简介:Thispaperhasstudiedthevapor-liquidequilibrium(VLE)forthesalt-containingextractivedistillationofthe1-propanol/watersystem.BinaryVLEdataweremeasuredforthesystemsof1-propanol(1)/KAc(4),ethanediol(3)/KAc(4),and1-propanol(1)/ethanediol(3),withtheVLEdatacorrelatedwiththeNRTLmodelinordertoobtainthemodelparametersofthesebinarysystems.ThebinaryVLEdatacitedintechnicalliteraturewerecorrelatedtoobtainthemodelparametersforotherbinarysystems.VLEdataofternaryandquaternarysystemspredictedbytheNRTLmodelagreedwellwiththeliteraturedata.TheinfluenceofKAc,ethanediol,andtheKAc/ethanediolmixtureonvolatilitybetween1-propanolandwaterwasinvestigatedrespectively.Testresultsshowedthattheabove-mentionedmaterials(KAc,ethanediol)andtheirmixture(KAcandethanediol)havedifferentinfluenceonthevolatility.Whenx3=0.5,andx4=0.05,theazeotropicpointcanbeeliminated.TheNRTLmodelmethodofsalt-containingVLEissimpleandeffectiveforthepredictionofthesystem’sVLEdata.
简介:Theproductionunitusinganewprocessformanufactureof1,3-phenylenediaminedevelopedindependentlybytheQingdaoScienceandTechnologyUniversity(QSTU)hasbeensuccessfullyputonstreamattheShandongEkesenChemicalCompanywithitsproductioncapacityreaching10kt/aandalltechnicalindicatorscomplyingwith
简介:为了认识黏土矿物对油层低电阻率化的影响,以薄片、扫描电镜、X射线衍射、测井解释和试油结果为依据,对吴起地区长61油层黏土矿物特征及其对电阻率的影响进行了研究。结果表明,黏土矿物对低电阻率油层的形成具有控制作用,具体表现在3个方面:第一为附加导电作用,以网状伊/蒙混层矿物最强,是油层电阻率降低的关键因素;第二为对孔隙结构的改造,导致束缚水饱和度增高,电阻率降低,以伊利石最为明显;第三是对水分子的吸附作用,以绿泥石等为主。综合三者的作用大小和矿物含量,吴起地区黏土矿物对电阻率的影响程度依次为:伊利石〉伊/蒙混层〉绿泥石〉高岭石。此项研究可对低电阻率油层的存在机理和分布进行有效解释和预测。