简介:Inthisarticle,theFCCdieselfuelischemicallytreatedwithGZreagent.Theexistentgum,insolublesafteroxidation,andiodinemunberaregreatlyreducedafterchermicaltreatment.Thismethodhasagoodeffectandissimple.Thismethodischaracterizedbyhighrecoveryrateoffuel(>99.7?andlowcost.Thepropertyofthemixtureofchemicallytreateddieselfuelwithstraight-rundieselfuelcanmeettherequirementsofnationalstandardGB252-2000.Thecolorandoxidationstabilityofthemixedfuelafterhavingbeenstoredforthreemonthswerestilllowerthanthevaluesspecifiedinthenationalstandard.
简介:Investigationsonthepyrolysisandkineticbehaviorsduringpyrolysisoffossilfuelsamples,suchascoal,arefundamentalfordevelopingtherelatedtechnologyandpracticalapplication.Inthiswork,pyrolysisbehaviorandkineticsinthepyrolysisprocessofacoalsamplewereinvestigatedbythethermogravimetricanalyzerataheatingrateof10,40,70,100,200,and500°C/min,respectively.ThepyrolysisprocesscouldbedividedintofourstagesaccordingtotheTG/DTGcurves.Thefirststagewasmainlyattributedtotheremovalofvolatiles,andthesecondpeakwasthepolycondensationreactionbetweenthevolatilecomponents.Itwasfoundthatmorevolatilescouldbereleasedfromcoalduringpyrolysisathigherheatingrateandthehigherpyrolysistemperaturewasnecessaryforarapidpyrolysisprocess.Kineticanalysisrevealedthatboththemodel-free(KASandFWO)andtheCoats-Redfernmethodsweresuitabletodescribingthepyrolysisprocess,andthevariationofactivationenergy(E)withthetwotypesofkineticmodelswasconsistentduringthewholepyrolysisprocess.Furthermore,theheatingratedidnotalterthereactionsequenceofthewholepyrolysisprocess,buthigherheatingratecouldmaketheEvalueoftheinitialpyrolysisstagesmaller.
简介: Inordertoactivelyutilizethenon-traditionalresourcesandreducethedependenceofchemicalindustryoncrudeoil,theMinistryofScienceandTechnologyhasincludedtheproject"Keytechnologyformanufactureofmassivechemicalsviaanon-oilbasedroute"inthe"NationalEleventhFive-YearScienceandTechnologySupportingPlan"andisnowcallingforapplicationforrelevantresearchprojects.……
简介:Ahigh-density,high-fluxcirculatingfluidizedbed(CFB)riser(100mminIDand10.614minheight)wasappliedinawiderangeofoperatingconditions(withsolidfluxesupto400kg/m2sandsuperficialgasvelocitiesupto12m/s)toexamineitsradialnon-uniformitydynamics.Thesolidsholdupwasdeterminedthroughtheuseofafiber-opticprobeat11axiallevels.Theresultsindicatedthatunderalloperatingconditions,thehighsuperficialgasvelocityandlowsolidfluxesmaintainedalowradialnon-uniformityindex(RNI).Thehigh-density/fluxCFBriserhadseveraluniquecharacteristics,sothatthepeakoftheradialsolidsholdupprofileoccurredatapositionwithr/R=0.8.TheRNIandsolidsholdupatthecross-sectionalpositionhadagoodlogarithmicrelationshipatthelow-densitycondition(withameansolidsholdupof<0.2),andtheRNIdecreasedwhenthemeansolidsholdupexceeded0.2.InvestigationofthedynamicsofstratifiedinjectionrevealedthatthefeedratiohadanimportanteffectonGsandonsolidsholdupdistribution.Anovel"<"shapedaxialsolidsholdupprofilewasfound.Gsdecreasedsharplywhentheup-flowfeedratioexceeded0.5,andRNIwaslowestwhentheup-flowfeedratiowas1.