简介:Diamond-likecarboncoatingshavebeenusedassolidlubricatingcoatingsinvacuumtechnologyfortheirgoodphysicalandchemicalproperties.Inthispaper,thehybridtechniqueofunbalancedmagnetronsputteringandplasmaimmersionionimplantation(PIll)wasadoptedtofabricatediamond-likecarbon-basedfunctionallygradientfilm,N/TiN/Ti(N,C)/DLC,onthe304stainlesssteelsubstrate.ThefilmwascharacterizedbyusingRamanspectroscopyandglancingX-raydiffraction(GXRD),andthetopographyandsurfaceroughnessofthefilmwasobservedusingAFM.Themechanicalpropertiesofthefilmwereevaluatedbynano-indentation.Theresultsshowedthatthesurfaceroughnessofthefilmwasapproximately0.732nm.Thehardnessandelasticmodulus,fracturetoughnessandinterfacialfracturetoughnessofN/TiN/Ti(N,C)/DLCfunctionallygradientfilmwereabout19.84GPa,190.03GPa,3.75MPa.m1/2and5.68MPa@m1/2,respectively.ComparedwiththatofDLCmonolayerandC/TiC/DLCmultilayer,thisDLCgradientfilmhasbetterqualitiesasasolidlubricatingcoating.
简介:Glassbasedbonecement(GBC)wassynthesizedbymixingCaO-SiO2-P2O5basedglasspowderwithammoniumphosphateliquidmedium.Bone-likehydroxyapatite(HAP,Ca10(PO4)6(OH)2)wasfoundtoformafterGBCwasimmersedinsimulatedbodyfluid(SBF).HAPcrystalgrewwithanincreasingtimealongcaxleandreachedabout200nminlengthafter30days,however,theendplanegranularityremained30~50nm.Thechemicalcomposition,crystalstructureandmorphologyofHAPformedfromGBCwereprovedtohavegreatresemblancewithlivingHAP.ItisbelievedthatGBCwasadesirablebiomedicalmaterialwithhighbioactivity.Furthermore,thehighcompressivestrengthguaranteedthepossibilityofGBCinclinicalapplication.
简介:六角形结构的单人赛水晶的镍硫化物nanorodshave的粉末在cetyltrimethyl综合了溴化铵(CTAB)/water/hexane/n-pentanol在热水的条件由下面的第四级的微乳液用尿素和二硫化碳的反应,作为硫化物,source.Single水晶的镍nanorods被是使用单人赛水晶的镍硫化物nanorods经由热分解综合了先锋。产品的形态学上的不同反应参数的影响是产品的investigated.Thestructure,形态学和磁性被X光检查衍射(XRD)描绘,传播电子显微镜(TEM),thermogravimetric分析微分的扫描热量计(TGA-DSC)和颤动的样品磁强计(VSM)。磁性的大小的结果证明特定的浸透磁化(sigma_s)和nickelnanorods的coercivity价值(H_c)分别地是37.5emu/g和68.5Oe。
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简介:Microstructureandsubsequentphasetransformationsonheatingofthemelt-spunNd85Al15alloyhavebeenstudiedbyX-raydiffraction,transmissionelectronmicroscopyanddifferentialscanningcalorimetry.Themelt-spunNd85Al15alloyshowstwo-stagetransformationprocessesasfollows:amorphous+72nmsupersaturatedbcc-Nd(Al)solidsolution→7nmomega-likephase→AlNd3+hexagonalNd.Theactivationenergiesforthefirstandsecondtransformationwerefoundtobe100kJ/moland188kJ/mol,respectively.Theformationmechanismofnanoscaleomega-likephaseisdiscussed.
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简介:Theuniformcauliflower-likeZnOfilmsweredepositedontheconductingsubstratebyachemicalbathdepositioninurea/watersolution.ThefilmstructureandmorphologywerecharacterizedbyX-raydiffraction,thermogravimetricdifferentialthermalanalysis,energydispersivespectroscopy,selectedareaelectrondiffraction,fieldemissionscanningelectronmicroscopyandhighresolutiontransmissionelectronmicroscopy.TheaveragediameterofZnOnanoparticlesandthepetalthicknesswere25nmand8mm,respectively.Dyesensitizedsolarcellsbasedonthecauliflower-likeZnOfilmelectrodeshowedtheshort-circuitcurrentdensityof6.08mA/cm2,theopen-circuitphotovoltageof0.66V,thefillfactorof0.55andtheoverallconversionefficiencyof2.18%.TheequivalentcircuitofcellsbasedontheZnOfilmelectrodeswasmeasuredbytheelectrochemicalimpedancespectroscopy.Furthermore,theanalysisofequivalentcircuitprovidedtherelationshipbetweenthecellperformanceandtheinterfacialresistance,suchastheshuntresistanceandtheseriesresistance.