythereaction58Ni(32S,2p1n),atabeamenergy127MeVthrougha8umAldegrader.A200ug/cm^2layerof58Nievaporatedontoa200ug/cm^2thickcarbonfoilwasemployedasthetarget.Afterevaporationresidueswereseparatedfromtheprojectilebeamsbythegas-filledrecoilseparatorSHANS[1],thenucleiofinterest87Zrcanbeobtainedwithahigherpurityandthenwereimplantedintoa300umsilicondetector.

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