简介:TheresultsofcommercialapplicationoftwotypesofC_8aromaticsisomerizationcatalystsunderdifferentfeedconditionswerecomparedtogainaninsightinthetechno-economicalbasisforselectingpropertechnologicalrouteattheplant.Thecomparisonrevealsdifferencesineveryaspectoffeedconsumption,unitcapacity,productoutput,productdistribution,andunitprocessparametersdependinguponwhichcatalysttypeisadoptedbytheintegratedPXcomplex.Thetypeofaromaticsisomerizationcatalysthasitsinfluenceontheplantscale,theconstructioncost,theprocessunitcapacityandtheproductcost,withthemagnitudeofitsimpactvaryingwithchangingfeedconditions.
简介:用TSQ-70GC/MS/MS色质仪分析了珠江口盆地100余个原油和生油岩样品,发现部分原油样品具有异常丰富的ααα-C29甾烷(20S)异构体。国内外许多学者认为甾烷ααα-C2920S/(20S+20R)值是最有效的成熟度指标,只与成熟度有关,其热成熟平衡值为0.50-0.55。珠江口盆地有部分油样甾烷ααα-C2920S/(20S+20R)值异常之高,最高达0.67,已超过其热平衡值,已超过了当地成熟、过成熟生油岩样品值。确认油源之后,发现离生油凹陷越远,运移距离越大的原油,其甾烷ααα-C2920S/(20S+20R)值越大。因此,ααα-C2920S(20S+20R)不仅与成熟度有关,还与运移距离有关。
简介:1引言世界上许多中、新生代沉积盆地中均发现丰富的CO2气藏(体积含量大于20%),如松辽盆地[1,2,3]、渤海湾盆地[4]、东海盆地、珠江口盆地和莺歌海盆地[5,6,7]、Pannonian盆地[8,9]、Cooper-Eromanga盆地、北海维京地堑南部[10]、台西南坳陷和日本中新世火山碎屑"绿色凝灰岩"地层[11]及ValVerde前陆盆地[12,13]等,且主要沿环太平洋和欧亚交界、阿尔卑斯和大西洋等构造带分布14,15].研究这些CO2的成因和分布,不仅对天然气勘探和开发有着显著的经济意义,而且对地震预测[14]、壳幔脱气与大气温室效应和环境灾害预测具有重要的理论价值[16].
简介:The^Siand^1Hhigh-resolutionliquid-phaseNMRhasbeenusedtoinvestigatethehydrolysisprocessofthetetraethylorthosilicate(TEOS).^1H-NMRspectroscopyshowsthatthehydrolysisofTEOSinTPAisfasterthaninTEA.TheimpactsofTPAandTEAontheTOEShydrolysisprocessanditshydrolyzedproductdistributionhavebeenobservedby^29Si-NMRrespectively.Theinfluencesofwaterandtheisopropylalcoholonhydrolysishavealsobeendiseussed.ThepresenceofTBOTmarksanevidentdifferentiationbetweenTPAandTEAforhydrolysisin^29Si-NMRspectra.
简介:Thisarticlereferstotheresultsofsmall-scaleandcommercialtestsonhigh-temperaturecrackingofC4fractioninFCCunittoincreasethepropyleneyield.ThebenchtestsrevealedthattheconversionrateofC4fractionduringhigh-temperaturecrackingreached37.38%andpropyleneyieldwasequalto15.60%withtheconversionrateofC4olefinsequatingaround50%.Theresultsofcommercialapplicationshowedthatadoptionofthetechnologyforhigh-temperaturecrackingofC4fractioninFCCunithadledtoanincreaseofpropyleneyieldby2.16%withnoremarkablechangesintheyieldsandpropertiesofotherproducts.
简介:Thispaperhasstudiedthevapor-liquidequilibrium(VLE)forthesalt-containingextractivedistillationofthe1-propanol/watersystem.BinaryVLEdataweremeasuredforthesystemsof1-propanol(1)/KAc(4),ethanediol(3)/KAc(4),and1-propanol(1)/ethanediol(3),withtheVLEdatacorrelatedwiththeNRTLmodelinordertoobtainthemodelparametersofthesebinarysystems.ThebinaryVLEdatacitedintechnicalliteraturewerecorrelatedtoobtainthemodelparametersforotherbinarysystems.VLEdataofternaryandquaternarysystemspredictedbytheNRTLmodelagreedwellwiththeliteraturedata.TheinfluenceofKAc,ethanediol,andtheKAc/ethanediolmixtureonvolatilitybetween1-propanolandwaterwasinvestigatedrespectively.Testresultsshowedthattheabove-mentionedmaterials(KAc,ethanediol)andtheirmixture(KAcandethanediol)havedifferentinfluenceonthevolatility.Whenx3=0.5,andx4=0.05,theazeotropicpointcanbeeliminated.TheNRTLmodelmethodofsalt-containingVLEissimpleandeffectiveforthepredictionofthesystem’sVLEdata.
简介:DuringJuneandJuly2003,JingmenPetrochemicalCompanycardedoutthecommercialtestontechnologyforhigh-temperaturecrackingofC5fractiontodecreaseolefincontentofgasolineinDCCU.ThetestresultsshowedthattheolefincontentofDCCgasolinehaddecreasedfrom68.32m%to42.5m%,meanwhilethepropyleneyieldincreasedby0.90m%.