简介:TheesterificationoflauricacidwithmethanolcouldbeefficientlycatalyzedbyZrOCl2·8H2O,andthisreactionwasstudiedtodevelopagreenmethodforbiodieselproduction.Theinfluencingfactors,suchasamountofcatalyst,reactiontimeandmolarratioofacidtomethanol,wereinvestigated.TheresultsindicatedthattheZrOCl2·8H2Ocatalystshowedhighcatalyticactivity,andgavea97.0%methyllaurateconversionrateunderthefollowingoptimizedconditions,viz.:alauricacid/methanolmolarratioof1:10,acatalystdosageof4%,andareactiondurationof2hatmethanolrefluxingtemperature.Thecatalystcouldbeeasilyrecoveredwhileitsactivitycouldbewellretainedafterthreecycles.TheZrOCl2·8H2Ocatalystalsoexhibitedexcellentcatalyticactivityfortheesterificationofdifferentfreelong-chainfattyacids(includingnonedibleoilswithhighacidvalue)withdifferentshortcarbonchainalcohols.Therefore,theZrOCl2·8H2Ocatalysthasgoodpotentialforthesynthesisofbiodieselfromlow-costfeedstockssuchaswastevegetableoilsandnon-edibleoils.
简介:在层序地层学和沉积学理论指导下,依据地震反射终止关系(不整合界面特征),将珠江口盆地番禺4洼古近系文昌组划分为6个三级层序,不同层序的地层分布明显受断裂构造控制.根据地震反射内部结构和外部形态,识别出强振幅高连续楔状地震相、丘状地震相和前积反射地震相等.其中,楔状地震相主要分布在洼陷东侧边界断层下降盘,前积反射地震相主要分布在洼陷西侧的缓坡带.文昌组地震相在平面上具有不对称性,在垂向上具有较强的继承性.东沙隆起为研究区提供物源,在番禺4洼东侧边界断层下降盘发育大规模粗粒近岸水下扇和扇三角洲;西侧和南侧缓坡也均为研究区提供物源,并形成中小规模的多类型较粗粒三角洲.