简介:Tungstenisregardedasanimportantcandidateofplasmafacingmaterialininternationalthermonuclearexperimentalreactor(ITER),sothedeterminationandmodelingofspectraoftungstenplasma,especiallythespectraathightemperaturewereintenselyfocusedonrecently.Inthiswork,usingtheatomicstructurecodeofCowan,acollisionalradiativemodel(CRM)basedonthespin-orbit-split-arraysisdeveloped.Basedonthismodel,thechargestatedistributionoftungstenionsisdeterminedandthesoftX-rayspectrafromhighchargedionsoftungstenatdifferenttemperaturesarecalculated.Theresultsshowthatboththeaverageionizationchargeandlinepositionsarewellagreedwithotherscalculationsandmeasurementswithdiscrepanciesoflessthan0.63%and1.26%,respectively.Thespectraathighertemperaturesarealsoreportedandtherelationshipbetweenionabundanceandtemperatureispredictedinthiswork.
简介:传统的化学分析方法分析硅酸盐类矿物样品组份,操作过程繁琐、分析周期长、劳动强度较大,分析结果受分析人员及各种试剂因素影响较大。采用国产能量色散X-射线荧光分析仪,以Li2B4O7和LiBO2作混合熔剂,NH4NO3为氧化剂,熔融制作玻璃熔片,对硅酸盐中SiO2等10个主要成分含量进行同时分析,建立了能量色散X-射线荧光光谱法测定硅酸盐主成分含量的方法,准确度和精密度均达到了规范要求,得到了较为满意的分析结果。
简介:Novelsulfur-containingcompounds(3a–3c,4a–4c)wereobtainedinethanolwith1,3-diphenyl-2-propanoneasthestartingmaterial.Theadvantagesofthisprocedureweremildreactionconditions,simpleprotocol,andhighyields.ThestructuresoftheproductswerecharacterizedbyIR,1HNMR,MSandelementaryanalysis.Thecrystalofthenewcompound4abelongstomonoclinic,spacegroupC2witha=18.727(3),b=6.5179(9),c=13.7576(18),b=131.0610(10)°,V=1266.2(3)A3,Z=2,Dc=2.136g/cm3,μ=1.078mm-1,F(000)=843,R=0.0490andwR=0.1247for3211observedreflectionwithI>2δ(I).X-rayanalysisrevealsthatthemoleculeisnotsymmetrical,themolecularstructureisstabilizedbyweakp–pstackinginteractions,andnoclassicalhydrogenbondscanbeobserved.
简介:Basedonconsolidationequationsproposedforunsaturatedsoil,ananalyticalsolutionfor1Dconsolidationofanunsaturatedsingle-layersoilwithnonhomogeneousmixedboundaryconditionisdeveloped.Themixedboundaryconditioncanbeusedforspecialapplications,suchastestsoccurinlaboratory.Theanalyticalsolutionisobtainedbyassumingallmaterialparametersremainconstantduringconsolidation.Inthederivationoftheanalyticalsolution,thenonhomogeneousboundaryconditionisfirsttransformedintoahomogeneousboundarycondition.Then,theeigenfunctionandeigenvaluearederivedaccordingtotheconsolidationequationsandthenewboundarycondition.Finally,usingthemethodofundeterminedcoefficientsandtheorthogonalrelationoftheeigenfunction,theanalyticalsolutionforthenewboundaryconditionisobtained.Thepresentmethodisapplicabletovarioustypesofboundaryconditions.Severalnumericalexamplesareprovidedtoinvestigatetheconsolidationbehaviorofanunsaturatedsingle-layersoilwithmixedboundarycondition.
简介:采用粉末样品直接压片法,使用自制校准样品在布鲁克S2RANGEREDX光谱仪上通过各种基体干扰校正手段,建立了基夫赛特直接炼铅炉渣中Pb,Zn,Cu,Fe,SiO2,CaO的测定工作曲线,并考察了样品粒度、制样条件对结果的影响以及考核了压片精度和方法准确度。方法简便快捷、精密度高、准确度满足主产工艺指标要求。
简介:EQrot1nonconformingfiniteelementapproximationtoaclassofnonlineardualphaselaggingheatconductionequationsisdiscussedforsemi-discreteandfully-discreteschemes.Byuseofaspecialproperty,thatis,theconsistencyerrorofthiselementisoforderO(h2)oneorderhigherthanitsinterpolationerrorO(h),thesupercloseresultsoforderO(h2)inbrokenH1-normareobtained.Atthesametime,theglobalsuperconvergenceinbrokenH1-normisdeducedbyinterpolationpostprocessingtechnique.Moreover,theextrapolationresultwithorderO(h4)isderivedbyconstructinganewinterpolationpostprocessingoperatorandextrapolationschemebasedontheknownasymptoticexpansionformulasofEQrot1element.Finally,optimalerrorestimateisgainedforaproposedfully-discreteschemebydifferentapproachesfromthepreviousliterature.