简介:Theproject“StudyonFactorsInfluencingtheWaterQualityforEO/EGUnitandOptimizationofWaterTreatmentSystem”performedbytheChemicalIndustryDivisionofShanghaiPetrochemicalCompanyandtheResearchInstituteofYanshanPetrochemicalCompanyhadpassedonJuly8,2004thetechnicalappraisalorganizedbySinopecCorp.Thistech-
简介:为2-propanol/water/ethanediol/KAc系统的咸包含的引得出的蒸馏列和咸包含的代理人恢复列被NRTL模型和修改罗斯松驰方法模仿。模拟结果证明在蒸汽液体平衡和NRTL参数的关联方法(TDCM)的盐效果的预言对说的系统合适。四个不同蒸馏技术过程被调查;结果证明咸包含的引得出的蒸馏过程是最好的。引得出的蒸馏列的模仿的设计在不同全部的阶段数字的条件下面被执行,喂地点,倒流比率,混合代理人的数量和KAc的集中。结果证明象17个阶段,在第9舞台的一个喂的地点,1.2的倒流比率,和喂的一个混合代理人的如此的因素1.141kmol/h评价,最好可能被适合操作条件。模仿的设计也为恢复咸包含的代理人为列被做。咸包含的引得出的蒸馏的模拟方法在这个工作简单、有效。
简介:Oil-waterseparationiscriticaltosolventextractionprocessofrareearth,whichcandirectlyaffecttheyieldandqualityoftheproduct.Theexperimentsmeasurethetwo-phaseseparationtimeinabeaker,mixinguniformityoftwophasesinthemixerandtheoilphaseentrainmentatoilexitbytheKarlFischermethodandnumericalsimulationforthemixersettlertostudythecombinedeffectofgravityandstirring.Experimentalresultsshowthatrelativetothestaticsituation,theseparationefficiencyresultedfromlow-speedstirringisincreasedby25%.ThewatercontentintheoilisaminimumatanoffsetdistanceLof10cmandtheclearanceoffthetankbottomzof10cmisaslowas0.49%.Distributionimagesofoilwaterseparationat2sindicatesthatstirringisveryconducivetotheseparationoftheoil-waterphase.
简介:二进制蒸汽液体平衡(VLE)数据为2-propanol/ethanediol和ethanediol/potassium醋酸盐(KAc)的系统被测量。为propanol/ethanediol的系统的VLE数据用热力学的一致性测试被测试。y1和P的平均价值分别地是0.0776和0.1542kPa。VLE数据的上述二个集合与NRTL模型一起被相关。为2-propanol/water/KAc的系统的第三的VLE数据被用来为2-propanol/KAc和water/KAC(叫的TDCM)的二进制系统获得NRTL模型的更合适的参数。为multicomponent系统,第三、第四级,NRTL模型预言的VLE价值与文学数据同意了很好。KAc的KAc,ethanediol和在2propanol和水之间的轻快上的ethanediol的影响分别地被调查。结果证明上述材料和混合物在在2-propanol和水之间的轻快上有不同影响。为咸包含的VLE的关联和预言的方法为说的系统简单、有效。
简介:Inordertoimprovethestabilityandcorrosioninhibitionperformanceofbioenzyme,lipaseandlsozymewereco-immobilizedonthemesoporousmolecularsieveMCM-41bytheadsorptionmethod.Thentheimmobilizedenzymeswerecombinedwithaminotrimethylenephosphonicacidandpolyasparticacidtopreventcorrosioncausedbycirculatingcoolingwater.Theweight-lossmethodandelectrochemicaltechniqueswereusedtoevaluatetheperformanceofcompositeinhibitors.Theco-immobilizedlysozymeandlipaseachievedgoodinhibitioneffects.Aftertheywerecombinedwithaminotrimethylenephosphonicacidandpolyasparticacid,thecorrosioninhibitionpropertieswerefurtherimproved.Theinhibitionefficiencywaspromotedto94.4%.Duringthecorrosioninhibitionprocess,theimmobilizedenzymesplayedanimportantrole.Theadditionofcorrosioninhibitorcouldinhibittheanodicdissolutionandcathodichydrogenevolutionprocessofcarbonsteelatthesametime.Theadsorptionofco-immobilizedlysozymeandlipasecompositeinhibitoronthesteelsurfacewasajointactioninvolvingphysicaladsorptionandchemicaladsorption.
简介:Thispaperhasstudiedthevapor-liquidequilibrium(VLE)forthesalt-containingextractivedistillationofthe1-propanol/watersystem.BinaryVLEdataweremeasuredforthesystemsof1-propanol(1)/KAc(4),ethanediol(3)/KAc(4),and1-propanol(1)/ethanediol(3),withtheVLEdatacorrelatedwiththeNRTLmodelinordertoobtainthemodelparametersofthesebinarysystems.ThebinaryVLEdatacitedintechnicalliteraturewerecorrelatedtoobtainthemodelparametersforotherbinarysystems.VLEdataofternaryandquaternarysystemspredictedbytheNRTLmodelagreedwellwiththeliteraturedata.TheinfluenceofKAc,ethanediol,andtheKAc/ethanediolmixtureonvolatilitybetween1-propanolandwaterwasinvestigatedrespectively.Testresultsshowedthattheabove-mentionedmaterials(KAc,ethanediol)andtheirmixture(KAcandethanediol)havedifferentinfluenceonthevolatility.Whenx3=0.5,andx4=0.05,theazeotropicpointcanbeeliminated.TheNRTLmodelmethodofsalt-containingVLEissimpleandeffectiveforthepredictionofthesystem’sVLEdata.