学科分类
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32 个结果
  • 简介:Thetime-of-flightmassspectrum(TOFMS)relativetotheresonanttwo-photonionizationofgasphasep-dichlorobenzenewasobtainedinthewavelengthrangeof240-250nmbyahome-madesystem.Aspecialdesignwasmadetoreducetheeffectofmemoryontheinnerwallofthesampleinletsystemsuitablefortheinvestigationofsemi-volatileorganiccompound.Inthiswavelengthrange,p-dichlorobenzenemoleculesfirstlyabsorbedonephotontobeexcitedfromthegToundstate~1A_g(S_0)tothefirstexcitedstate1B2u($1),thenabsorbedanotherphotontobeionized.Therelationshipbetweenthesignalintensityofp-dichlorobenzenemolecularionC_6H_4~(35)Cl_2~+at248-nmwavelengthandthelaserpowerwasgiven.The1.52powerindexofC_6H_4~(35)Cl_2~+wasatypicalidentificationofthe3/2powerlaw.TherelationshipbetweentheionsignalintensityofC_6H_4~(35)Cl_2~+andthesampleconcentrationwasclosetoalinearoneintheppm(V/V)range,whichledtoadetectionlimitof125ppb(V/V)forp-dichlorobenzene.

  • 标签: 激光器 二氯苯 光谱测定法 电离化
  • 简介:Theeffectofλ/2SiO2overcoatonthelaserdamagecharacteristicsofHfO2/SiO2high-reflector(HR)coatingsisinvestigatedwith1-on-1andN-on-1laserdamagetestmethods.Thelaserdamagesurfaceof1-on-1isanalyzedbyastepanalyzer.ThesurfacemorphologiesshowthatlaserdamagemakesthecoatingdamagedareaprotrudentandroughforHRcoatingwithoutλ/2silicaovercoat,butconcaveandsmoothforHRcoatingwithλ/2silicaovercoat.Theresultof10-on-1multi-pulseirradiationonthesamepointofthecoatingshowsthatthereisanenergydensitystageonthedamagecurve.Ifthelaserenergydensityiswithintherangeofthestage,HfO2/SiO2HRcoatingswithλ/2silicaovercoatwillnotbedamagedmorethan2timesformulti-shots,andthesurfacedamagesareveryslightsothatthereisnoimpactonthecoatingperformance.Anotherinterestingresultisthattheenergydensitystageextendsfromthedamagethresholdtothepointofabout3timesofthreshold,whichissimilartotheeffectofthelaserconditiononcoating.

  • 标签: 激光损伤 高能激光装置 光学涂层 高反射涂层 二氧化硅 HFO2/SIO2
  • 简介:温度漂移对水听器系统输出的影响是其实用化进程中的关键技术障碍。这主要表现在温度变化引起水听器探头背衬材料的胀缩和光纤折射率的变化。首先从弹性力学轴对称问题的准静态理论出发分析了背衬材料的应力特性,并用光弹理论及热应力理论分析了温度改变对光纤相位常数的影响,得出了温度影响干涉式光纤水听器光学相位输出的数学表达式。给出了温度变化对水听器光学相位输出影响的实验测量结果,得出了光学相位随温度变化的线性关系图,与理论计算结果吻合。

  • 标签: 光纤传感器 水听器 光弹效应 热应力 温度漂移
  • 简介:提出了使用DSP对F-P腔滤波后的FBG反射谱进行信号处理的解调方案,DSP处理器不断地对测量支路和参考支路的信号进行采集、比较,从而解算出待测量的变化值。从光学原理上探讨了F-P腔用波长表示的干涉滤波函数,对光电探测器测得的信号进行反卷积模拟运算,得到了当光电探测器接收的光强度分布不是中心对称时,分别提高了0.0399nm和0.057nm的FBG反射谱,提高了光纤光栅传感器的解调精度。

  • 标签: 布拉格光纤光栅 F-P腔滤波器 解调 反卷积
  • 简介:Thenonlinearswitchingcharacteristicsoffusedfiberdirectionalcouplerswerestudiedexperimentally.Byusingfemtosecondlaserpulseswithpulsewidthof100fsandwavelengthofabout1550nmfromasystemofTi:sapphirelaserandopticalparametricamplifier(OPA),thenonlinearswitchingpropertiesofanullcoupleranda100%couplerweremeasured.Theexperimentalresultswerecoincidentwiththesimulationsbasedonnonlinearpropagationequationsinfiberbyusingsuper-modetheory.Nonlinearlossinfiberwasalsomeasuredtogettheinjectedpoweratthecoupler.Afterdeductingthenonlinearlossandinputefficiency,thenonlinearswitchingcriticalpeakpowersfora100%andanullfusedcouplerswerecalculatedtobe9410and9440W,respectively.ThenonlinearlossparameterPNinanexpressionofαNL=αP/PNwasobtainedtobePN=0.23W.

  • 标签: 非线性开关 熔融光纤定向耦合器 费秒激光脉冲 光学参数放大器
  • 简介:通过分析F-P扫描干涉仪的工作原理,基于STC89C52RC单片机,采用PA93功率放大器驱动压电陶瓷,设计了1064nm平平腔结构的F-P扫描干涉仪。腔镜反射率为98%,精细度156,腔长0.1~100mm连续可调,对应自由光谱区1.5~1500GHz和分辨率9.65~9650MHz。压电陶瓷驱动电压和频率通过4×4矩阵键盘,可以在0~200V和1~30Hz连续可调,显示在1602液晶屏上。同时可以通过RS232串口与计算机通讯,在上位机使用LabVIEW软件界面方便地设置压电陶瓷驱动电压和频率。最后使用该F-P扫描干涉仪,对激光二极管泵浦Nd:YVO4激光器纵模进行了测量,验证了整个系统的工作性能。

  • 标签: F-P扫描干涉仪 F-P标准具 激光器 单片机
  • 简介:Byusingagraded-indexmultimodefiber(GI-MMF)witharelativelyflatindexprofileandhighrefractiveindexofthefibercore,amicroextrinsicfiber-opticFabryProtinterferometric(MEFPI)strainsensorisfabricatedthroughchemicaletchingandfusionsplicing.Higherreflectanceofthemicrocavityisobtainedduetotheless-curvedinnerwallinthecenterofthefibercoreafteretchingandhigherindexcontrastbetweentheGI-MMFcoreandair.Themaximumreflectionofthesensorisenhanced12dBthanthatobtainedbyetchingoftheEr-orB-dopedfibers.Highfringecontrastof22dBisobtained.ThestrainandtemperatureresponsesoftheMEFPIsensorsareinvestigatedinthisexperiment.Goodlinearityandhighsensitivityareachieved,withwavelength-strainandwavelength-temperaturesensitivitiesof7.82pm/μεand5.01pm/°C,respectively.

  • 标签: 光纤应变传感器 多模光纤 光纤法 梯度折射率 腐烂 化学蚀刻
  • 简介:Thepotentialenergycurves(PECs)ofBOmolecule,includingΣ+andΠsymmetrieswithdoubletspinmultiplicities,areobtainedemployingmulti-referenceconfigurationinteraction(MRCI)methodandDunning'scorrelationconsistentbasissets.Theanalyticalpotentialenergyfunctions(APEFs)arefittedusingtheMurrell-Sorbie(MS)functionandtheleastsquaremethod.BasedonthePECs,thespectroscopicconstantsofthestateshavebeendeterminedandcomparedwiththetheoreticalandexperimentalresultsavailabletoaffirmtheaccuracyandliabilityofthecalculations.Theroot-mean-square(RMS)errorsbetweenthefittedresultsandtheabinitiovaluesaretoolittleincomparisonwiththechemicalaccuracy(349.755cm-1).ItisshownthatthepresentAPEFsareaccurateandcandisplaytheinteractionbetweentheatomswell.ThepresentAPEFscanbeusedtoconstructmorecomplicatedAPEFordosomedynamicinvestigations.

  • 标签: 组态相互作用 分子势能函数 势能曲线 分析势能函数 最小二乘法 光谱常数
  • 简介:Usingamicrowavegenerator,chlorinedilutedbyheliumwasdissociatedtochlorineatomsthatsubse-quentlyreactedwithhydrogenazidetoproducetheexcitedstatesofNCl(a1△).Meanwhile,moleculariodinewithcarriergasofheliumreactedwithatomicchlorinetoproduceatomiciodinewhichthenwaspumpedtoexcitedstateofI(2P1/2)byanenergytransferreactionfromNCl(a1△).Inthispaper,thechangesofNCl(a1△)andNCl(bi∑)emissionintensityispresentedwhenI2/HeisintroducedintothestreamofCl/Cl2/He/HN3/NCl(a1△)/NCl(b1∑).ThedependencesofatomiciodineI(2P1/2)onflowratesofgaseswerealsoinvestigated.TheoptimumparametersforI(2P1/2)productionaregiven.

  • 标签: 化学激光器 微波发生器 实验研究
  • 简介:FourkindsofY2O3stabilizedZrO2(YSZ)thinfilmswithdifferentY2O3contents(from0to12mol%)aredepositedonBK7glasssubstratesbyelectron-beamevaporationmethod.TheeffectsofdifferentY2O3dopantcontentsonresidualstress,structure,andopticalpropertiesofZrO2thinfilmsareinvestigated.TheresultsshowthatresidualstressinYSZthinfilmsvariesfromtensiletocompressivewiththeincreaseofY2O3molarcontent.TheadditionofY2O3isbeneficialtothecrystallizationofYSZthinfilmandtransformationfromamorphoustohightemperaturephase,andtherefractiveindexdecreaseswiththeincreaseofY2O3molarcontent.Moreover,thevariationsofresidualstressandtheshiftsofrefractiveindexcorrespondtotheevolutionofstructuresinducedbytheadditionofY2O3.

  • 标签: 光学 感光底层 氧化锌薄膜 研究
  • 简介:Ag-MgF2cermetfilmswithdifferentAgfractionswerepreparedbyvacuumevaporation.Themicrostruc-tureofthefilmswasexaminedbyRamanscatteringtechnique.Thesurface-enhancedRamanspectrumforMgF2moleculesinthecermetfilmstronglysuggeststheexistenceofAgnanoparticlesdispersedinMgF2matrix.TheintensitiesoftheRamanspectraofAg-MgF2cermetfilmsincreasewithAgfraction.TheenhancementofRamanscatteringdisappearswhenAgcontentreacheswt.20%.TheanalyseswiththetransmissionelectronmicroscopyshowedthatAg-MgF2cermetfilmsaremainlycomposedofamor-phousMgF2matrixwithembeddedfaced-center-cubicAgnanoparticles.Itsuggeststhatthepercolationthresholdshouldbearoundwt.20%ofAgcontent.

  • 标签: 微观结构 拉曼光谱 金属陶瓷薄膜 Ag-MgF2薄膜 二氟化镁
  • 简介:Nitridatedβ-Ga_2O_3(100)substratewasinvestigatedasthesubstrateforGaNepitaxialgrowth.Theeffectsofnitridationtemperatureandsurfaceroughnessofβ-Ga_2O_3wafersontheformationofGaNwerestudied.Itwasfoundthatthemostoptimizednitridationtemperaturewas900°C,andhexagonalGaNwithpreferredorientationwasproducedonthewell-polishedwafer.Thenitridationmechanismwasalsodiscussed.

  • 标签: 单晶体 β-Ga2O3 氮化镓 光学应用
  • 简介:AprototypeRamanlidarwasdesignedformonitoringtroposphericCO_2profileandotherscientificin-vestigations.ThethirdharmonicofNd:YAGlaser(354.7-nmwavelength)wasusedasstimulatedlightsourcetoprovidenighttimemeasurements.FilterwithhighrejectionratioperformancewasusedtoextractCO_2RamansignalsfromRayleigh-Miescatteringsignalseffectively.Toimprovetherealtimemonitoringfunction,atwo-channelsignalcollectionsystemwasdesignedtocollectCO_2andN_2Ramanscatteringsig-nalssimultaneously.TheN_2Ramanscatteringsignalswereusedtoretrieveaerosolextinctioncoefficient.TypicalfeaturesofCO_2concentrationprofileandaerosolextinctioncoefficientinHefeiwerepresented.ThemixingratioofatmosphericCO_2inHefeicanreachabout360-400ppmv.

  • 标签: 对流层 气溶胶 激光雷达 谐波
  • 简介:采用HCl与NH2·H2O分步催化制各了SiO2胶体,在同一终点pH值下可得到不同的粒度,用静电自组装法制各了PDDA/SiO2有机/无机多层复合光学增透薄膜。用TEM测试了薄膜的微观结构,用721分光光度计监测了薄膜的透射率,研究了薄膜的光学性能随薄膜层数及波长的变化。

  • 标签: SIO2 溶胶 静电自组装 增透膜
  • 简介:选用高功率脉冲TEACO2激光器,对不同颜色不同种类的油漆进行了清洗实验,运用数码照片分析程序计算出清洁率,找出了完全清洗阈值和损伤阈值.实验结果较为清晰地给出了激光输出能量和重复频率对清洗效果的影响.对红色醇酸漆来说,完全清洗阈值为10.37J/cm^2,而损伤阈值为11.43J/cm^2;红色金属喷漆的完全清洗阈值为9.66J/cm^2,其损伤阈值达10.37J/cm^2;黄色金属喷漆的完全清洗阈值为10.71J/cm^2,损伤阈值则为11.07J/cm^2.输出能量和重复频率未达指定参数时,激光清洗清洁率则低于100%.

  • 标签: TEA CO2激光器 激光除漆 清洁率 清洗阈值
  • 简介:以正硅酸乙酯为前驱体,乙醇为溶剂,盐酸为催化剂,采用溶胶-凝胶法制备了用于压敏漆基质薄膜材料的SiO2溶胶。不同的成膜助剂对SiO2溶胶的涂膜性能影响较大,其中以异丙醇作为添加剂的溶胶涂膜性能最好。吸收光谱测试结果表明SiO2溶胶不吸收激发光,同时发射光谱研究结果表明SiO2溶胶发光波长为415nm左右,不影响压敏漆探针分子的发光。

  • 标签: 压敏漆 溶胶-凝胶法 SIO2溶胶 吸收光谱 发射光谱
  • 简介:Becausepulserepetitionrateaffecteddirectlythemomentumcouplingcoefficientoftransverselyexcitedatmospheric(TEA)CO2laserpropulsion,adoublepulsetrigger,controllinghighvoltageswitchoflaserexcitationcircuit,wasdesigned.Thepulseintervalrangedbetween5and100ms.Themomentumcouplingcoefficientforair-breathingmodelaserpropulsionwasstudiedexperimentally.Itwasfoundthatthemomentumcouplingcoefficientdecreasedwiththepulserepetitionrateincreasing.

  • 标签: 偶合系数 二氧化碳激光器 变量脉冲重复比率 动量耦合
  • 简介:WhenfemtosecondlaserpulsesinterferewithchirpedfemtosecondlaserpulsesinAs2S3fiber,achirpedfibergratingisformed.Ananalyticalexpressionisgiventodescribethechirpedgrating,anditsBraggreflectivityiscalculated.BecauseofthehighphotosensitiveeffectofAs2S3material,thechirpedfibergratinghasawideBraggreflectivespectrumandhighreflectivitybychoosingproperparameters.Thisindicatesthatthechirpedfibergratingcanbeusedasastretcherinthefemtosecondchirpedpulseamplification(CPA)system.

  • 标签: As2S3 三硫化二砷 啁啾光纤光栅 双光子吸收效应 飞秒啁啾脉冲放大器 CPA
  • 简介:Thecombinationofdeepwetetchingandamagneto-rheologicalfinishing(MRF)processisinvestigatedtosimultaneouslyimprovelaserdamageresistanceofafused-silicasurfaceat355nm.ThesubsequentlydepositedSiO2coatingsareresearchedtoclarifytheimpactofsubstratefinishingtechnologyonthecoatings.Itisrevealedthatadeepremovalproceedingfromthesinglesideordoublesidehadasignificantimpactonthelaser-induceddamagethreshold(LIDT)ofthefusedsilica,especiallyfortherearsurface.Afterthedeepetching,theMRFprocessthatfolloweddoesnotactuallyincreasetheLIDT,butitdoesamelioratethesurfacequalitieswithoutadditionalLIDTdegradation.Thecombinationguaranteeboththeintegrityofthesurface’sfinishandthelaserdamageresistanceofthefusedsilicaandsubsequentSiO2coatings.

  • 标签: SiO2涂层 二氧化硅涂层 光学表面 熔融石英 激光损伤 后处理