简介:轧了nanorods被磁控管劈啪作响和加氨系统综合,并且Tb中间的层的厚度被改变学习效果在上轧了nanorods。结果被扫描电子测试显微镜学(SEM),X光检查衍射(XRD),传播电子显微镜学(TEM),高分辨率的传播电子显微镜学(HRTEM),和光致发光(PL)系列。结果证明Tb层的厚度在形式,质量,和光性质上有明显的效果轧了nanorods。在房间温度的PL系列在368点显示出一座很强壮的排放山峰?nm和弱排出物在387点达到顶点?当Tb层是20时,为生产样品的山峰的nm,和紧张到达最大值?nm。最后,20的最佳的厚度?为综合的Tb中间的层的nm轧了nanostructures被完成。
简介:Thestructure,CurietemperatureandmagnetostrictionofPr0.15Tb0.30Dy0.55Fe1.85Cx(x=0-0.1)compoundswereinvestigatedbyX-raydiffraction,avibratingsamplemagnetometerandastandardstraintechnique.AllthesamplesshowentirelyMgCu2-typeLavesphasestructure.ThelatticeparameterandCurietemperatureincreasewithCcontentincreasing.Themagnetostrictionathighmagneticfieldshowsmaximumvalueatx=0.05.
简介:ThedosimetricphosphorsLi_3PO_4:M(M=Tb,Cu)wereproducedbymodifiedsolid-statemethod.ThestructuralandmorphologicalcharacterizationwascarriedoutthroughX-raydiffraction(XRD)andscanningelectronmicroscope(SEM).Additionally,thephotoluminescence(PL),thermoluminescence(TL)andopticallystimulatedluminescence(OSL)propertiesofpowderLi_3PO_4dopedwithTbandCuwerestudied.ItisadvocatedthatLi_3PO_4:CuphosphornotonlyshowshigherOSLsensitivity(25timesormore)butalsogivesfasterdecayinOSLsignalsthanthatofLi_3PO_4:Tb~(3+)phosphor.Theminimumdetectabledose(MDD)ofLi_3PO_4:M(M=Tb,Cu)phosphorsisfoundtobe21.69×10~(-3)and3.33×10~(-6)J·kg~(-1),respectively.InOSLmode,phosphorshowslineardoseresponseintherangeof0.02-20.00J·kg~(-1).InTLmode,sensitivityofLi_3PO_4:CuphosphorismorethanthatofLi_3PO_4:Tbphosphor.Thekineticsparameterssuchasactivationenergyandfrequencyfactorsweredeterminedbypeakshapemethod,andphotoionizationcrosssectionsofpreparedphosphorwerecalculated.
简介:本文对TB6钛合金锻件弦向和径向两种取样方向分别进行了室温和200℃下旋转弯曲高周疲劳、轴向低周疲劳和疲劳裂纹扩展性能试验研究。试验结果表明,弦向(C)和径向(R)两种取样方向对该合金锻件的旋转弯曲高周疲劳、轴向低周疲劳性能和疲劳裂纹扩展性能没有影响;温度升高可加速该合金锻件的疲劳裂纹萌生,但在裂纹扩展阶段,该合金高温下的韧性优势与屈服强度降低的劣势平衡的结果使其在室温~200℃温度范围内的疲劳性能基本不受温度的影响;在10—20mm的厚度范围内,厚度对该合金的疲劳裂纹扩展性能没有影响;在3.5%NaCl盐雾环境中。腐蚀介质对TB6钛合金的疲劳裂纹扩展速率在初始阶段有迟滞作用,但在应力强度因子范围大于14MPam后有加速作用。
简介:ThemicrostructureandmagnetostrictivepropertieswereinvestigatedintheTbdopedFe83Ga17-xTbx(x=0.05,0.10,0.20,0.30,0.40,0.50)bulkrodspreparedbymeltrapidlyquenching.ThepartialsolidsolubilityofTbintheFe–GamatrixwaspreliminarydetectedbythelatticeparametersandSEMobservation.ThematrixkeepsA2structureandthesecondphaseappearssurroundthegrainboundaryasxC0.1.h100ipreferredorientationisalsoobservedforx=0.1samplealongtheaxisofthequenchedrod.Thesaturationmagnetostrictionfirstincreasesandmaximumvaluereachesatx=0.1,andthendecreaseswithTbadditionincreasing.TheinitialincreaseofthemagnetostrictionshouldbeassociatedwiththepartialsolutionofTbinthematrix,themaximumvalueatx=0.1shouldbeattributedtotheh100ipreferredorientation,andthedecreaseofthemagnetostrictioniscorrelatedwiththeappearanceofthesecondphasealongthegrainboundary.
简介:FluorescenceandcofluorescencepropertiesofTb(Ⅲ)solidcomplexeswerestudiedusingpyromelliticacid(PMA)asligandandfluorescenceinertionsasdopingelements.Thecofluorescenceenhancement,aresultofligandsensitizedfluorescence,wasobservedinTb(Ⅲ)solidcomplexesdopedwithfluorescentinertionsLa(Ⅲ),Gd(Ⅲ),Ca(Ⅲ),andSr(Ⅲ).Theeffectofthetypeandcontentofdopingelementsonfluorescenceenhancementwasstudied,andoptimumconditionsweredetermined.TheresultsshowthatGd(La,Ca,Sr)hasclearcofluorescenceeffectinsolidcomplexTb-M-PMAsystem,andinpresentwork,rareearthcomplexfluorescentpowderthatemitsbrightgreenfluorescenceatultravioletexcitationwasobtained,whichhadpotentialapplicationasfluorescentanti-counterfeitink.
简介:阶段和磁电机在合金R(Co_(1-x)Sn_x)的热量的效果有x=的_20,0.025,0.050,0.075,和0.100被X光检查衍射分析和磁化测量调查。在RCo_2的Sn的替换是有限的。为RCo_2的合金的立方的MgCu_2-typestructure被X光检查粉末衍射证实,留下的合金主要由RCo_2阶段组成了,与一些RCo_3和R_5Sn_3杂质阶段一起。Theimpurity阶段随Sn内容的增加增加。合金的T_c不对为Dy(Co_(1-x)Sn_x)的Sn替换很敏感_2和Tb(Co_(1-x)Sn_x)_2inGd(Co_(1-x)Sn_x)_2,居里温度显著地增加。最大的磁性的熵在合金Dy(Co_(1-x)Sn_x)改变_2(x=0,0.025,0.050,0.075)是5.78,5.43,3.88,并且2.98J·kg~(-1)·K~(-1),分别地,并且那些在Tb(Co_(1-x)Sn_x)_2(x=0,0.025)是3.44,and2.29J·kg~(-1)·K~(-1)分别地0-2.0T在应用的地里变化。
简介:Mechanicalalloying(MA)andsubsequentsolidsinteringprocesswasusedtopreparetheNd-containingmagnetostrictiveTb0.4Nd0.6(Fe0.8Co0.2)1.90alloy.Thestructure,thermalstabilityandphasetransformationwereinvestigatedasfunctionsofcomposition,millingprocessandannealingtemperature.Anamorphousphasewasformedbyhigh-energyballmillingfor5hwiththeball-to-powderweightratioof20:1,whichcrystallizedintoMgCu2-typeandPuNi3-typecrystallinestructurewithdifferentannealingte...
简介:Luminescentpolystyrenemicrosphereswereeasilyfabricatedfrompoly(styrene-co-methacrylicacid)andaqueousRE(III)chloridesolution(RE=Eu,Tb)inthepresenceof2,20-bipyridineassecondligand.Thenegativechargesofcarboxylgroupsonthesurfaceofmicrospherescoordinatedwithrareearthionsatfirst,suchascomplexescovalentlylinkedto2,20-bipyridine,resultinginstrongphotoluminescence.Variousmethods,includingtransmissionelectronmicroscope(TEM),scanningelectronmicroscope(SEM),energydispersivespectroscopy(EDS),Fouriertransforminfraredspectroscopy(FT-IR),andfluorescencespectrophotometer,wereusedtocharacterizetheresultantpolystyrenecompositemicrospheres.Thisworkhighlightstheideathatitisfaciletosynthesisluminescentmicrospheresbysurface-modifiedmethoddirectly.
简介:研究烧结温度对含Mn-Nb-Tb的Zn-V-O基陶瓷显微组织和压敏性能的影响。结果表明,随着烧结温度由875°C升高到950°C,烧结陶瓷样品的密度由5.55g/cm3降低到5.45g/cm3,其平均晶粒尺寸由4.1μm增大至8.8μm,击穿场强由7443V/cm显著降低至1064V/cm。经900°C烧结的压敏陶瓷样品具有明显的非线性特性,其非线性系数为49.4,漏电流密度为0.21mA/cm2。当烧结温度由875°C升高到950°C时,Zn-V-O基陶瓷样品的介电常数由440.1增大到2197.2,其损耗因数的变化范围为0.237-0.5。因此,本研究中Zn-V-O基陶瓷组分和烧结条件有利于以银为内电极的先进多层芯片压敏电阻的开发。
简介:本文中介绍了物联网的特点及其相关电子产品对PCB基板材料的要求、目前市场上可供选用基板材料的品种、规格及其主要性能等情况。
简介:聚苯硫醚(PPS)和聚醚砜(PES)树脂都具有较好的耐腐蚀性和较高的耐热性能,这2种热塑性聚合物共混改性可能会得到具有优良性能的共混物。采用差示扫描量热法(DSC)分析共混物的玻璃化转变温度(Tg)及结晶熔融情况,利用扫描电镜观察共混物的形貌结构,行在氮气气氛下用热灭平分析共混物的耐热性能。结果表明:PPS/PES共混物具有2个Tg,且这2个Tg都介于纯聚合物的Tg之间;共混物断面形态比较均匀,两相界而比较模糊,表明共混物为部分相容体系;随着PPS组分的增加,结晶熔融热也逐渐增大,说明PES降低丁PPS的结晶度。用热天平对共混物的耐热性能进行了研究,结果表明共混物在不同PPS/PES比例下耐热性能并没有发生明显变化。