简介:ThispaperdealswiththestructureoftheY^Ⅲcomplexwithaminopolycarboxylicacids,synthesisandstructuraldeterminationofthecomplex(NH4)[YⅢ(edta)(H2O)3]·3H2O(edta=ethylenediaminetetraaceticacid).Thecrystalandmolecularstructuresofthe(NHO[YⅢ(edta)(H2O)3]·3H20complexhavebeendeterminedbysingle-crystalX-raystructureanalysis.Thecrystalofthecomplex(NH4)[YⅢ(edta)(H2O)3]·3H2Obelongstoorthorhombiccrystalsystemandfdd2spacegroup.Thecrystaldataareasfollows:a=1.9441(9)nm,b=3.5459(18)nm,c=1.2196(6)nm,V=8.407(7)nm3,Z=16,M~=503.25,Dc=1.590g.cm3,μ=2.844mm-1andF(000)=4160.ThefinalRandRware0.0486and0.1332for3388(I>2σ(I))uniquereflections,respectively.Thecomplexanion[YⅢ(edta)(H2O)3]hasapseudo-mono-cappedsquareantiprismaticnine-coordinatestructureinwhichthesixcoordinateatoms(twoNandfourO)arefromanedtaligandandthreewatermoleculescoordinatetothecentralYⅢiondirectly.Fromtheresultsitcanbepredictedthattheymioncanalsoformanine-coordinatecomplexwithttha(=triethylenetetraminehexaaceticacid)ligand,sotheradioactivecomplexanion[99YⅢ(Httha)]2-cansupplyafreecarboxylgroup(-CH2COOH)beingusedformolecularembellishmenttoformtheTDDSforthetreatmentofcancers.
简介:采用等温溶解饱和度法,在25~100°C下于密闭的聚四氟乙烯容器内测定ZnO在NaOH溶液中的溶解度。结果表明:在低浓度NaOH溶液中,平衡体系中只有ZnO一种固相存在,此时氧化锌的溶解度基本上不随温度改变。随着NaOH浓度增高,平衡固相由ZnO突然转变为NaZn(OH)3。这个突变点叫不变点。不变点的NaOH浓度随着温度的升高而增加,但在同一温度下NaZn(OH)3的溶解度随NaOH浓度增加而减少。在同Na2O浓度下,温度越高,NaZn(OH)3的溶解度越高。