简介:SZorbadsorptivedesulfurizationtechnologyisofgreatsignificanceontheproductionofcleangasolineinChina,buttheformationofZn2SiO4duringtheoperationinsorbentswouldbringforthnegativeimpactsonthedesulfurizationperformanceandthestabilityoftheprocessingunit.Byusingthein-situTPO,XRD,andIRtechniquestostudythemechanismofZn2SiO4formationunderoperatingconditions,itwasfoundthatthecoexistenceofacidandhydrothermalconditionscouldacceleratetheformationofZn2SiO4.Moreover,thestudyofZn2SiO4inhibitionmethodindicatedthatthedecreaseofoxygenconcentrationinregenerationgaswouldinhibittherateofZn2SiO4formation,andtheregenerationofZnSwouldtakeplaceinamildregenerationcondition.
简介:FreshZSM-5zeolitecatalystswerepretreatedat460℃and500℃withvariouscumulativeamountofwaterfeed(CAWF)inafixedbedreactor.Thecatalyticprocesswascarriedoutunderthefollowingconditions:atemperatureof480℃;amethanolWHSVof3h-1;amethanolpartialpressureof30kPa;andatimeonstreamof12h,24hand48h,respectively.TheBETparametersofcatalystsanddiffusioncoefficientsoftolueneshowedthatthereweretwotypesofmesoporesgeneratedunderdifferenthydrothermalconditions.MildtemperatureandmoderateCAWFconditionsledtoexternalopenmesoporeswhichcouldbeenteredfromtheexternalsurfaceofthezeolite,whileahightemperatureorahighCAWFconditionresultedinthegenerationofmacroporesorinternalisolatedmesopores,whichwereoccludedinthemicroporousmatrix.TheTGAresultsshowedthatcatalystwithexternalopenmesoporeshadgoodabilitytoresistcokeaccumulationandgoodperformanceonpropyleneselectivity,whiletheinternalisolatedmesoporesdidnocontributetotheincreaseddiffusivityofreactantsandproducts.
简介:致密油资源评价在国内还处于起步阶段,不同专家对其资源潜力和规模的认识差异较大。三塘湖盆地芦草沟组属典型的致密油,烃源岩厚度、成熟度和总有机碳含量均是控制油气富集的主要因素。与生产实际紧密结合,建立了三塘湖盆地芦草沟组致密油有利区分级地质评价标准,优选出油气勘探的3级评价区。以EUR(EstimatedUltimateRecovery)分级类比法资源评价的关键参数研究为核心,应用油井产量递减规律进行不同评价区单井EUR值求取,运用合理开发井距法、探边测试法和微地震裂缝监测法等3种方法开展了井控面积参数研究,并进行了多方法相互印证,保证了评价结果的科学性与合理性。评价结果已应用于勘探生产中,有效地指导了油气勘探部署,该方法对其他致密油评价区也具有参考价值。
简介:页岩储层具有影响因素多、孔渗关系复杂、非均质性强、评价难度大等特征,为了确定页岩气储层评价参数权重的大小,以重庆南川地区龙马溪组页岩为例,运用灰色关联分析法与模糊综合评判法对页岩储层进行评价。结果显示:总有机碳含量(TOC)、镜质体反射率(Ro)、有效厚度、孔隙度、脆性矿物含量和渗透率均是影响该区页岩储层质量的主要因素,其权重分别为0.2579,0.1331,0.1191,0.1496,0.1392和0.2011。通过对各参数进行模糊数学计算得到页岩储层的综合评价因子为0.41~0.93,并以此为依据预测了南川地区龙马溪组页岩气储层的分布规律。